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Unique hydrocarbon-generating mechanism of Oligocene evaporites of Qaidam Basin, West China

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Abstract

The principle hydrocarbon source in West Qaidam Basin, China, is the Xiaganchaigou formation, which charges a series of Cenozoic large reservoirs. We identified a series of organic-rich intervals within a sequence of Oligocene-age Xiaganchaigou evaporites in southwest Qaidam. By analyzing 2D and 3D seismic tomography and gamma ray well logs, we defined the distribution and extent of these source rocks. We also characterized their composition with trace element analysis and carbon and oxygen isotope measurements. Our data demonstrated distinctive characteristics of these source rocks with high salinity, abundant organic material, high hydrocarbon generation efficiency, and low maturity, which are associated with relatively rapid and productive hydrocarbon generation. Using high-pressure and high temperature experiments to simulate pyrolysis in samples of the source rocks, we investigated what enabled these young salt-rich source rocks to generate such an abundance of hydrocarbons. Our results highlighted the key role of saline and radioactive minerals in catalyzing accelerated pyrolysis of hydrocarbons during diagenesis and catagenesis. Salt catalysis clearly played an important role in hydrocarbon generation within lower maturity formations and also significantly improved and redefined the source rocks distribution and the extent of probable reserves in the southwest Qaidam.

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References

  • Alexander R, Kagi RI, Larcher AV (1982) Clay catalysis of aromatic hydrogen exchange reactions. Geochim Cosmochim Acta 46(2):219–222

    Article  Google Scholar 

  • Alexander R, Kagi RI, Larcher AV (1984) Clay catalysis of alkyl hydrogen exchange reactions-reaction mechanisms. Org Geochem 6:755–760

    Article  Google Scholar 

  • Behar F, Roy S, Jarvie D (2010) Artificial maturation of a type I kerogen in closed system: mass balances and kinetic modeling. Org Geochem 41:1235–1247

    Article  Google Scholar 

  • Campbell T, Newton MA, Boyd V, Lee DF, Evans J (2005) Effects of precursor and support variation in the genesis of uranium oxide catalysts for CO oxidation and selective reduction of NO: synthesis and characterization. J Phys Chem B 109(7):2885–2893

    Article  Google Scholar 

  • Cassou AM, Connan J, Correia M (1975) Etudes chimiques et observbation microscopiques de la matiere organique de quelques mineralisations uraniferes. Le Phenomene d’Oklo. IAEA-SM-204, Vienna, pp 195–206

  • Chen Q, Zhao F, Su Q, Ma F, Wu L (2016) Quaternary evaporites of biogenic methane gas in the eastern Qaidam Basin, China. Carbonates Evaporites 31(2):213–218. https://doi.org/10.1007/s13146-016-0288-3

    Article  Google Scholar 

  • Espitaile J, Madec M, Tissot B (1980) Role of mineral matrix in kerogen pyrolysis: influence on petroleum generation and migration. AAPG Bull 69(1):59–66

    Google Scholar 

  • Espitaile J, Makadi KS, Trichet J (1984) Role of mineral matrix during kerogen pyrolysis. Org Geochem 6(84):365–382

    Article  Google Scholar 

  • Fu ST, Yuan JY, Wang LQ, Zhang SC (2014) Geological conditions of hydrocarbon accumulation in Qaidam Basin. Science Press, Beijing, pp 255–278 (in Chinese)

    Google Scholar 

  • Fu ST, Ma DD, Guo ZJ (2015) Strike-slip superimposed Qaidam Basin and its control on oil and gas accumulation, NW China. Pet Explor Dev 42(6):778–789

    Article  Google Scholar 

  • Goldstein TP (1983) Geocatalytic reaction in formation and maturation of petroleum. AAPG Bull 67(1):152–159

