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Assessment of shallow groundwater quality for drinking purposes: an integrated approach based on the water quality index and the use of multivariate statistical analyses, southern Brazil

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Abstract

Groundwater plays a strategic role supplying the worldwide demand of water. In Canguçu town, groundwater is used as an alternative source for domestic supply. The present study evaluated urban shallow groundwater quality through the use of water quality indexes and a multivariate statistical approach. The following parameters: thermotolerant coliforms, Escherichia coli, pH, total dissolved solids, calcium, magnesium, potassium, sodium, bicarbonate, chloride, sulfide, and manganese were obtained from four surveys from spring five sampling points during the period 2020–2021. The results were compared with the WHO drinking water guideline limits, then a drinking groundwater quality index DGQI was calculated. The data were evaluated through the use of a stepwise multiple linear regression, and a principal component analysis was carried out. Microbiological results demonstrated that groundwater analyzed is not safe for drinking without disinfection. Physicochemical results indicated that the parameters pH, manganese, and potassium often did not comply with the WHO guideline limits. The DGQI indicated that 55% of the samples were classified as having “good” to “excellent” water quality, 25% had “poor” water quality, 15% had “very poor” water quality, and 5% were considered to be unsuitable for drinking purposes. Stepwise multiple linear regression analysis modeled two equations and identified that sodium, pH, manganese, potassium, and calcium as the variables that contributed most to the DGQI results. Principal component analysis demonstrated the predominance of the ion exchange process in controlling groundwater chemistry in the area. The present study is the first groundwater quality study of shallow groundwater in Canguçu town, Pelotas Batholith, and demonstrated the patterns of groundwater and the urgently necessity of previous treatment of groundwater, as well as the great hazard of drinking untreated water.

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References

  • Abbasi T, Abbasi SA (2012) Water-Quality indices. Elsevier, pp 353–356. https://doi.org/10.1016/B978-0-444-54304-2.00016-6

  • Ameen HA (2019) Spring water quality using water quality index in villages of Bawari, Duhok, Kurdistan Region. Iraq 176:2–12. https://doi.org/10.1007/s13201-019-1080-z

    Article  Google Scholar 

  • ANA (2021) Agência Nacional de Águas e Saneamento Básico. Sub bacias hidrográficas DNAEE. https://dadosabertos.ana.gov.br/datasets/10480692111f443bb5a38d9bb156851f/explore?location=-31.317956%2C-52.176039%2C8.53. Accessed 02 September 2021

  • APHA (2017) Standards methods for the examination of water and wastewater, twenty second ed. American Public Health Association (APHA), American Water Works Association (AWWA) and Water Environment Federation (WEF), New York

  • Bahir M, Ouazar D, Ouhamdouch S (2018) Characterization of mechanisms and processes controlling groundwater salinization in coastal semi-arid area using hydrochemical and isotopic investigations (Essaouira basin, Morocco). Environ Sci Pollut Res 25:24992–25004

    Article  Google Scholar 

  • Barakat A, Meddah R, Afdali M, Touhami F (2018) Physicochemical and microbial assessment of spring water quality for drinking supply in Piedmont of Béni-Mellal Atlas (Morocco). Phys Chem Earth 104:39–46. https://doi.org/10.1016/j.pce.2018.01.006

    Article  Google Scholar 

  • Batabyal KA, Chakraborty S (2015) Hydrogeochemistry and water quality index in the assessment of groundwater for drinking uses. Water Environ Res 87:607–617. https://doi.org/10.2175/106143015X14212658613956

    Article  Google Scholar 

  • Bentes VS, Neto GWA, Meschede MSC (2020) Qualidade da águaa utilizada para consumo humano proveniente do Aquífero Alter do Chão em Santarém (Oeste do Pará) e sua relação com a saúde pública. Geochim Brasil 34:101–109. https://doi.org/10.21715/GB2358-2812.2020341101

  • Bodrud-Doza MD, Islam T, Ahmed FDS, Saha N, Rahman MS (2016) Characterization of groundwater quality using water evaluation indices. multivariate statistics and geostatistics in central of Bangladesh. Water Sci 30:19–40

