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Heavy metals in Changjiang estuarine and offshore sediments: responding to human activities

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Abstract

The Changjiang (Yangtze) estuarine and offshore sediments were analyzed for total heavy metals concentrations and chemical fractions. Distributions of heavy metals show typical banded diffusion pattern, with high concentrations near the river mouth and following a decreasing trend in the offshore direction. According to chemical fractions, Fe/Mn oxide fraction is the major non-residual fraction in the Changjiang estuarine and offshore sediments. Higher percentage of non-residual fraction of Pb implies that, the industrial contaminations transported via the atmosphere and river input, may affect the non-residual fraction of heavy metals. Over past fifteen years, the concentration of Pb normalizing to Al presents significant increasing trend, corresponding to the effect of human activities. By comparison of heavy metals fractions in 2003 to 2006, it has been realized that increasing water and sediment may cause a higher percentage non-residual fraction of Cu in the southern part of offshore muddy sediments.

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References

  • Abe K, Ishihi Y, Watanabe Y. 2003. Dissolved copper in the Yellow Sea and the East China Sea—Cu as a tracer of the Changjiang discharge. Deep Sea Research Part II: Topical Studies in Oceanography, 50: 327–337

    Article  Google Scholar 

  • Audry S, Schäfer J, Blanc G, et al. 2004. Fifty-year sedimentary record of heavy metal pollution (Cd, Zn, Cu, Pb) in the Lot River reservoirs (France). Environmental Pollution, 132: 413–426

    Article  Google Scholar 

  • Bao Xiang, Watanabe M, Wang Qinxue, et al. 2006. Nitrogen budgets of agricultural fields of the Changjiang River basin from 1980 to 1990. Science of The Total Environment, 363: 136–148

    Article  Google Scholar 

  • Chen Jiyu, Li Daoji, Chen Banglin, et al. 1999. The processes of dynamic sedimentation in the Changjiang Estuary. Journal of Sea Research, 41: 129–140

    Article  Google Scholar 

  • Chen Zhongyuan, Saito Y, Kanai Y, et al. 2004. Low concentration of heavy metals in the Yangtze estuarine sediments, China: a diluting setting. Estuarine, Coastal and Shelf Science, 60: 91–100

    Article  Google Scholar 

  • Chu Zhongxin, Zhai Shikui, Lu X, et al. 2009. A quantitative assessment of human impacts on decrease in sediment flux from major Chinese rivers entering the western Pacific Ocean. Geophysical Research Letters, 36: L19603

    Article  Google Scholar 

  • DeMaster D J, McKee B A, Nittrouer C A, et al. 1985. Rates of sediment accumulation and particle reworking based on radiochemical measurements from continental shelf deposits in the East China Sea. Continental Shelf Research, 4: 143–158

    Article  Google Scholar 

  • Dong Aiguo, Zhai Shikui, Zabel M, et al. 2009a. The distribution of heavy metal contents in surface sediments of the Changjiang estuary in China and surrounding coastal area. Acta Oceanologica Sinica, 31: 54–68

    Google Scholar 

  • Dong Aiguo, Zhai Shikui, Zabel M, et al. 2009b. Geochemistry characters of the core sediments in the Yangtze estuary and the response to human activities. Marine Geology & Quaternary Geology, 29: 107–114

    Google Scholar 

  • Edmond J M, Spivack A, Grant B C, et al. 1985. Chemical dynamics of the Changjiang estuary. Continental Shelf Research, 4: 17–36

    Article  Google Scholar 

  • Farkas A, Erratico C, Viganò L. 2007. Assessment of the environmental significance of heavy metal pollution in surficial sediments of the River Po. Chemosphere, 68: 761–768

    Article  Google Scholar 

  • Feng Huan, Han Xiaofei, Zhang Weiguo, et al. 2004. A preliminary study of heavy metal contamination in Yangtze River intertidal zone due to urbanization. Marine Pollution Bulletin, 49: 910–915

    Article  Google Scholar 

  • Feng Huan, Kirk Cochran J, Hirschberg D J. 2002. Transport and sources of metal contaminants over the course of tidal cycle in the turbidity maximum zone of the Hudson River estuary. Water Research, 36: 733–743

    Article  Google Scholar 

  • Gao Xuelu, Song Jinming. 2005. Phytoplankton distributions and their relationship with the environment in the Changjiang Estuary, China. Marine Pollution Bulletin, 50: 327–335

    Article  Google Scholar 

  • Gao Shu, Wang Yaping. 2008. Changes in material fluxes from the Changjiang River and their implications on the adjoining continental shelf ecosystem. Continental Shelf Research, 28: 1490–1500

    Article  Google Scholar 

  • Guo Zhigang, Feng Jialiang, Fang Ming, et al. 2004. The elemental and organic characteristics of PM2.5 in Asian dust episodes in Qingdao, China, 2002. Atmospheric Environment, 38: 909–919

