Abstract
Understanding the groundwater evolution has always been a challenging work for geochemists and hydrogeologists. The purpose of this study is to reveal the evolution mechanism of groundwater quality in karst groundwater system from Liulin, northern China. Multiple hydrochemical indicators were used to differentiate the dominant geochemical processes of hydrogeochemical evolution. The results suggested that the dissolution of calcite and dolomite widely occurred in Liulin karst water system, especially in the recharge area, and the dissolution of halite, gypsum and mirabilite locally occurred in the runoff and discharge areas of the system. Dedolomitization driven by gypsum dissolution was found in the runoff areas of karst aquifers on the north and south of Liulin springs. Cation exchange between Ca2+, Mg2+ and Na+ was proved to take place in the runoff and discharge areas. Besides, the springs in the north of Sanchuan River were more saline than those in the south, which could be attributed to the common effect of geologic background and recharge sources. Eventually, an updated conceptual model of the geochemical processes in Liulin karst water system was developed, which illustrated the chemical evolution and geochemical processes of karst groundwater along the flow paths.
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References
Back W, Hanshaw BB, Plummer LN, Rahn PH, Rightmire CT, Rubin M (1983) Process and rate of dedolomitization: mass transfer and 14C dating in a regional carbonate aquifer. Geol Soc Am Bull 94:1414–1429
Barzegar R, Moghaddam A, Najib M, Kazemian N, Adamowski J (2016) Characterization of hydrogeologic properties of the Tabriz plain multilayer aquifer system, NW Iran. Arab J Geosci 9:147
Belfar D, Fehdi C, Baali F, Salameh E (2015) Results of a hydrogeological and hydrogeochemical study of a semi-arid karst aquifer in Tezbent plateau, Tebessa region, northeast of Algeria. Appl Water Sci. doi:10.1007/s13201-015-0357-0
Bischoff JL, Juliá R, Shanks WC III, Rosenbauer RJ (1994) Karstification without carbonic acid Bedrock dissolution by gypsum-driven dedolomitization. Geology 22:995–998
Cerling TE, Pederson BL, Damm KLV (1989) Sodium-calcium ion exchange in the weathering of shales: implications for global weathering budgets. Geology 17:552–554
Clark I, Fritz P (1997) Environmental isotopes in hydrogeology. Lewis Publisher, Boca Raton
Feng ZZ, Chen JX, Zhang JS (1991) Lithofacies paleogeography of Early Paleozoic in Ordos area. Geology Publishing House, Beijing
Fisher RS, Mulican WF (1997) Hydrogeochemical evolution of sodiumsulphate and sodium-chloride groundwater beneath the Northern Chihuahua desert, Trans-Pecos, Texas, USA. Hydrogeol J 10(4):455–474
Gao BY, Liang YP, Wang WT (2008) Features of karst water and geologic background in Liulin spring basin. Carsologica Sinca 27(3):209–214
Goldscheider N, Drew D (2007) Methods in karst hydrogeology. Taylor & Francis, London
Hamed Y (2013) The hydrogeochemical characterization of groundwater in Gafsa-Sidi Boubaker region (Southwestern Tunisia). Arab J Geosci 6:697–710
Hamed Y, Dhahri F (2013) Hydro-geochemical and isotopic composition of groundwater, with emphasis on sources of salinity, in the aquifer system in Northwestern Tunisia. J Afr Earth Sci 83:10–24
Hamed Y, Ahmadi R, Demdoum A, Bouri S, Gargouri I, Dhia HB, Al-Gamal S, Laouar R, Choura A (2014) Use of geochemical, isotopic, and age tracer data to develop models of groundwater flow: a case study of Gafsa mining basin-Southern Tunisia. J Afr Earth Sci 100:418–436. doi:10.1016/j.jafrearsci.2014.07.012
Hidalgo MC, Cruz-Sanjulian J (2001) Groundwater composition, hydrochemical evolution and mass transfer in a regional detrital aquifer (Baza basin, southern Spain). Appl Geochem 16:745–758
Hou G, Zhang M, Liu F, Wang Y, Liang Y (2008) Groundwater exploration in the Ordos basin. Geology Publishing House, Beijing
Jeelani Gh, Bhat NA, Shivanna K, Bhat MY (2011) Geochemical characterization of surface water and spring water in SE Kashmir Valley, western Himalaya: implications to water–rock interaction. J Earth Syst Sci 120(5):921–932
Kumar M, Rmanathan AL, Rao MS, Kumar B (2006) Identification and evaluation of hydrogeochemical processes in the groundwater environment of Delhi, India. Environ Geol 50:1025–1039
Kumar M, Herbert JR, Ramanathan AL, Someshwar RM, Kim K, Deka JP, Kumar B (2013) Hydrogeochemical zonation for groundwater management in the area with diversified geological and landuse setup. Chem Erde-Geochem 73(3):267–274
Li Y (2010) Study on environmental isotopes in groundwater of Yangzhou–Taizhou–JingJiang area. Chinese Academy of Geological Sciences, Beijing
Li LP, Gao BY, Wang Z (2000) Development, utilization and protection of Liulin underground karst spring in Shanxi Province. Water Resour Protect 2:22–27
Li P, Wu J, Qian H (2013) Assessment of groundwater quality for irrigation purposes and identification of hydrogeochemical evolution mechanisms in Pengyang County, China. Environ Earth Sci 69(7):2211–2225. doi:10.1007/s12665-012-2049-5
Li P, Qian H, Wu J, Chen J, Zhang Y, Zhang H (2014) Occurrence and hydrogeochemistry of fluoride in shallow alluvial aquifer of Weihe River, China. Environ Earth Sci 71(7):3133–3145. doi:10.1007/s12665-013-2691-6
