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Comparative Study of Corrosion Inhibition on Mild Steel in HCl Medium by Three Green Compounds: Argania spinosa Press Cake, Kernels and Hulls Extracts

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Abstract

Argania spinosa press cake, kernels and hulls extracts are excellent corrosion inhibitors for steel. In this work electrochemical methods are used to study the inhibition of corrosion on steel in 1 M HCl. It has shown that Argan press cake, kernels and hulls extracts suppress both the anodic and cathodic process and they behave as mixed-type inhibitors. The inhibition efficiency was found to increase with inhibitors content. Data obtained from EIS measurements, were analyzed to model the corrosion inhibition process through appropriate equivalent circuit model; a constant phase element has been used. The values of the inhibition efficiency calculated from these techniques are in reasonably good agreement. The adsorption isotherm of natural compounds on the steel surface was found to obey Langmuir’s adsorption isotherm.

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References

  1. Zarrok H, Oudda H, Zarrouk A, Salghi R, Hammouti B and Bouachrine M, Der Pharma Chemica 3 (6) (2011) 576.

    CAS  Google Scholar 

  2. El Issami S, Bazzi L, Mihit M, Hammouti B, Kertit S, Ait Addi E, and Salghi R, Pigment Resin Technol 36 (3) (2007) 161.

    Article  Google Scholar 

  3. Barouni K, Bazzi L, Salghi R, Mihit M, Hammouti B, Albourine A, and El Issami S, Mater Lett 62 (2008) 3325.

    Article  CAS  Google Scholar 

  4. El Issami S, Bazzi L, Hilali M, Salghi R and Kertit S, Ann Chim Sci Mat 27 (2002) 63.

    Article  Google Scholar 

  5. Mihit M, El Issami S, Bouklah M, Bazzi L, Hammouti B, Ait Addi E, Salghi R, and Kertit S, Applied Suf Sci 252 (2006) 2389.

    Article  CAS  Google Scholar 

  6. Hammouti B, Salghi R, and Kertit S, J Electrochem Soc India 47 (1998) 31.

    CAS  Google Scholar 

  7. El Issami S, Bazzi L, Mihit M, Hilali M, Salghi R, and Ait Addi E, J Phys IV 123 (2005) 307.

    Google Scholar 

  8. Olusegun K, Abiola A O, and James A, Corros Sci 52 (2010) 661.

    Article  Google Scholar 

  9. Abiola O K, Otaigbe J O E, and Kio O J, Corros Sci 51 (2009) 1879.

    Article  CAS  Google Scholar 

  10. Abiola O K, and Oforka N C, Scientia Africana 2 (2003) 82.

    Google Scholar 

  11. El-Etre A Y, Abdallah M, and El-Tantawy Z E, Corros Sci 47 (2005) 385.

    Article  CAS  Google Scholar 

  12. Valek L, and Martinez S, Mater Lett 61 (2007) 148.

    Article  CAS  Google Scholar 

  13. Znini M, Majidi L, Bouyanzer A, Paolini J, Desjobert J M, Costa J, and Hammouti B, Arabian J Chem 2010. http://www.sciencedirect.com/science/journal/18785352.

  14. El-Etre A Y, J Colloid Interface Sci 314 (2007) 578.

    Article  CAS  Google Scholar 

  15. Bouyanzer A, Hammouti B, and Majidi L, Mater Lett 60 (2006) 2840.

    Article  CAS  Google Scholar 

  16. Afia L, Salghi R, Bammou L, Bazzi L h, Hammoutin B, Bazzi L, and Bouyanzer A, J Saudi Chem Soc 2011. http://www.sciencedirect.com/science/journal/13196103.

  17. Afia L, Salghi R, Bammou L, Bazzi L h, Hammouti B, and Bazzi L, Acta Metalurgica Sinica 25(1) (2012) 10.

  18. Afia L, Salghi R, Bazzi E l, Bazzi L, Errami M, Jbara O, Al-Deyab S S, and Hammouti B, Int J Electrochem Sci 6 (2011) 5918.

    CAS  Google Scholar 

  19. Afia L, Salghi R, Bazzi E l, Zarrouk A, Hammouti B, Bouri M, Zarrouk H, Bazzi L, Bammou L, Research on Chemical Intermediates (in press).

