Abstract
Groundwater resource in alluvial aquifers is significantly essential for the sustainable development of arid regions worldwide. Forty-eight phreatic groundwaters were sampled and analyzed to elucidate the hydrochemical features, genesis and constraints on domestic and irrigational water supply in a hyper-arid alluvial fan on Tibetan plateau. The human health risk assessment and entropy-weighted water quality index (EWQI) along with drinking water guidelines were introduced to assess groundwater quality for domestic purpose, and the irrigation suitability was discussed in terms of the potential soil permeability damage and salinity hazard. The results indicated groundwater in the Golmud alluvial fan plain is slightly alkaline water and dominated in the hydrochemical faces of mixed Cl–Mg–Ca type, and followed Cl–Na type and mixed HCO3–Na–Ca type. Groundwater nitrite (~ 6.25%) and ammonia (~ 2.08%) exceed the drinking water standards in the farmlands and human settlements at the alluvial fan front, but would not threaten human health. The geogenic toxic elements of fluoride and boron would potentially pose health risks to the populations of infants, children and adult males at some sporadic locations. The risks are mainly attributed to the aqueous fluoride. Groundwaters in the alluvial fan plain are almost suitable for domestic purpose according to the EWQI appraisal results (35–151), and have suitable quality for irrigation regardless of sodium adsorption ratio, percentage sodium and permeability index. But, salinity hazard is widespread and should be concerned. Groundwater chemistry is basically governed by the natural rock–water interactions and influenced by agricultural practices and urban domestic effluents at the alluvial fan front. These anthropogenic contamination inputs resulted in the excessive nitrogen and elevated salinity of groundwater. Measures should be taken to protect groundwater resources in alluvial aquifers out of anthropogenic contamination. Geogenic fluoride is also needed to pay attention in the drinking water supply.
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References
Adimalla N (2019) Groundwater quality for drinking and irrigation purposes and potential health risks assessment: a case study from semi-arid region of South India. Expo Health 11:109–123. https://doi.org/10.1007/s12403-018-0288-8
Adimalla N (2020) Spatial distribution, exposure, and potential health risk assessment from nitrate in drinking water from semi-arid region of South India. Hum Ecol Risk Assess 26:310–334. https://doi.org/10.1080/10807039.2018.1508329
Adimalla N (2021) Application of the entropy weighted water quality index (EWQI) and the pollution index of groundwater (PIG) to assess groundwater quality for drinking purposes: a case study in a rural area of Telangana State, India. Arch Environ Contam Toxicol 80:31–40. https://doi.org/10.1007/s00244-020-00800-4
Adimalla N, Venkatayogi S (2018) Geochemical characterization and evaluation of groundwater suitability for domestic and agricultural utility in semi-arid region of Basara, Telangana State, South India. Appl Water Sci 8:44. https://doi.org/10.1007/s13201-018-0682-1
Adimalla N, Qian H, Li P (2020) Entropy water quality index and probabilistic health risk assessment from geochemistry of groundwaters in hard rock terrain of Nanganur County, South India. Geochemistry. https://doi.org/10.1016/j.chemer.2019.125544
Aravinthasamy P, Karunanidhi D, Subba Rao N, Subramani T, Srinivasamoorthy K (2020) Irrigation risk assessment of groundwater in a non-perennial river basin of South India: implication from irrigation water quality index (IWQI) and geographical information system (GIS) approaches. Arab J Geosci 13:1125. https://doi.org/10.1007/s12517-020-06103-1
Blackburn J, Comte J-C, Foster G, Gibbins C (2021) Hydrogeological controls on the flow regime of an ephemeral temperate stream flowing across an alluvial fan. J Hydrol 595:125994. https://doi.org/10.1016/j.jhydrol.2021.125994
Chowdhury AH, Scanlon BR, Reedy RC, Young S (2018) Fingerprinting groundwater salinity sources in the Gulf Coast Aquifer System, USA. Hydrogeol J 26:197–213. https://doi.org/10.1007/s10040-017-1619-8
