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A Structurally Precise Ag(I) Complex Bulk-Modified Carbon Paste Electrode for Effective H2O2-Sensing

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Abstract

A bulk-modified carbon paste electrode (Ag-CPE) containing a new structurally precise Ag(I) complex, [Ag2(H2bbimb)2](pts)2 (H2bbimb = 1,3-Bis(2-benzimidazolyl)benzene, pts = p-toluenesulfonate), has been constructed and its hydrogen peroxide sensing performance was researched. The crystal structure analysis reveals that the Ag(I) complex is a dual-core cluster. The H2O2-sensing ability of Ag-CPE was studied by cyclic voltammetry and chronoamperometry method. Ag-CPE was found to lead to a linear response from 0.5 μM to 4.0 mM with a detection limit of 0.45 μM, and has been verified to have excellent stability and good anti-interference ability. The results indicate that Ag-CPE is an efficient H2O2 sensor.

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Funding

The present research was supported by the Foundation of A Hundred Youth Talents Training Program of Lanzhou Jiaotong University (grant no. 152022).

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  1. School of Chemistry and Chemical Engineering, Lanzhou Jiaotong University, Lanzhou, Gansu, 730070, People’s Republic of China

    Huilu Wu, Fugang Sun, Jianping Dong, Geng Zhang, Ruixue Li & Yuxuan Jiang

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  1. Huilu Wu
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Wu, H., Sun, F., Dong, J. et al. A Structurally Precise Ag(I) Complex Bulk-Modified Carbon Paste Electrode for Effective H2O2-Sensing. Electrocatalysis 13, 378–385 (2022). https://doi.org/10.1007/s12678-022-00727-5

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