Abstract
Ordered intermetallic compounds of Pt-based metal electrocatalysts have been recently proposed as very efficient anode materials for reactions involved in low temperature fuel cells. In this work, supported ordered intermetallics nanoparticles PtSn/C and PtSb/C and supported platinum nanoparticles (Pt/C) were prepared at low temperature from their metallic precursors by a modified polyol process, using tetraethylene glycol as the solvent and reducing agent and Vulcan carbon XC-72 as the support. Powder X-ray diffraction patterns confirmed the presence of the ordered intermetallic phase and furnished lattice parameters and crystal structure. Transmission electron microscopy images show that the metal particles were highly dispersed and distributed homogeneously over the support, and energy-dispersive X-ray spectroscopy showed that the composition of the final product is within that of the desired stoichiometry. The electrocatalytic activity of these intermetallic phases toward the oxidation of methanol, ethanol, and ethylene glycol were confirmed by cyclic voltammetry and steady-state polarization curve at room temperature. The results showed that the supported intermetallic nanoparticles PtSn and PtSb are more active than the Pt/C catalyst prepared by the same method for alcohol oxidation.
Similar content being viewed by others
References
Gonzalez ER (2000) Quim Nova 23:262–266
Wendt H, Götz M, Linardi M (2000) Quim Nova 23:538–546
Li H, Sun G, Cao L, Jiang L, Xin Q (2007) Electrochim Acta 52:6622–6629
Gleiter H (1995) Nanostruct Mater 6:3–14
Campelo JM, Luna D, Luque R, Marinas JM, Romero AA (2009) ChemSusChem 2:18–45
Sauthoff G (2000) Intermetallics 8:1101–1109
Cahn RW (2001) Contemp Phys 42:365–375
Zhang L, Xia D (2006) Appl Surf Sci 252:2191–2194
Casado-Rivera E, Volpe DJ, Alden L, Lind C, Downie C, Vázquez-Alvarez T, Ângelo ACD, DiSalvo FJ, Abruña HD (2004) J Am Chem Soc 126:4043–4049
Casado-Rivera E, Gál Z, Ângelo ACD, Lind C, DiSalvo FJ, Abruña HD (2003) Chem Phys Chem 4:193
Blasini DR, Rochefort D, Fachini E, Alden RL, Disalvo FJ, Cabrera CR, Abruña HD (2006) Surf Sci 600:2670–2680
Pinto LCM, Silva ER, Caram R, Tremiliosi-Filho G, Ângelo ACD (2008) Intermetallics 16:246–254
Innocente AF, Ângelo ACD (2006) J Power Sources 162:151–159
Innocente AF, Ângelo ACD (2008) J Power Sources 175:779–783
Bauer JC, Chen X, Liu Q, Phan T-H, Schaak RE (2008) J Mater Chem 18:275–282
Fievet F, Lagier JP, Blin B, Beaudoin B, Figarez M (1989) Solid State Ionics 198:32–33
Joseyphus RJ, Matsumoto T, Takahashi H, Kodama D, Tohji K, Jeyadevan B (2007) J Solid State Chem 180:3008
Roychowdhury C, Matsumoto F, Mutolo PF, Abruña HD, DiSalvo FJ (2005) Chem Mater 17:5871–5876
Cable RE, Schaak RE (2005) Chem Mater 17:6835–6841
Sra AK, Schaak RE (2004) J Am Chem Soc 126:6667–6672
Cable RE, Schaak RE (2006) J Am Chem Soc 128:9588–9589
Henderson NL, Schaak RE (2008) Chem Mater 20:3212–3217
Watanabe M, Uchida M, Motoo S (1987) J Electroanal Chem 229:395–406
Liu Z, Guo B, Hong L, Lim TH (2006) Electrochem Commun 8:83–90
Neto AO, Dias RR, Tusi MM, Linardi M, Spinacé EV (2007) J Power Sources 166:87–91
Guo Y, Zheng Y, Huang M (2008) Electrochim Acta 53:3102–3108
Colmati F, Antolini E, Gonzalez ER (2005) Electrochim Acta 50:5496–5503
Cullity BD, Stock SR (2001) Elements of X-Ray Diffraction, 3rd edn. Prentice Hall, Upper Saddle River
Spinacé EV, Linardi M, Neto AO (2005) Electrochem Commun 7:365
Perez J, Gonzalez ER, Ticianelli EA (1998) Electrochim Acta 44:1329
Ralph TR, Hogarth MP (2002) Platinum Metals Rev 46:3–14
Gurau B, Viswanathan R, Liu R, Lafrenz TJ, Ley KL, Smotkin ES, Reddington E, Sapienza A, Chan BC, Mallouk TE, Sarangapani S (1998) J Phys Chem B 102:9997
Iwasita T (2002) Electrochim Acta 47:3663–3674
Manohara R, Goodenough JB (1992) J Mater Chem 2:875
Oliveira RTS, Santos MC, Marcussi BG, Nascente PAP, Bulhões LOS, Pereira EC (2005) J Electroanal Chem 575:177–182
Chen S, Schell M (1999) J Electroanal Chem 478:108–117
Lemos SG, Oliveira RTS, Santos MC, Nascente PAP, Bulhões LOS, Pereira EC (2007) J Power Sources 163:695–701
Xia XH, Liess HD, Iwasita T (1997) J Electroanal Chem 437:233–240
Iwasita T, Pastor EA (1994) Electrochim Acta 39:531–537
Camara GA, Iwasita T (2005) J Electroanal Chem 578:315–321
Kelaidopoulou A, Abelidou E, Papoutsis A, Polychroniadis EK, Kokkinidis G (1998) J Appl Electrochem 28:1101–1106
Wang H, Jusys Z, Behm RJ (2009) Electrochim Acta 54:6484–6498
Chatterjee M, Chatterjee A, Ghosh S, Basumallick I (2009) Electrochim Acta 54:7299–7304
Salvaraj V, Vinoba M, Alagar M (2008) J Colloid Interface Sci 322:537–544
de los Santos-Álvarez N, Alden LR, Rus E, Wang H, DiSalvo FJ, Abruña HD (2009) J Electroanal Chem 626:14–22
Lopes PP, Ticianelli EA (2007) Quim Nova 30:1256–1260
Acknowledgments
Authors thank FINEP (Proc. 01.06.0939.00) for financial support, and M. R. Silva would like to thank Finep/CNPQ for the scholarship granted (Proc. 380318/2007-5).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Rodrigues da Silva, M., Ângelo, A.C.D. Synthesis and Characterization of Ordered Intermetallic Nanostructured PtSn/C and PtSb/C and Evaluation as Electrodes for Alcohol Oxidation. Electrocatal 1, 95–103 (2010). https://doi.org/10.1007/s12678-010-0010-5
Published:
Issue Date:
DOI: https://doi.org/10.1007/s12678-010-0010-5