    Google Scholar 

  • Gou YC, Cao ZL, Zhang XJ, Wan CZ, Wang P, Su XY (2014) Delta sedimentary simulating experiment on saline basin. Geoscience 28(6):1284–1288 (in Chinese with English abstract)

    Google Scholar 

  • Hoering TC (1984) Thermal reactions of kerogen with added water, heavy water and pure organic substances. Org Geochem 5(4):267–278

    Article  Google Scholar 

  • Horsfield B, Douglas AG (1980) The influence of minerals on the pyrolysis of kerogens. Geochim Cosmochim Acta 44:1119–1131

    Article  Google Scholar 

  • Huang D, Zhang D, Li J (1989) The tertiary oil source correlation in Qaidam Basin. Acta Sedimentol Sin 7:1–14 (in Chinese with English abstract)

    Google Scholar 

  • Huang D, Zhang D, Li J (1994) The origin of 4-methyl steranes and pregnanes from tertiary strata in the Qaidam Basin, China. Org Geochem 22:343–348

    Article  Google Scholar 

  • Huang CG, Zhao F, Yuan JY, Wu LY, Chen GX (2015) The characteristics of dolomite reservoir in saline lacustrine basin, Qaidam, China. Carbonates Evaporites. https://doi.org/10.1007/s13146-015-0267-0

    Article  Google Scholar 

  • Huizinga BJ, Tannenbaum E, Kaplan IR (1987) The role of minerals in the thermal alteration of organic matter-IV. Generation of n-alkanes, acyclic isoprenoids, and alkenes in laboratory experiments. Geochim Cosmochim Acta 51(5):1083–1097

    Article  Google Scholar 

  • Jin Q, Guangyou Zhu, Juan Wang (2008) Deposition and distribution of high potential source rocks in saline lacustrine environments. J China Univ Pet 32(4):19–23 (in Chinese with English abstract)

    Google Scholar 

  • Lei TZ, Jin M, Zhang R, Qiu JL, Xia YQ (2007) Investigation into the hydrocarbon generation kinetics of tertiary source rocks from the west of Qaidam Basin. J Lanzhou Univ (Nat Sci) 43(1):15–18 (in Chinese with English abstract)

    Google Scholar 

  • Lewan MD (1997) Experiments on the role of water in petroleum formation. Geochim Cosmochim Acta 61(17):3691–3723

    Article  Google Scholar 

  • Li HB, Zhang M, Zhang CM, Peng DH (2008) Geochemical characteristics of tertiary source rocks in the south area of western Qaidam Basin. Nat Gas Geosci 19(4):519–523 (in Chinese with English abstract)

    Google Scholar 

  • Liu ZG, Zhu C, Li SM (2017) Geological features and exploration fields of tight oil in the Cenozoic of west Qaidam Basin, NW China. Pet Explor Dev 44(2):217–225

    Article  Google Scholar 

  • Lu SH, Chen FW, Li JJ (2012) Identification of the lower limit of high quality source rocks and its relation to hydrocarbon accumulation: taking the Beier Sag in the Hailaer Basin as an example. Pet Sci 9:10–17

    Article  Google Scholar 

  • Madhavaram H, Idriss H (2004) Acetaldehyde reactions over the uranium oxide system. J Catal 224:358–369

    Article  Google Scholar 

  • Mango FD (1992) Transition metal catalysis in the generation of petroleum and natural gas. Geochim Cosmochim Acta 56:553–555

    Article  Google Scholar 

  • Mao GZ, Liu CY, Liu BQ, Zhang DD, Qiu XW, Wang JQ (2012a) Effects of uranium on hydrocarbon generation of low mature hydrocarbon source rocks containing kerogen type I. J China Univ Pet 36(2):172–181 (in Chinese with English abstract)

    Google Scholar 

  • Mao GZ, Liu CY, Zhang DD, Qiu XW, Wang JQ, Liu BQ, Liu JJ, Qu SD, Zhang C, Deng Y, Wang FF (2012b) Effects of uranium(type II) on evolution of hydrocarbon generation of source rocks. Acta Geol Sin 86(11):1833–1840 (in Chinese with English abstract)