  20. Ostovari A, Hoseinieh S M, Peikari M, Shadizadeh S R, and Hashemi S J, Corros Sci 51 (2009) 193521.

    Article  Google Scholar 

  21. Bouyanzer A, Majidi L, and Hammouti B, Bull Electrochem 22 (2006) 321.

    CAS  Google Scholar 

  22. Chetouani A, Hammouti B, and Benkaddourm M, Pigment Resin Technol 33 (2004) 26.

    Article  CAS  Google Scholar 

  23. Bendahou M, Benabdellah M, and Hammouti B, Pigment Resin Technol, 35 (2006) 95.

    Article  CAS  Google Scholar 

  24. Chaieb E, Bouyanzer A, Hammouti B, Benkaddour M, and Berrabah M, Trans SAEST 39 (2004) 58.

    CAS  Google Scholar 

  25. El-Ouariachi E, Paolini J, Bouklah M, Elidrissi A, Bouyanzer A, Hammouti B, Desjobert J.M, and Costa J, Acta Metall Sin 23 (2010) 13.

    CAS  Google Scholar 

  26. Ouachikh O, Bouyanzer A, Bouklah M, Desjobert J M, Costa J, Hammouti B, and Majidi L, Surf Rev Lett 16 (2009) 49.

    Article  CAS  Google Scholar 

  27. Benabdellah M, Benkaddour M, Hammouti B, Bendahou M, Aouiti A, Appl Surf Sci 252 (2006) 6212.

    Article  CAS  Google Scholar 

  28. Bouyanzer A, and Hammouti B, Pigment Resin Technol 33 (2004) 287.

    Article  CAS  Google Scholar 

  29. Zerga B, Sfaira M, Rais Z, Ebn Touhami M, Taleb M, Hammouti B, Imelouane B, and Elbachiri A, Mater Tech 97 (2009) 297.

    Article  CAS  Google Scholar 

  30. Faska Z, Majidi L, Fihi R, Bouyanzer A, and Hamouti B, Pigment Resin Technol 36 (2007) 293.

    Article  CAS  Google Scholar 

  31. Chaieb E, Bouyanzer A, Hammouti B, and Benkaddour M, Appl Surf Sci 246 (2005) 199.

    Article  CAS  Google Scholar 

  32. Faska Z, Bellioua A, Bouklah M, Majidi L, Fihi R, Bouyanzer A, and Hammouti B, Monatsh Chem 139 (2008) 1417.

    Article  CAS  Google Scholar 

  33. Khallouki F, Spiegelhalder B, Bartsch H, and Owen R W, Afr J Biotechnol 4 (2005) 381.

    CAS  Google Scholar 

  34. Henry F, Danoux L, Pauly G, and Charrouf Z, Patent EP 1430900 (2004).

  35. El-Etre A Y, Mater Chem Phys 108 (2008) 278.

    Article  CAS  Google Scholar 

  36. Bammou L, Mihit M, Salghi R, Bazzi L, Bouyanzer A, and Hammouti B, Int J Electrochem Sci 6 (2011) 1454.

    CAS  Google Scholar 

  37. Tsuru T, Haruyama S, and Gijutsu B, J Jpn Soc Corros Eng 27 (1978) 573.

    CAS  Google Scholar 

  38. Dahmani M, Et-Touhami A, Al-Deyab S S, Hammouti B, and Bouyanzer A, Int J Electrochem Sci 5 (2010) 1060.

    CAS  Google Scholar 

  39. Shih H, and Mansfeld H, Corros Sci 29 (1989) 1235.

    Article  CAS  Google Scholar 

  40. Martinez S, and Metikos-Hukovic M, J Appl Electrochem 33 (2003) 1137.

    Article  CAS  Google Scholar 

  41. Macdonald J R, Impedance, A Wiley-Interscience Publication ,New York(1987).

    Google Scholar 

  42. McCafferty E, Corros Sci 39 (1997) 243.

    Article  CAS  Google Scholar 

  43. Morad M S, Corros Sci 42 (2000) 1313.

    Article  Google Scholar 

  44. Chaieb E L, Bouyanzer A, Hammouti B, and Benkaddour M, Appl Surf Sci 249 (2005) 183.

    Article  Google Scholar 

  45. Langmuir I, J Amer Chem Soc 39 (1947) 1848.

    Article  Google Scholar 

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Correspondence to Rachid Salghi.

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Afia, L., Salghi, R., Zarrouk, A. et al. Comparative Study of Corrosion Inhibition on Mild Steel in HCl Medium by Three Green Compounds: Argania spinosa Press Cake, Kernels and Hulls Extracts. Trans Indian Inst Met 66, 43–49 (2013). https://doi.org/10.1007/s12666-012-0168-z

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