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Spray deposited Nb2O5 thin film electrodes for fabrication of dye sensitized solar cells

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Abstract

Nb2O5 thin film electrodes have been deposited on indium tin oxide substrates by spray pyrolysis technique. XRD analysis reveals tetragonal phase of the film. Reticulated micro-fibrous surface morphology has been observed by scanning electron microscopy and atomic force microscopy indicates closely packed crystallites. Film thickness found using a stylus profilometer is around 26 nm. Transmittance spectra show the film to be 70–80% transparent in the visible region. Direct, indirect band gap and phonon energy are also estimated. Cyclic voltammetry measurement indicate distinct anodic peak during negative potential of the scan due to Li extraction. A reversible colour change from transparent to grey has been observed. The photo-electrochemical characteristic of the dye sensitized solar cell is studied by recording the I-V characteristics of the unsealed type cell under illumination of 40 mW/cm2 using a solar simulator.

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References

  1. Mujawar S H, Inamdar A I, Betty C A, Ganesan V and Patil P S, Electrochim. Acta, 52 (2007) 4899.

    Article  CAS  Google Scholar 

  2. Jung S C, Imashi N and Park H C, J. Appl. Phys. 34 (1995) p L775.

    Google Scholar 

  3. Roberts G L, Cava R J, Peek W F and Krajewski J J, J. Mater. Res. 12 (1997) 526.

    Article  CAS  Google Scholar 

  4. Duffy M T, Wang C C, Waxman A and Zaininger K H, J. Electrochem. Soc. 116 (1969) 234.

    Article  CAS  Google Scholar 

  5. Rosenfeld C. Sanjines R, Levy F, Buffat B A, Demarne V and Grisel A, J. Vac. Sci. Technol A, 12 (1994) 135.

    Article  CAS  Google Scholar 

  6. Ponzi M, Duschatzky C, Carrascull A and Ponzi E, Appl. Catal, A, 169 (1998) 373.

    Article  CAS  Google Scholar 

  7. Kumagai N, Tateshita Y, Takatsuka Y, Baba M, Ikeda T and Tanno K, J. Power Sources, 54 (1995) 175.

    Article  CAS  Google Scholar 

  8. Nakazawa H, Kimihiro S, Takashi A, Baba M and Kumagai N, J. Power Sources, 174 (2007) 838.

    Article  CAS  Google Scholar 

  9. Aegerter M A, Solar Energy Mater. and Solar Cells, 68 (2001) 401.

    Article  CAS  Google Scholar 

  10. Fachun Lai, Limei Lin, Zhigao Huang, Rongquan Gai and Yan Qu, Appl. Surf. Sci 253 (2006) 180.

    Article  Google Scholar 

  11. Xiaofeng Zhou, Zhengcao Li, Yuquan Wang, Xing Sheng and Zhengjun Zhang, Thin Solid Films, 516 (2008) 4213.

    Article  CAS  Google Scholar 

  12. Dyer C K and Leach J S L, J. Electrochem Soc, 125 (1978) 23.

    Article  CAS  Google Scholar 

  13. Yinsong Huang, Yuzhi Zhang and Xingfang Hu, Sol. Energy Mat. and Sol. Cells, 77 (2003) 155.

    Article  CAS  Google Scholar 

  14. Yao J N, Loo B H, Hashimoto K, Fujishima A and Ber Bunsenges, Phys Chem, 96 (1992) 699.

    CAS  Google Scholar 

  15. Rosario A V and Pereira E C, Sol. Energy Mat. and Sol. Cells 71 (2002) 41.

    Article  CAS  Google Scholar 

  16. Bueno P R, Avellaneda C O, Faria R C and Bulhoes L O S, Electrochim. Acta, 46 (2001) 2113.

    Article  CAS  Google Scholar 

  17. Romero R, Calchiele E A, Martin F, Leinen D and Ramos-Barrado J R, Sol. Energy Mat. and Sol. Cells, 93 (2009) 222.

    Article  CAS  Google Scholar 

  18. Mujawar S H, Inamdar A I, Patil S B and Patil P S, Solid State Ionics, 177 (2006) 3333.

    Article  CAS  Google Scholar 

  19. Ozer N, Din-Guo Chen and Lampert C M, Thin Solid Films, 277 (1996) 162.

    Article  Google Scholar 

  20. Rosario A V and Pereira E C, Electochimica Acta, 46 (2001) 1905.

    Article  CAS  Google Scholar 

  21. Fachun Lai, Ming Li, Haiqian Wang, Hailong Hu, Xiaoping Wang, Hou J G, Yizhou Song and Yousong Jiang, Thin Solid Films, 488 (2005) 314.

    Article  CAS  Google Scholar 

  22. Pawalicka A, Atik M and Aegerter M A, Thin Solid Films, 301 (1997) 236.

    Article  Google Scholar 

  23. Avellaneda C O, Pawalicka A, and Aegerter M A, J. Mat. Sci, 33 (1998) 2181.

    Article  CAS  Google Scholar 

  24. Toshiro Maruyama and Susumu Arai, Appl. Phys. Lett. Vol. 63, No. 7, 16 August 1993.

  25. Kamal H, Elmaghraby E K, Ali S A, Abdel-Haddy K, J. Cryst. Growth 262 (2004) 424.

    Article  CAS  Google Scholar 

  26. Regan B O’ and Graetzel M, Nature, 353 (1991) 737.

    Article  Google Scholar 

  27. Nazeeruddin M K, Kay A, Rodicio I, Humphry-Baker R, Muller E, Liska P, Vlachopoulos N, and Graetzel M, J. Am. Chem. Soc., 115 (1993) 6382.

    Article  CAS  Google Scholar 

  28. Sirimanne P M, Shirata T, Soga T, and Jimbo J, Solid. State Chem., 166 (2002) 142.

    Article  CAS  Google Scholar 

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Kovendhan, M., Joseph, D.P., Manimuthu, P. et al. Spray deposited Nb2O5 thin film electrodes for fabrication of dye sensitized solar cells. Trans Indian Inst Met 64, 185 (2011). https://doi.org/10.1007/s12666-011-0036-2

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  • DOI: https://doi.org/10.1007/s12666-011-0036-2

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