    Google Scholar 

  • Mao GZ, Liu CY, Zhang DD, Qiu XW, Wang JQ, Liu BQ, Liu JJ, Qu SD, Deng Y, Wang FF, Zhang C (2014) Effects of uranium on hydrocarbon generation of hydrocarbon source rocks with type-III kerogen. Sci China (Ser D) 44(8):1740–1750 (in Chinese with English abstract)

    Google Scholar 

  • Mao LG, Xiao AC, Zhang HW (2016) Structural deformation pattern within the NW Qaidam Basin in the Cenozoic era and its tectonic implications. Tectonophisics 687:78–93

    Article  Google Scholar 

  • Mohammad RK, Ahad AM (2004) Total organic carbon content determined from well log using ΔlogR and neuro fuzzy techniques. J Pet Sci Eng 45(3–4):141–148

    Google Scholar 

  • Pettijohn FJ, Potter PE, Siever R (1987) Diagenesis. In: Sand and Sandstone. Springer, New York, NY. https://doi.org/10.1007/978-1-4612-1066-5_11

  • Price LC (1993) Thermal stability of hydrocarbons in nature: limits, evidence, characteristics, and possible controls. Geochim Cosmochim Acta 57(14):3261–3280

    Article  Google Scholar 

  • Reynolds JG, Burnham AK (1995) Comparison of analysis of source rocks and kerogen concentrates. Org Geochem 21(1):11–19

    Article  Google Scholar 

  • Schimmelmann A, Bondon JP, Lewan MD, Wintsch RP (2001) Experimental controls on D/H and 13C/12C ratios of kerogen, bitumen and oil during hydrous pyrolysis. Org Geochem 32(8):1009–1018

    Article  Google Scholar 

  • Seewald JS (2003) Origanic–inorganic interaction in petroleum producing basins. Nature 426(20):327–333

    Article  Google Scholar 

  • Shi H, Liu Z, Lian LD, Mao YK, Zhang QX, Yang QZ, Wu J (2013) Enrichment regularity of lithologic reservoirs in plateau saline lacustrine basin: taking the southwestern Qaidam Basin for example. Nat Gas Geosci 24(4):701–709 (in Chinese with English abstract)

    Google Scholar 

  • Stalker L, Farrimond P, Larter SR (1994) Water as an oxygen source for the production of oxygenated compounds (including CO2 precursors) during kerogen maturation. Org Geochem 22(3–5):477–486

    Article  Google Scholar 

  • State Economic and Trade Commission (2003) The People’s Republic of China petroleum and natural gas industry standards SY/T 5477-2003—the division of diagenetic stages in clastic rocks. Petroleum Industry Press, Beijing, pp 1–11

    Google Scholar 

  • Tannenbaum E, Kaplan IR (1985) Low-Mr hydrocarbons generated during hydrous and dry pyrolysis of kerogen. Nature 317(6039):708–709

    Article  Google Scholar 

  • Taylor SH, Hutchings GJ, Palacious ML, Lee DF (2003) The partial oxidation of propane to formaldehyde using uranium mixed oxide catalysts. Catal Today 81(2):171–178

    Article  Google Scholar 

  • Tissot BP, Pelet R, Ungerer PH (1987) Thermal history of sedimentary basins, maturation indices, and kinetics of oil and gas generation. AAPG Bull 71(12):1445–1466

    Google Scholar 

  • Wang L, Jin Q, Lin LM, Liu YC, Zhang BM (2009) Characteristics of quality tertiary source rocks in West Qaidam Basin. Nat Gas Ind 29(2):23–26 (in Chinese with English abstract)

    Google Scholar 

  • Wang D, Wu BL, Cun XN, Sun L, Xu ZG, Zhan J, Yuan K (2015) Coexistence of multiple energy minerals in Qaidam Basin and its geological significance. J Earth Sci Environ 37(3):55–67 (in Chinese with English abstract)

