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Morphological, Opto-Electrochemical, and Sensing Proprieties of a Mixed Isopolymolybdate [Eu(dmso)8][Eu(η2-NO3)2(dmso)4(α-Mo8O26)0.5][Mo6O19] for Sulfaguanidine Detection

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Abstract

Environmental pollution and human health problems, caused by antibiotics abuse, require detection techniques development. The present review presents a photoelectrochemical impedimetric sensor for sulfaguanidine (Sg) determination. The recognition component is a mixed isopolymolybdate [Eu(dmso)8][Eu(η2-NO3)2(dmso)4(α-Mo8O26)0.5][Mo6O19] (I). The proposed sensor was constructed by ITO surface functionalization by polymeric thin film of poly(allylamine hydrochloride (PAH) and subsequently coated using (I). Scanning electron microscopy (SEM) and contact angle (CA) characterizations greatly confirm the successful immobilization of the sensing thin film. The electrochemical sensor has been able to detect Sg in the range from 10−11 to 10−5 M. In darkness, it has showed dynamic linear range from 10−11 to 10−7 M with a calculated limit of detection (LOD) was 1.1 × 10−12 M. By applying photonic excitation, it has presented a wider linear photoelectrochemical response to Sg ranging from 10−11 to 10−5 M with a reduced LOD of 1.2 × 10−13 M. It is gratifying that interferences with different and similar structure have had no significant interference on Sg determination. Furthermore, it has exhibited excellent regeneration (RSD = 2.2%, n = 6), repeatability (RSD = 3.8%, n = 6) as well as high reproducibility (RSD = 1.9%, n = 6).

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Authors and Affiliations

  1. Laboratory of Interfaces and Advanced Materials (LIMA), Faculty of Sciences of Monastir, University of Monastir, 5019, Monastir, Tunisia

    D. Najlaoui & A. Rouis

  2. NANOMISENE Lab, LR16CRMN01, Center for Research On Microelectronics and Nanotechnology CRMN of Technopark of Sousse, B.P. 334, Sahloul, 4034, Sousse, Tunisia

    M. Echabaane

  3. Department of Chemistry, University College at al Khafji, University of Hafr al Batin, al Khafji, 39256, Saudi Arabia

    A. Ben Khelifa

Authors
  1. D. Najlaoui
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  3. A. Ben Khelifa
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  4. A. Rouis
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Correspondence to D. Najlaoui.

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Najlaoui, D., Echabaane, M., Khelifa, A.B. et al. Morphological, Opto-Electrochemical, and Sensing Proprieties of a Mixed Isopolymolybdate [Eu(dmso)8][Eu(η2-NO3)2(dmso)4(α-Mo8O26)0.5][Mo6O19] for Sulfaguanidine Detection. Electrocatalysis 13, 502–510 (2022). https://doi.org/10.1007/s12678-022-00723-9

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