    Article  Google Scholar 

  • Bortolin TA, Reginato PAR, Leão MI, Schneider VE (2014) Hidrogeologia e hidroquímica dos aquíferos fraturados associados às rochas vulcânicas ácidas do Município de Carlos Barbosa (RS). Ambiente Água 9:56–65. https://doi.org/10.4136/1980-993X

    Article  Google Scholar 

  • Brown RM, McClelland NI, Deininger RA, O’Connor MF (1972) A water quality index—crashing the physiological barrier. Indic Environ Qual, pp 173–182. https://doi.org/10.10007/978-1-4684-2856-8_15

  • Cecconello ST, Centeno LN, Guedes HAS (2018) Índice de qualidade de água modificado pela análise multivariada: estudo de caso do Arroio Pelotas, RS, Brasil. Eng Sanit Ambient 23:973–978. https://doi.org/10.1590/S1413-41522018165394

    Article  Google Scholar 

  • Centeno LN, Cecconello ST (2016) Modificação de um índice de qualidade da água. Revista Científica Rural 18:65–82

    Google Scholar 

  • Citrini A, Camera CAS, Francesca Alborghetti F, Beretta GP (2021) Karst groundwater vulnerability assessment: application of an integrative index-based approach to main catchments of middle Valseriana springs (Northern Italy). Environ Earth Sci 80:2–20. https://doi.org/10.1007/s12665-021-09860-8

    Article  Google Scholar 

  • CPRM (2021) Serviço Geológico Brasileiro. Sistema de informações de Águas Subterrâneas SIAGAS. http://siagasweb.cprm.gov.br/layout/. Accessed 20 March 2022

  • Cunha NG, Silveira RJC, Severo CRS, Nunes ML, Soares MJ, Costa CN (1997) Estudos dos solos do município de Canguçu. EMBRAPA-CPCAT

  • De Giglio O, Barbuti G, Trerotoli P, Brigida S, Calabrese A, Di Vittorio G, Lovero G, Caggiano G, Uricchio VF, Montgna MT (2016) Microbiological and hydrogeological assessment of groundwater in southern Italy. Environ Monit Assess 188:638. https://doi.org/10.1007/s10661-016-5655-y

    Article  Google Scholar 

  • Elisante E, Muzuka ANN (2016) Sources and seasonal variation of coliform bacteria abundance in groundwater around the slopes of Mount Meru Arusha Tanzania. Environ Monit Assess 188(7):395. https://doi.org/10.1007/s10661-016-5384-2

    Article  Google Scholar 

  • Esteves FA (1988) Fundamentos de Limnologia. FINEP Interciência, Rio de Janeiro, p 575

    Google Scholar 

  • Feitosa FAC, et al (2008) Hidrogeologia: conceitos e aplicações. CPRM

  • Freeze A, Cherry J (1979) Groundwater. Prentice Hall, USA

    Google Scholar 

  • Guedes HAS, Silva DD, Elesbon AAA, Ribeiro CBM, Matos AT, Soares JHP (2012) Aplicação da análise estatística multivariada no estudo da qualidade da água do Rio Pomba, MG. Rev Brasil Engenharia Agríc Ambiental 16:558–563

    Article  Google Scholar 

  • Hair JFWC, Babin BJ, Anderson RE, Tatham RL (2009) Análise multivariada de dados. Bookman Editora

  • Hölting BW and Coldewey G (2019) Hydrogeology: physicochemical process in groundwater flow. Springer textbooks in earth sciences, geography and environment

  • Hou Q, Zhang Q, Huang G, Liu C, Zhang Y (2020) Elevated manganese concentrations in shallow groundwater of various aquifers in a rapidly urbanized delta, south China. Sci Total Environ 701:2–9. https://doi.org/10.1016/j.scitotenv.2019.134777

    Article  Google Scholar 

  • Howladar MF, Numanbakth MAA, Faruque MO (2017) An application of Water Quality Index (WQI) and multivariate statistics to evaluate the water quality around Maddhpara Granite Mining Industrial Area, Dinajpur, Bangladesh. Environ Syst Res 6:2–18. https://doi.org/10.1186/s40068-017-0090-9