    Google Scholar 

  • Wu DY, Zhang GF (1994) Simulation experiment study on hydrocarbon generation from organic matter in saline lake facies rocks. Geochimica 23(S1):173–181 (in Chinese with English abstract)

    Google Scholar 

  • Xiong D, Bingwen W, Jingshan C, Qingsong T, Han W (2018a) Characteristics of the tight sand reservoirs in the delta front in the Xu-2 Member of the Upper Triassic Xujiahe formation (Hechuan area of the central Sichuan Basin, SW China). Arab J Geosci. https://doi.org/10.1007/s12517-018-3489-3

    Article  Google Scholar 

  • Xiong D, Bingwen W, Xingzhi W, Hong L, Deming Z, Minyou F (2018b) The three different types of paleokarstification and reservoir distribution of Leikoupo formation, Middle Triassic in the northern Sichuan Basin, China. Carbonates Evaporates 33:243–254

    Article  Google Scholar 

  • Xiong D, Han W, Yuefeng S, Hanghang Y, Zihao Z, Jingshan C, Qingsong T (2018c) Genetic types of carbonate shoal reservoirs in the Middle Triassic of the Sichuan Basin (SW China). Mar Pet Geol. https://doi.org/10.1016/j.marpetgeo.2018.10.003

    Article  Google Scholar 

  • Yi DH, Wang JG, Shi YJ (2017) Evolution characteristic of gypsum-salt rocks of the upper member of Oligocene Lower Ganchaigou FM in the Shizigou area, West Qaidam Basin. Nat Gas Ind 4:390–398

    Article  Google Scholar 

  • Yuan JY, Huang CG, Zhao F, Pan X (2015) Carbon and oxygen isotopic compositions, and palaeoenvironmental significance of saline lacustrine dolomite from the Qaidam Basin, Western China. J Pet Sci Eng 135(11):596–607

    Article  Google Scholar 

  • Yuan JY, Huang CG, Zhao F, Sun XJ (2016) Geochemical characteristics of Eocene dolomite in the saline lacustrine basin, Qiadam, China. Carbonates Evaporates. https://doi.org/10.1007/s13146-016-0315-4

    Article  Google Scholar 

  • Zhao F (2013) Acustrine algal limestone reservoir in Western Qaidam Basin China. Carbonates Evaporates. https://doi.org/10.1007/s13146-013-0182-1

    Article  Google Scholar 

  • Zhao F (2014) Identification of Neogene mixed lacustrine carbonate in western Qaidam Basin. Carbonates Evaporates. https://doi.org/10.1007/s13146-014-0210-9

    Article  Google Scholar 

  • Zhou FY, Peng DH, Bian LZ, Huang DP, Wang YB (2002) Progress in the organic matter study of immature oils in the Qaidam Basin. Acta Geol Sin 76(1):107–113 (in Chinese with English abstract)

    Google Scholar 

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Authors and Affiliations

  1. State Key Laboratory of Continental Dynamics, Department of Geology, Northwest University, Xi’an, 710069, China

    Xinmin Ma

  2. Northwest Branch of Research Institute of Petroleum Exploration and Development, Petrochina, Lanzhou, 730020, China

    Xinmin Ma, Chenggang Huang, Yajun Shi, Haiyan Chang & Fan Zhao

  3. Key Laboratory of Reservoir Description, CNPC, Lanzhou, 730020, China

    Chenggang Huang

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  1. Xinmin Ma
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Correspondence to Chenggang Huang.

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Ma, X., Huang, C., Shi, Y. et al. Unique hydrocarbon-generating mechanism of Oligocene evaporites of Qaidam Basin, West China. Carbonates Evaporites 34, 1455–1467 (2019). https://doi.org/10.1007/s13146-019-00484-5

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