    Article  Google Scholar 

  • Guo Zhigang, Lin Tian, Zhang Gan, et al. 2007. The sedimentary fluxes of polycyclic aromatic hydrocarbons in the Yangtze River Estuary coastal sea for the past century. Science of The Total Environment, 386: 33–41

    Article  Google Scholar 

  • Hao Yunchao, Guo Zhigang, Yang Zuosheng, et al. 2008. Tracking historical lead pollution in the coastal area adjacent to the Yangtze River Estuary using lead isotopic compositions. Environmental Pollution, 156: 1325–1331

    Article  Google Scholar 

  • Hu Bangqi. 2010. Sediment Provenance Diserimination and Paleoenvironment Records in the Mud Area of East China Seas since the Holoeene [dissertation]. Qingdao: Ocean University of China, China

    Google Scholar 

  • Hu Bangqi, Yang Zuosheng, Wang Houjie, et al. 2009. Sedimentation in the Three Gorges Dam and the future trend of Changjiang (Yangtze River) sediment flux to the sea. Hydrology and Earth System Sciences, 13: 2253–2264

    Article  Google Scholar 

  • Huh C A, Su C C. 1999. Sedimentation dynamics in the East China Sea elucidated from 210Pb, 137Cs and 239,240Pu. Marine Geology, 160: 183–196

    Article  Google Scholar 

  • Ip C C M, Li Xiangdong, Zhang Gan, et al. 2007. Trace metal distribution in sediments of the Pearl River Estuary and the surrounding coastal area, South China. Environmental Pollution, 147: 311–323

    Article  Google Scholar 

  • Kelderman P, Osman A A. 2007. Effect of redox potential on heavy metal binding forms in polluted canal sediments in Delft (The Netherlands). Water Research, 41: 4251–4261

    Article  Google Scholar 

  • Li Xiangdong, Shen Zhenguo, Wai O W H, et al. 2001. Chemical Forms of Pb, Zn and Cu in the Sediment Profiles of the Pearl River Estuary. Marine Pollution Bulletin, 42: 215–223

    Article  Google Scholar 

  • Ligero R A, Barrera M, Casas-Ruiz M, et al. 2002. Dating of marine sediments and time evolution of heavy metal concentrations in the Bay of Cádiz, Spain. Environmental Pollution, 118: 97–108

    Article  Google Scholar 

  • Lima A, Eglinton T, Reddy C. 2003. High-resolution record of pyrogenic polycyclic aromatic hydrocarbon deposition during the 20th century. Environ Sci Technol, 37: 53–61

    Article  Google Scholar 

  • Lin S, Hsieh I J, Huang K M, et al. 2002. Influence of the Yangtze River and grain size on the spatial variations of heavy metals and organic carbon in the East China Sea continental shelf sediments. Chemical Geology, 182: 377–394

    Article  Google Scholar 

  • Lin F J, Hsu S C, Jeng W L. 2000. Lead in the southern East China Sea. Marine Environmental Research, 49: 329–342

    Article  Google Scholar 

  • Liu Jingpu, Li Anchun, Xu Kehui, et al. 2006. Sedimentary features of the Yangtze River-derived alongshelf clinoform deposit in the East China Sea. Continental Shelf Research, 26: 2141–2156

    Article  Google Scholar 

  • Liu Jingpu, Xu Kehui, Li Anchun, et al. 2007. Flux and fate of Yangtze River sediment delivered to the East China Sea. Geomorphology, 85: 208–224

    Article  Google Scholar 

  • Milliman J D, Shen Huangting, Yang Zuosheng, et al. 1985. Transport and deposition of river sediment in the Changjiang estuary and adjacent continental shelf. Continental Shelf Research, 4: 37–45

    Article  Google Scholar 

  • Muller G. 1969. Index of geoaccumulation in sediments of the Rhine River. Geojournal, 2: 108–118

    Google Scholar 

  • Murakami M, Fujita M, Furumai H, et al. 2009. Sorption behavior of heavy metal species by soakaway sediment receiving urban road runoff from residential and heavily trafficked areas. Journal of Hazardous Materials, 164: 707–712

    Article  Google Scholar 

  • Niggemann J, Ferdelman T G, Lomstein B A, et al. 2007. How depositional conditions control input, composition, and degradation of organic matter in sediments from the Chilean coastal upwelling region. Geochimica et Cosmochimica Acta, 71: 1513–1527

    Article  Google Scholar 

  • Saito Y, Yang Zuosheng, Hori K. 2001. The Huanghe (Yellow River) and Changjiang (Yangtze River) deltas: a review on their characteristics, evolution and sediment discharge during the Holocene. Geomorphology, 41: 219–231

    Article  Google Scholar 

  • State Oceanic Administration People’s Republic of China. 2008. Bulletin of Chinese marine environment quality in 2000–2008. http://www.soa.gov.cn/hyjww/hygb