    Article  Google Scholar 

  • Huang G, Chen Z, Sun J (2013) Water quality assessment and hydrochemical characteristics of shallow groundwater in eastern Chancheng District, Foshan, China. Water Environ Res 85:355–362. https://doi.org/10.2175/106143013X13596524516185

    Article  Google Scholar 

  • Hynds PD, Misstear BD, Gill W (2012) Development of a microbial contamination susceptibility model for private domestic groundwater sources. Water Resour Res 48:1–13. https://doi.org/10.1029/2012WR012492

    Article  Google Scholar 

  • Instituto Brasileiro de Geografia e Estatística (IBGE) (2010) http://cidades.ibge.gov.br. Accessed 19 August 2021

  • Isa NM, Aris ZA, Sulaiman ANW (2012) Extent and severity of groundwater contamination based on hidrochemistry mechanism of sandy tropical coastal aquifer. Sci Total Environ 438:414–425. https://doi.org/10.1016/j.scitotenv.2012.08069

    Article  Google Scholar 

  • Isokangas E, Ronkanen AK, Rossi PM, Martila H, Klove B (2019) A tracer-based method for classifying groundwater dependence in boreal headwater streams. J Hydrol 577:2–16. https://doi.org/10.1016/j.jhydrol.2019.05.029

    Article  Google Scholar 

  • Kaiser HF (1970) A second generation little jiffy. Psychometrika 35:401–415

    Article  Google Scholar 

  • Karavoltsos S, Sakellari A, Mihopoulos N, Dassenakis M, Scoullos MJ (2008) Evaluation of the quality of drinking water in regions of Greece. Desalination 224:317–329. https://doi.org/10.1016/j.desal.2007.06.013

    Article  Google Scholar 

  • Kousa A, Komulainen H, Hataka T, Backman B, Hartikainen S (2020) Variation in groundwater manganese in Finland. Environ Geochem Health 43:1193–1211. https://doi.org/10.1007/s10653-020-00643-x

    Article  Google Scholar 

  • Kresic N (2007) Hydrogeology and groundwater modeling, 2nd edn

  • Kumar S, Tripathi VR, Garg SK (2012) Physicochemical and microbiological assessment of recreational and drinking waters. Environ Monit Assess 186:2691–2698. https://doi.org/10.1007/s10661-011-2144-1

    Article  Google Scholar 

  • Lapworth DJ, Nkhuma DCW, Okotto-Okotto J, Pedley S, Stuart ME, Tijani MN, Wright J (2017) Urban groundwater quality in Sub-Saharan Africa: Current status and implications for water security. Hydrogeol J 25:1093–1116. https://doi.org/10.1007/s10040-016-1516-6

    Article  Google Scholar 

  • Leite NK, Stolberg J, Cruz SP, Tavela AO, Safanelli JL, Marchini HR, Exterkoetter R, Leite GMC, Krusche AV, Johnson MS (2018) Hydrochemistry of shallow groundwater and springs used for potable supply in Southern Brazil. Environ Earth Sci 80:2–17. https://doi.org/10.1007/s12665-018-7254-4

    Article  Google Scholar 

  • Lutterodt G, Vossenberg J, Hoiting Y, Kamara KA, Oduro-Kwarteng S, Foppen JWA (2018) Microbial groundwater quality status of hand-dug wells and boreholes in the Dodowa Area of Ghana. Int J Environ Res Public Health 730:2–12. https://doi.org/10.3390/ijerph15040730

    Article  Google Scholar 

  • Maas B, Peterson EW, Honings J, Oberhelman A, Oware P, Rusthoven I, Watson A (2019) Differentiation of surface water and groundwater in a Karst system using anthropogenic signatures. Geosciences 148:2–16

    Google Scholar 

  • Machado JLF, Freitas MA (2005) Mapa Hidrogeológico do Rio Grande do Sul. http://rigeo.cprm.gov.br/jspui/handle/doc/5249. Accessed 19 August 2021

  • Mahato S, Mahato A, Karna PK, Balmiki N (2018) Investigating aquifer contamination and groundwater quality in eastern Terai region of Nepal. BMC Res Notes 321:2–7. https://doi.org/10.1186/s13104-018-3445-z

