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High-Temperature Rheological Behavior and Composition Design of Hf-Be-Ti-Zr-Cu-Ni High-Entropy Amorphous Alloy

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Abstract

The glass forming ability, thermal stability and high-temperature rheological behavior of the Hf-Be-Ti-Zr-Cu-Ni high-entropy alloy were studied. The results show that the appropriate Cu/Ni ratio significantly increases the glass forming ability and thermal stability of Hf based high-entropy alloy. When the Cu/Ni ratio is 0.21, the critical size increases from 10 to 18 mm, the supercooled liquid region is 61.15 K. The high-temperature rheological behavior of Hf30Be18Ti16Zr16Cu3.5Ni16.5 amorphous alloy is highly sensitive to strain rate and temperature. And with the decrease of strain rate, the structure of Hf-Be-Ti-Zr-Cu-Ni amorphous alloy changes more obviously at higher temperature, the thermal processing diagram is established, and the results show that the Hf30Be18Ti16Zr16Cu3.5Ni16.5 has good thermoplastic formability at 663–693 K, the strain rate: 5 × 10–4 s−1–1 × 10–3 s−1.

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Acknowledgements

The authors wish to acknowledge the financial support from the China Postdoctoral Science Foundation (2021M702982) and Major special project of scientific and technological innovation 2025 in Ningbo (2019B10086).

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Authors and Affiliations

  1. College of Materials and Chemical Engineering, Xi’an Technological University, Xi’an, 710021, China

    Jinbei Zhao & Bing Li

  2. Ningbo Branch of China Academy of Ordnance Science, Ningbo, 315100, China

    Jinbei Zhao, Weiming Huang, Yongxu Wang, Jilong Han & Xi Wang

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  1. Jinbei Zhao
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  4. Yongxu Wang
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Correspondence to Bing Li.

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Zhao, J., Li, B., Huang, W. et al. High-Temperature Rheological Behavior and Composition Design of Hf-Be-Ti-Zr-Cu-Ni High-Entropy Amorphous Alloy. Trans Indian Inst Met 76, 1165–1174 (2023). https://doi.org/10.1007/s12666-022-02827-8

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