  • Taylor S R. 1964. Abundance of chemical elements in the continental crust: a new table. Geochimica et Cosmochimica Acta, 28: 1273–1285

    Article  Google Scholar 

  • Tessier A, Campbell P, Bisson M. 1979. Sequential extraction procedure for the speciation of particulate trace metals. Analytical Chemistry, 51: 844–851

    Article  Google Scholar 

  • Wang Houjie, Yang Zuosheng, Wang Yan, et al. 2008. Reconstruction of sediment flux from the Changjiang (Yangtze River) to the sea since the 1860s. Journal of Hydrology, 349: 318–332

    Article  Google Scholar 

  • Wang Yonghong, Yu Zhigang, Li Guangxue, et al. 2009. Discrimination in magnetic properties of differentsized sediments from the Changjiang and Huanghe Estuaries of China and its implication for provenance of sediment on the shelf. Marine Geology, 260: 121–129

    Article  Google Scholar 

  • Wen Xianghua, Allen H E. 1999. Mobilization of heavy metals from Le An River sediment. The Science of The Total Environment, 227: 101–108

    Article  Google Scholar 

  • Yang Shouye, Wang Zhongbo, Guo Yun, et al. 2009. Heavy mineral compositions of the Changjiang (Yangtze River) sediments and their provenancetracing implication. Journal of Asian Earth Sciences, 35: 56–65

    Article  Google Scholar 

  • Yang Shilun, Belkin I M, Belkina A I, et al. 2003. Delta response to decline in sediment supply from the Yangtze River: evidence of the recent four decades and expectations for the next half-century. Estuarine, Coastal and Shelf Science, 57: 689–699

    Article  Google Scholar 

  • Yao Qingzhen, Zhang Jing, Wu Ying, et al. 2007. Hydrochemical processes controlling arsenic and selenium in the Changjiang River (Yangtze River) system. Science of The Total Environment, 377: 93–104

    Article  Google Scholar 

  • Yuan Dongliang, Hsueh Y. 2010. Dynamics of the cross-shelf circulation in the Yellow and East China Seas in winter. Deep Sea Research Part II: Topical Studies in Oceanography, 57(19–20): 1745–1761

    Article  Google Scholar 

  • Zabel M, Schneider R R, Wagner T, et al. 2001. Late Quaternary climate changes in central Africa as inferred from terrigenous input to the Niger Fan. Quaternary Research, 56: 207–217

    Article  Google Scholar 

  • Zhai Shikui, Meng Wei, Yu Zhigang. 2008. Changjiang Estuarine Environment after the Phase-I Storage of the Three Gorges Project. Beijing: Science Press

    Google Scholar 

  • Zhang Jing. 1999. Heavy metal compositions of suspended sediments in the Changjiang (Yangtze River) estuary: significance of riverine transport to the ocean. Continental Shelf Research, 19: 1521–1543

    Article  Google Scholar 

  • Zhang Weiguo, Feng Huan, Chang Jinna, et al. 2009. Heavy metal contamination in surface sediments of Yangtze River intertidal zone: An assessment from different indexes. Environmental Pollution, 157: 1533–1543

    Article  Google Scholar 

  • Zhang Jing, Liu Changling. 2002. Riverine composition and estuarine geochemistry of particulate metals in China-weathering features, anthropogenic impact and chemical fluxes. Estuarine, Coastal and Shelf Science, 54: 1051–1070

    Article  Google Scholar 

  • Zhang Jing, Wu Ying, Jennerjahn T C, et al. 2007. Distribution of organic matter in the Changjiang (Yangtze River) Estuary and their stable carbon and nitrogen isotopic ratios: Implications for source discrimination and sedimentary dynamics. Marine Chemistry, 106: 111–126

    Article  Google Scholar 

  • Zhang Huaijing, Zhai Shikui, Fan Dejiang, et al. 2007. Distribution of suspended matter concentration in the Changjiang estuary and adjacent area after the First-Stage storage of the Three Gorges Project. Environmental Science, 28(8): 1665–1661

    Google Scholar 

  • Zhao Yiyang, Yan Mingcai. 1994. Geochemistry of Sediments of the China Shelf Sea. Beijing: Science Press

    Google Scholar 

  • Zhou Huaiyang, Peng Xiaotong, Pan Jianming. 2004. Distribution, source and enrichment of some chemical elements in sediments of the Pearl River Estuary, China. Continental Shelf Research, 24: 1857–1875

    Article  Google Scholar 

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Correspondence to Shikui Zhai.

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Foundation item: The National Natural Science Foundation of China under contract No. 41076022; the National Basic Research Program of China under contract No. 2002CB412400.

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Dong, A., Zhai, S., Zabel, M. et al. Heavy metals in Changjiang estuarine and offshore sediments: responding to human activities. Acta Oceanol. Sin. 31, 88–101 (2012). https://doi.org/10.1007/s13131-012-0195-y

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  • DOI: https://doi.org/10.1007/s13131-012-0195-y

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