    Article  Google Scholar 

  • Manahan S (2017) Environmental chemistry. CRC press

  • Maroco J (2003) Análise Estatística—Com utilização do SPSS. 2ª edição; Edições Sílabo

  • Marques CHG, Terada R, Galvão P, Hirata R (2019) Spatial and temporal Evolution of nitrate in the urban aquifer of Urânia (SP) Águas subterrâneas 33:258–269.https://doi.org/10.14295/ras.v33i3.29524

  • Matthess G (1982) The properties of groundwater. Willey, New York, p 406

    Google Scholar 

  • de Menezes JPC, Bertossi APA, Santos AR, Neves MA (2014) Correlação entre uso da terra e qualidade da água subterrânea. Engenharia Sanitaria e Ambiental 19(2):173–186. https://doi.org/10.1590/S1413-41522014000200008

    Article  Google Scholar 

  • Mester T, Balla D, Szabó G (2020) Assessment of groundwater quality changes in the rural environment of the Hungarian great plain based on selected water quality indicators. Water Air Soil Pollut 231:2–14. https://doi.org/10.1007/s11270-020-04910-6

    Article  Google Scholar 

  • Musley ML, Fitzpatrick RW, Palmer D, Leyden E, Shand P (2014) Changes in acidity and metal geochemistry in soils, groundwater, drain and river in the Lower Murray River after a severe drought. Sci Total Environ 485: 281–291. https://doi.org/10.1016/j.scitotenv.2014.03.063.

  • Nnorom CI, Ewuzie U, Eze SO (2019) Multivariate statistical approach and water quality assessment of natural springs and other drinking water sources in Southeastern Nigeria. Heliyon 1123:2–36. https://doi.org/10.1016/j.heliyon.2019.e01123

    Article  Google Scholar 

  • Noori SMS, Ebrahimi K, Liaghat AM (2013) Groundwater quality assessment using the water quality index and GIS in Saveh-Nobaran aquifer. Iran Environ Earth Sci 71:3827–3843. https://doi.org/10.1007/s12665-013-2770-8

    Article  Google Scholar 

  • Olasoji SO, Ovewole NO, Abiola B, Edokpavi JN (2019) Water quality assessment of surface and groundwater sources using a water quality index method: a case study of a Peri-Urban town in Southwest, Nigeria. Environments 23:1–11. https://doi.org/10.3390/environments6020023

    Article  Google Scholar 

  • Pazand K, Javashir RA (2016) Application of multivariate statistical techniques in hydrogeochemical evolution of groundwater in a igneous rock and sedimentary aquifer system: a case study of the southern Bam. SE Iran Carbonites Evaporites 31:9–16

    Article  Google Scholar 

  • Pitkänen T, Karinen P, Miettinen TI, Lettojärvi H, Heikkilä A, Maunula R, Aula H, Vepsäläinen A, Nousiainen LL, Pelkonen S, Heinonen-Tanski H (2011) Microbial contamination of groundwater at small community water supplies in Finland. Ambio 40:377–390

    Article  Google Scholar 

  • Rakib MA, Sasaki J, Matsuda H, Quraishi SB, Mahmud MJ, Bodrud-Doza M, Ullah AKMA, Fatema KJ, Newaz MA, Bhuiyan MAH (2020) Groundwater salinization and associated co-contamination risk increase severe drinking water vulnerabilities in the southwestern coast of Bangladesh. Chemosphere 246:125646. https://doi.org/10.1016/j.chemosphere.2019.125646

    Article  Google Scholar 

  • Reginato PAR, Ahlert S, Gilioli KC, Cemim G (2012) Caracterização hidrogeológica e hidroquímia do aquífero livre localizado no manto de alteração da Formação Serra Geral. na bacia hidrográfica Taquari-Antas. região nordeste do estado do Rio Grande do Sul. Ambiente Água 7:144–162. https://doi.org/10.4136/ambi-agua.903

