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Structure and Properties of Ti–Zr–Ni–Co–Cu High-Entropy Alloy After Powder Bed Fusion of Powders Produced by Mechanical Alloying and Plasma Spheroidization

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Abstract

In this paper, the Ti25Zr25Ni25Co10Cu15 high entropy alloy has been investigated. A novel approach to manufacture high-temperature shape memory alloys is proposed. A fundamental possibility to obtain compact samples by powder bed fusion using a laser beam (PBF-LB) from Ti25Zr25Ni25Co10Cu15 powder obtained by mechanical alloying and plasma spheroidization is shown. During PBF-LB, a mixed structure is formed. It consists of B2-TiNi-type austenite with Laves phases and zirconium oxides. The average grain size is around 5 μm. The hardness of the alloy produced is more than 600 HV and significantly exceeds that of the alloy produced by conventional techniques. The ultimate compressive strength and the compressive yield strength of the samples are 640 MPa, and 600 MPa, respectively, meaning the synthesized samples are significantly inferior to the alloys produced by conventional smelting technologies. However, the ductility of 1.3% is comparable to that of similar alloys and indicates potential prospects of PBF-LB to manufacture Ti–Zr–Ni–Co–Cu HEAs.

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Acknowledgements

This research was carried out with the support of the State contract # H.4щ.241.09.20.1081 dated June 4, 2020 “Development and material science substantiation of the design of materials and products based on shape memory alloys with a controlled structure and piezoelectric ceramics using additive 4D technologies. Stage of 2020” (IGK 17706413348200001110).

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Authors and Affiliations

  1. Institute of Machinery, Materials and Transport, Peter the Great St. Petersburg Polytechnic University, Polytechnicheskaya, 29, Saint-Petersburg, Russian Federation, 195251

    N. G. Razumov, T. Yu. Makhmutov, A. Kim, N. E. Ozerskoi, A. O. Silin, E. V. Borisov, K. A. Starikov, A. K. Mazeeva & A. A. Popovich

  2. Department of Mechanical Engineering, Politecnico di Milano, Via Privata Giuseppe La Masa 1, 20156, Milan, Italy

    I. S. Goncharov

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  1. N. G. Razumov
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  2. T. Yu. Makhmutov
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  3. A. Kim
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  4. I. S. Goncharov
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  5. N. E. Ozerskoi
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Correspondence to A. K. Mazeeva.

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Razumov, N.G., Makhmutov, T.Y., Kim, A. et al. Structure and Properties of Ti–Zr–Ni–Co–Cu High-Entropy Alloy After Powder Bed Fusion of Powders Produced by Mechanical Alloying and Plasma Spheroidization. Trans Indian Inst Met 75, 2529–2538 (2022). https://doi.org/10.1007/s12666-022-02616-3

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