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Hot Corrosion Behaviour of Refractory and Rare Earth Oxide Reinforced CoCrAlY APS Coatings at 700 °C

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Abstract

This paper investigates cyclic hot corrosion of plasma sprayed CoCrAlY + Al2O3 + YSZ (C1) and CoCrAlY + CeO2 (C2) composite coatings on MDN 321 and Superni 76 substrates in molten salt (Na2SO4-60%V2O5) environment exposed to 700 °C. Weight change technique is used to evaluate the corrosion performance. Both C1 and C2 coatings showed better corrosion resistance than uncoated alloy. Both the coatings showed linear weight gain during the initial cycles and parabolic weight gain nature with subsequent hot corrosion cycles. The parabolic rate constant (Kp) of C1 and C2 coating was observed to be in the range 0.29–0.32 × 10−10 g2 cm−4 s−1 and 1.0–1.13 × 10−10 g2 cm−4 s−1 respectively. In C1 coating, the globular and continuously packed structure on the corroded surface having CoO, Cr2O3, CoCr2O4 and CoAl2O4 spinel oxides provided superior hot corrosion resistance. While in case of C2 coating, the outward growth of CeVO4 irregular crystals as a corrosion product of CeO2 and V2O5 salt deteriorated the oxide scales resulting in higher corrosion rate.

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References

  1. James W, and Rajagopalan S, Structural Alloys for Power Plants, (ed) Shirzadi A, and Jackson S, Woodhead Publishing Series in Energy (2014), p 3.

  2. Becker W T, and Shipley R J, ASM Metals Handbook: Vol. 11. Failure analysis and prevention, ASM Publication (2002), p. 1533.

  3. Gurrappa I, Surf. Coat. Technol. 139 (2001) 272.

    Article  CAS  Google Scholar 

  4. Doolabi D S, Rahimipour M R, Alizadeh M, Pouladi S, Hadavi S M, and Vaezi M R, Vacuum 135 (2017) 22.

    Article  Google Scholar 

  5. Ramesh M R, Prakash S, Nath S K, Sapra P K, and Venkataraman B, Wear 269 (2010) 197.

    Article  CAS  Google Scholar 

  6. Lu J, Zhu S, Wang F, Surf. Coat. Technol. 205 (2011) 5053.

    Article  CAS  Google Scholar 

  7. Cai J, Yang S Z, Ji L, Guan Q F, Wang Z P, and Han Z Y, Surf. Coat. Technol. 251 (2014) 2017.

    Article  Google Scholar 

  8. Utu I D, Marginean G, Hulka I, Serban V A, Cristea D, Int. J. Refract. Met. Hard Mater. 51 (2015) 118.

    Article  CAS  Google Scholar 

  9. Eliaz N, Shemesh G, and Latanision R M, Eng. Fail. Anal. 9 (2002) 31.

    Article  CAS  Google Scholar 

  10. Baiamonte L, Marra F, Gazzola S, Giovanetto P, Bartuli C, Valente T, and Pulci G, Surf. Coat. Technol. 295 (2016) 78.

    Article  CAS  Google Scholar 

  11. Nicholls J. R, Simms N J, Chan W Y and Evans H E, Surf. Coat. Technol. 149 (2002) 236.

    Article  CAS  Google Scholar 

  12. Bolelli G, Candeli A, Lusvarghi L, Ravaux A, Cazes K, Denoirjean A, and Valette S, Wear 344 (2015) 69.

    Article  Google Scholar 

  13. Cabral Miramontes J A, Gaona Tiburcio C, Almeraya Calderón F, Estupiñan Lopez F H, Pedraza Basulto G K, and Poblano Salas C A, Int. J. Corr (2014) 8.