    Article  Google Scholar 

  • Rivera-Hernández JR, Green-Ruiz CR, Pelling-Salazar LE, Flegal AR (2021) Monitoring of AS, Cd, Cr, and Pb in groundwater of Mexico’s agriculture Mocorito River Aquifer: implication for risks to human health. Water Air Soil Pollut 232:2–20. https://doi.org/10.1007/s11270-021-05238-5

    Article  Google Scholar 

  • Sabino H, Menezes J, Lima AL (2020) Indexing the groundwater quality index for human consumption (GWQIHC) for urban coastal aquifer assessment. Environ Earth Sci 167:3–14. https://doi.org/10.1007/s12665-020-8882-z

    Article  Google Scholar 

  • Sajil Kumar PJ, Jegathambal P, James EJ (2014) Chemometric evaluation of nitrate contamination in the groundwater of a hard rock area in Dharapuram, south India. Appl Water Sci 4:397–405. https://doi.org/10.1007/s13201-014-0155-0

    Article  Google Scholar 

  • Santana AGN, Suda CNK, Nascimento JRS, Vani GS (2020) Physical-chemical and microbiological analysis of water from shallow wells in Imperatriz (MA), Brazil. Ambiente Água 7:2–10. https://doi.org/10.4136/1980-993X

    Article  Google Scholar 

  • Santos GB, Valentini MHK, Silva LA, Franz HS, Corrêa BL, Viana FV, Corrêa GM, Vieira BM, Nadaleti WC, Leandro D, Vieira BM (2020) Avaliação dos parâmetros e do índice de qualidade de água para o Arroio Moreira/Fragata, Pelotas/RS. Revista Ibero-Americana De Ciências Ambientais 11:287–299. 10. 6008/CBPC2179-6858.2020.004.0024

  • Schijven JF, Hassanozadesh SM, Husman AMD (2010) Vulnerability of unconfined aquifers to virus contamination. Water Res 44:1170–1181

    Article  Google Scholar 

  • Selvam S, Venkatramanan S, Chung SY, Singaraja C (2016) Identification of groundwater contamination sources in Dindugal district of Tamil Nadu, India using GIS and multivariate statistical analyses. Arab J Geosci 9:2–14. https://doi.org/10.1007/s12517-016-2417-7

    Article  Google Scholar 

  • Şen Z (2015) Practical and applied hydrogeology: groundwater quality. Butterworth-Heinemann. Elsevier, pp 280–325

  • Silvia Z, Elisa A, Roberto L (2007) Neuropsychological testing for the assessment of manganese neurotoxicity: a review and a proposal. Am J Ind Med 50:812–830. https://doi.org/10.1002/ajim.20518

    Article  Google Scholar 

  • Soomro F, Rafique T, Michalski G, Azhar Ali S, Naseem S, Khan MU (2017) Occurrence and delineation of high nitrate contamination in the groundwater of Mithi sub-district, Thar Desert, Pakistan. Environ Earth Sci 76:1–9. https://doi.org/10.1007/s12665-017-6663-0

    Article  Google Scholar 

  • Spangler AH, Spangler JG (2009) Groundwater manganese and infant mortality rate by county in North Carolina: an ecological analysis. EcoHealth 6:596–600. https://doi.org/10.1007/s10393-010-0291-4

    Article  Google Scholar 

  • Speight JG (2020) Natural water remediation: water chemistry. Butterworth-Heinemann, Elsevier, pp 91–129

    Book  Google Scholar 

  • Su C, Zhuang F, Cui X, Cheng Z, Zheng Z (2020) Source characterization of nitrate in groundwater using hydrogeochemical and multivariate analysis in the Muling-Xingkai Palin, Northeast China. Environ Earth Sci 192:2–14. https://doi.org/10.1007/s10661-020-08347-6

    Article  Google Scholar 

  • Takehara L, Laux JH (2019) Área de relevante interesse mineral: Batólito Pelotas e Terreno Tijucas; Escala 1:500,000. Informe de recursos minerais. Série Províncias Minerais. nº 20. Porto Alegre: CPRM

  • Teixeira P, Costa SDD, Brown B, Silva EV (2020) Bactoroides ssp. And traditional fecal indicator bacteria in water quality assessment—an integrated approach for hydric resources management in urban centers. J Environ Manag. https://doi.org/10.1016/j.jenvman.2020.110989

