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Facile Synthesis of CeO2 Nanosheets via a Parallel Flow Precipitation Route

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Abstract

In this work, CeO2 nanosheet was facile synthesized via a parallel flow precipitation route, using cerium chloride trihydrate and sodium carbonate as the cerium source, without using any surfactants and templates. The results show that the CeO2 nanosheets have a median particle size (D50) of 118 nm, a range (R) of 0.69, a surface area of 3.01 m2/g, a pore diameter of 27.96 nm, a pore volume of 0.02 cm3/g, and a loss on ignition (L.O.I.) of < 1%. Furthermore, the activation energy of CeO2 nanocrystal growth during the calcination process is about 30.5 kJ/mol, indicating that the controlling link of the crystallite growth is the interfacial chemical reaction. Ostwald ripening (OR) mechanism has a synergistic effect with Oriented attachment (OA) mechanism during the process of nucleation and growth of Ce2(CO3)3 crystal grains.

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Acknowledgements

Financial support from the following programs is gratefully acknowledged: National Natural Science Foundation of China (Grant No. 52264051) and Yunnan Ten Thousand Talents Plan Young & Elite Talents Project (Grant No. YNWR-QNBJ-2018-323).

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Authors and Affiliations

  1. Faculty of Metallurgical and Energy Engineering, Kunming University of Science and Technology, Kunming, 650093, Yunnan, China

    Jianfeng Ran, Jiashu Yao, Shaohua Yin & Libo Zhang

  2. State Key Laboratory of Complex Nonferrous Metal Resources Clean Utilization, Kunming University of Science and Technology, Kunming, 650093, Yunnan, China

    Jianfeng Ran, Jiashu Yao, Shaohua Yin & Libo Zhang

  3. China Northern Rare Earth (Group) High-Tech Co., Ltd., Baotou, 014010, China

    Tingting Li, Zhanyu Xu & Guoguang Zhang

  4. Guangdong Lyric Robot Intelligent Equipment Co., Ltd, Huizhou, 516000, China

    Peng Lv

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  1. Jianfeng Ran
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Ran, J., Yao, J., Li, T. et al. Facile Synthesis of CeO2 Nanosheets via a Parallel Flow Precipitation Route. Trans Indian Inst Met 76, 1495–1507 (2023). https://doi.org/10.1007/s12666-022-02849-2

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  • DOI: https://doi.org/10.1007/s12666-022-02849-2

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