Li F, Zhang JX, Zhang R (2015) Spatial-temporal characteristics of precipitation in Shanxi during 1958–2013. J Desert Res 35(5):1301–1311
Li P, Wu J, Qian H (2016a) Hydrochemical appraisal of groundwater quality for drinking and irrigation purposes and the major influencing factors: a case study in and around Hua County, China. Arab J Geosci 9(1):15. doi:10.1007/s12517-015-2059-1
Li P, Wu J, Qian H, Zhang Y, Yang N, Jing L, Yu P (2016b) Hydrogeochemical characterization of groundwater in and around a wastewater irrigated forest in the southeastern edge of the Tengger Desert, Northwest China. Expo Health 8(3):331–348. doi:10.1007/s12403-016-0193-y
Ma T, Wang YX (1999) Using factor-Kriging to analyze the groundwater geochemistry in Liulin karst system, Shanxi Province. Hydrogeol Eng Geol 1:44–46
Marfia AM, Krishnamurthy RV, Atekwana EA, Panton WF (2004) Isotopic and geochemical evolution of ground and surface waters in a karst dominated geological setting: a case study from Belize, Central America. Appl Geochem 19:937–946
Marghade D, Malpe DB, Zade AB (2011) Geochemical characterization of groundwater from northeastern part of Nagpur urban, Central India. Environ Earth Sci 62:1419–1430
Mokadem N, Demdoum A, Hamed Y, Bouri S, Hadji R, Boyce A, Laouar R, Sâad A (2016) Hydrogeochemical and stable isotope data of groundwater of a multi-aquifer system: Northern Gafsa basin—Central Tunisia. J Afr Earth Sci 114:174–191
Pan J, Zhang J, Liang Y (2008) Water resources protection of karst spring area in Shanxi province. China Waterpower Press, Beijing
Plummer LN, Back W (1980) The mass balance approach: application to interpreting the chemical evolution of hydrologic systems. Am J Sci 80:130–142
Plummer LN, Busby JF, Lee RW, Hanshaw BB (1990) Geochemical modeling of the madison aquifer in parts of Montana, Wyoming, and South Dakota. Water Resour Res 26:1981–2014
Stimson J, Frape S, Drimmie R, Rudolph D (2001) Isotopic and geochemical evidence of regional-scale anisotropy and interconnectivity of an alluvial fan system, Cochabamba Valley, Bolivia. Appl Geochem 16:1097–1114
Shanxi Institute of Geological Survey (2008) Groundwater exploration (Shanxi province) report of Ordos Basin
Venugopal T, Giridharan L, Jayaprakash M, Periakali P (2009) Environmental impact assessment and seasonal variation study of the groundwater in the vicinity of river Adyar, Chennai, India. Environ Monit Assess 149:81–97
Wang YX, Ma T, Luo ZH (2001) Geostatistical and geochemical analysis of surface water leakage into groundwater on a regional scale: a case study in the Liulin karst system, northwestern China. J Hydrol 246:223–234
Wang YX, Guo QH, Su CL, Ma T (2006) Strontium isotope characterization and major ion geochemistry of karst water flow, Shentou, northern China. J Hydrol 328:592–603
Wendland F, Blum A, Coetsiers M, Gorova R, Griffioen J, Grima J, Hinsby K, Kunkel R, Marandi A, Melo T, Panagopoulos A, Pauwels H, Ruisi M, Traversa P, Vermooten JSA, Walraevens K (2008) European aquifer typology: a practical framework for an overview of major groundwater composition at European scale. Environ Geol 55:77–85
Wildemeersch S, Orban P, Ruthy I, Grière O, Olive P, El Youbi A, Dassargues A (2010) Towards a better understanding of the Oulmes hydrogeological system (Mid-Atlas, Morocco). Environ Earth Sci 60(8):1753–1769
Wu J, Li P, Qian H, Duan Z, Zhang X (2014) Using correlation and multivariate statistical analysis to identify hydrogeochemical processes affecting the major ion chemistry of waters: case study in Laoheba phosphorite mine in Sichuan, China. Arab J Geosci 7(10):3973–3982. doi:10.1007/s12517-013-1057-4
Wu J, Li P, Qian H (2015) Hydrochemical characterization of drinking groundwater with special reference to fluoride in an arid area of China and the control of aquifer leakage on its concentrations. Environ Earth Sci 73(12):8575–8588. doi:10.1007/s12665-015-4018-2
Xing LN, Guo HM, Zhan YH (2013) Groundwater hydrochemical characteristics and processes along flow paths in the North China Plain. J Asian Earth Sci 70–71:250–264
Zang HF, Zheng XQ, Jia ZX, Chen JF, Qin ZD (2015) The impact of hydrogeochemical processes on karst groundwater quality in arid and semiarid area: a case study in the Liulin spring area, north China. Arab J Geosci 8:6507–6519
Zhang GH, Guo MP, Zhao HY (2008) Study on the change of precipitation in Shanxi Province since recent 45 years. Arid Zone Res 25(6):858–892
Acknowledgements
The study has been financially supported by the National Natural Science Foundation of China (No. 41472227), Project of National Key Research and Development Program of China in the 13th Five-year Plan: Agroforestry complex operation technology and demonstration for rocky desertification control in the karst plateau-mountain region (2016YFC0502601). We appreciate very much the constructive comments from two anonymous reviewers and the editors.
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Yang, M., Lu, Y., Zhang, F. et al. Identification of geochemical processes by hydrogeochemical analysis in karst aquifers of a semi-arid region, Northern China. Carbonates Evaporites 34, 297–313 (2019). https://doi.org/10.1007/s13146-017-0384-z
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DOI: https://doi.org/10.1007/s13146-017-0384-z