  • Tirkey P, Bhattacharya T, Chakraborty S, Baraik S (2017) Assessment of groundwater quality and associated health risk: a case study of Ranchi city, Jharkhand, India. Groundw Sustain Dev 5:85–100. https://doi.org/10.1016/j.gsd.2017.05.002

    Article  Google Scholar 

  • Toma J, Ahmed R, Abdulla Z (2013) Application of water quality index for assessment water quality in some bottled water Erbil City, Kurdistan Region, Iraq. J Adv Lab Res Biol 4:118–124

    Google Scholar 

  • Tredoux G, Talma AS (2006) Nitrate pollution of groundwater in southern Africa. Groundwater pollution in Africa, pp 2–36

  • Uddin MG, Nash S, Olbert AI (2021) A review of water quality index models and their use for assessing surface water quality. Ecol Ind 122:2–21. https://doi.org/10.1016/j.ecolind.2020.107218

    Article  Google Scholar 

  • UNESCO (2015) The United Nations World Water Development Report. Water for sustainable development

  • Valentini MHK, Santos GB, Franz HS, Silva LA, Machado LL, Vieira DS, Vieira BM, Romani RF, Leandro D, Nadaleti WC, Vieira BM (2021a) Análise da qualidade da água da Lagoa Mirim através do IQA e de métodos estatísticos. Rev Ibero-Americana De Ciências Ambientais 12:376–384. https://doi.org/10.6008/CBPC2179-6858.2021.001.003

    Article  Google Scholar 

  • Valentini M, Santos GB, Vieira BM (2021b) Multiple regression analysis (MLR) applied for modelling a new WQI equation for monitoring water quality of Mirin Lagoon. in state of Rio Grande do Sul, Brazil. SN Appl Sci 70:1–11. https://doi.org/10.1007/s42452-020-04005-1

    Article  Google Scholar 

  • Vasudevan U, Gantayat RR, Chidambaram S, Prasanna MV, Venkatramanan S, Devaraj GN (2021) Microbial contamination and its associations with major ions in shallow groundwater along coastal Tamil Nadu. Environ Geochem Health 43:1069–1088. https://doi.org/10.1007/s10653-020-00712-1

    Article  Google Scholar 

  • World Health Organization (WHO) (2017) Guidelines for drinking-water quality. Fourth edition incorporating the first addendum

  • Wu J, Li P, Wang D, Ren X, Wei M (2019) Statistical and multivariate techniques to trace the sources and affecting factors of groundwater pollution in a rapidly growing city on the Chinese Loess Plateau. Hum Ecol Risk Int J 26:1603–1621. https://doi.org/10.1080/10807039.2019.1594156

    Article  Google Scholar 

  • Zhang Z, Xiao C, Adeyeye O, Yang W, Liang X (2020) Source and mobilization mechanism of iron, manganese and arsenicin groundwater of Shuangliao City, Northeast. China Water 534:2–17. https://doi.org/10.3390/w12020534

    Article  Google Scholar 

  • Zhou X, Shen Y, Zhang H, Song C, Li J, Liu Y (2015) Hydrochemistry of the natural low pH groundwater in the coastal aquifers near Beihai, China. J Ocean Univ China 14:475–483. https://doi.org/10.1007/s11802-015-2631-z

    Article  Google Scholar 

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Acknowledgements

This study is part of the Masters dissertation of Henrique Sanchez Franz, Programa de Pós-Graduação em Recursos Hídricos, Universidade Federal de Pelotas. The investigation was supported financially through Juliana Pertille da Silva. Revision by Léo Afraneo Hartmann of Universidade Federal do Rio Grande do Sul led to a significant improvement of the paper.

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Franz, H.S., Pertille, J., Kunst-Valentini, M.H. et al. Assessment of shallow groundwater quality for drinking purposes: an integrated approach based on the water quality index and the use of multivariate statistical analyses, southern Brazil. Environ Earth Sci 81, 452 (2022). https://doi.org/10.1007/s12665-022-10564-w

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