  14. Praveen A S, Sarangan J, Suresh S, and Subramanian J S, Int. J. Refract. Met. Hard Mater. 52 (2015) 209.

    Article  CAS  Google Scholar 

  15. Kim H J, Hwang S Y, Lee C H, and Juvanon P, Surf. Coat. Technol.172 (2003) 262.

    Article  CAS  Google Scholar 

  16. Ogawa K, Ito K, Shoji T, Seo D W, Tezuka H, and Kato H, J. Therm. Spray Technol. 15 (2006) 640.

    Article  CAS  Google Scholar 

  17. Zhou X, and Ouyang C, Surf. Coat. Technol. 315 (2017) 67.

    Article  CAS  Google Scholar 

  18. Wang Y, Yang Y, and Yan M F, Wear 263 (2007) 371.

    Article  CAS  Google Scholar 

  19. Song B, Dong S, Liao H, and Coddet C, Surf. Coat. Technol. 268 (2015) 24.

    Article  CAS  Google Scholar 

  20. He K, Chen J, Weng W, Li C, and Li, Q, Vacuum 151 (2018) 209.

    Article  CAS  Google Scholar 

  21. Xiao J K, Zhang W, Liu L. M, Gan X P, Zhou K C, and Zhang C, Surf. Coat. Technol. 337 (2018) 159.

    Article  CAS  Google Scholar 

  22. Otero E, Merino M C, Pardo A, Biezma M V, and Buitrago G, Proceedings of 10th ICMC 4 (1987) 3583.

  23. Ramesh M R, Prakash S, Nath S K, Sapra P K and Krishnamurthy N, J. Therm. Spray Technol. 20 (2011) 992.

    Article  CAS  Google Scholar 

  24. Somasundaram B, Kadoli R, and Ramesh M R, J. Therm. Spray Technol. 23 (2014) 1000.

    Article  CAS  Google Scholar 

  25. McAlister A J, Alloy Phase Diagram, (ed) Hugh B, United States of America (1989), p 288.

  26. Sampath S, Jiang X Y, Matejicek J, Leger A C, and Vardelle A, Mater. Sci. Eng. A 272 (1999) 181.

    Article  Google Scholar 

  27. Zhu L, Zhu S, and Wang F, Appl. Surf. Sci. 268 (2013) 103.

    Article  CAS  Google Scholar 

  28. Singh H, Kaur M, and Prakash S., J. Therm. Spray Technol. 6 (2016) 1192.

    Article  Google Scholar 

  29. Luthra K L, J. Electrochem. Soc. 132 (1985) 1293

    Article  CAS  Google Scholar 

  30. Zhang T, Huang C, Lan H, Du L, and Zhang W, J. Therm. Spray Technol. 6 (2016) 1208.

    Article  Google Scholar 

  31. Afrasiabi A, Saremi M, and Kobayashi A, Mater. Sci. Eng. A 478 (2008) 264.

    Article  Google Scholar 

  32. Jones R L, Williams C E and Jones A J, J. Electrochem. Soc. 133 (1986) 227.

    Article  CAS  Google Scholar 

  33. Nejati M, Rahimipour M R, and Mobasherpou I, Ceram. Int. 40 (2014) 4579.

    Article  CAS  Google Scholar 

  34. Ahmadi-Pidani R, Shoja-Razavi R, Mozafarinia R, and Jamali H, Mater. Des. 57 (2014) 336.

    Article  CAS  Google Scholar 

  35. Afrasiab A, and Kobayashi A, Vacuum 88 (2013) 103.

    Article  Google Scholar 

  36. Nithin H S, Desai V, and Ramesh M R, J. Mater. Eng. Perform. 26 (2017) 5251.

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. National Institute of Technology Karnataka, Surathkal, Mangalore, India

    H. S. Nithin, V. Desai & M. R. Ramesh

  2. REVA University Bengaluru, Bengaluru, India

    H. S. Nithin

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  1. H. S. Nithin
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  2. V. Desai
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  3. M. R. Ramesh
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Nithin, H.S., Desai, V. & Ramesh, M.R. Hot Corrosion Behaviour of Refractory and Rare Earth Oxide Reinforced CoCrAlY APS Coatings at 700 °C. Trans Indian Inst Met 71, 2403–2413 (2018). https://doi.org/10.1007/s12666-018-1371-3

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