Dash CJ, Sarangi A, Singh DK, Adhikary PP (2019) Numerical simulation to assess potential groundwater recharge and net groundwater use in a semi-arid region. Environ Monit Assess 191:371. https://doi.org/10.1007/s10661-019-7508-y
El-Ghannam MK, Aiad MA, Abdallah AM (2021) Irrigation efficiency, drain outflow and yield responses to drain depth in the Nile delta clay soil, Egypt. Agric Water Manag 246:106674. https://doi.org/10.1016/j.agwat.2020.106674
Gao Z, Wang Z, Wang S, Wu X, An Y, Wang W, Liu J (2019) Factors that influence the chemical composition and evolution of shallow groundwater in an arid region: a case study from the middle reaches of the Heihe River, China. Environ Earth Sci 78:390. https://doi.org/10.1007/s12665-019-8391-0
Gao X, Li X, Wang W, Li C (2020) Human activity and hydrogeochemical processes relating to groundwater quality degradation in the Yuncheng Basin, Northern China. Int J Environ Res Public Health. https://doi.org/10.3390/ijerph17030867
Gao Z, Han C, Xu Y, Zhao Z, Luo Z, Liu J (2021) Assessment of the water quality of groundwater in Bohai Rim and the controlling factors—a case study of northern Shandong Peninsula, north China. Environ Pollut 285:117482. https://doi.org/10.1016/j.envpol.2021.117482
GAQS (2017) Standards for groundwater quality (GB/T 14848–2017). General Administration of Quality Supervision, Beijing
Gibbs RJ (1970) Mechanisms controlling world water chemistry. Science 170:1088–1090. https://doi.org/10.1126/science.170.3962.1088
Gu X, Xiao Y, Yin S, Pan X, Niu Y, Shao J, Cui Y, Zhang Q, Hao Q (2017a) Natural and anthropogenic factors affecting the shallow groundwater quality in a typical irrigation area with reclaimed water, North China Plain. Environ Monit Assess. https://doi.org/10.1007/s10661-017-6229-3
Gu X, Xiao Y, Yin S, Shao J, Pan X, Niu Y, Huang J (2017b) Groundwater level response to hydrogeological factors in a semi-arid basin of Beijing, China. J Water Supply Res Technol AQUA 66:266–278. https://doi.org/10.2166/aqua.2017.093
Gu X, Xiao Y, Yin S, Hao Q, Liu H, Hao Z, Meng G, Pei Q, Yan H (2018) Hydrogeochemical characterization and quality assessment of groundwater in a long-term reclaimed water irrigation area, North China Plain. Water. https://doi.org/10.3390/w10091209
Hao Q, Shao J, Cui Y, Xie Z (2014) Applicability of artificial recharge of groundwater in the Yongding River alluvial fan in Beijing through numerical simulation. J Earth Sci 25:575–586. https://doi.org/10.1007/s12583-014-0442-6
Hao Q, Xiao Y, Chen K, Zhu Y, Li J (2020) Comprehensive understanding of groundwater geochemistry and suitability for sustainable drinking purposes in confined aquifers of the Wuyi Region, Central North China. Plain Water. https://doi.org/10.3390/w12113052
Huang J, Wang W, Cui X, Wang D, Liu W, Liu X, Wang S (2020) Environmental risk-based hydroeconomic evaluation for alluvial aquifer management in arid river basin. Sci Total Environ 711:134655. https://doi.org/10.1016/j.scitotenv.2019.134655
Hussain Y, Ullah SF, Hussain MB, Aslam AQ, Akhter G, Martinez-Carvajal H, Cárdenas-Soto M (2017) Modelling the vulnerability of groundwater to contamination in an unconfined alluvial aquifer in Pakistan. Environ Earth Sci 76:84. https://doi.org/10.1007/s12665-017-6391-5
Jean-Baptiste J, Le Gal La Salle C, Verdoux P (2020) Use of mixing models to explain groundwater quality time and space variation in a narrowed fluctuating alluvial aquifer. Appl Geochem 121:104700. https://doi.org/10.1016/j.apgeochem.2020.104700
Kumar PJS, Kuriachan L (2020) Chemometric appraisal of groundwater quality for domestic, irrigation and industrial purposes in Lower Bhavani River basin, Tamil Nadu, India. Int J Environ Anal Chem. https://doi.org/10.1080/03067319.2020.1770241
Kumar Joshi S, Gupta S, Sinha R, Logan Densmore A, Prakash Rai S, Shekhar S, Mason PJ, Dijk WMV (2021) Strongly heterogeneous patterns of groundwater depletion in Northwestern India. J Hydrol 598:126492. https://doi.org/10.1016/j.jhydrol.2021.126492
Kumari M, Rai SC (2020) Hydrogeochemical evaluation of groundwater quality for drinking and irrigation purposes using water quality index in semi arid region of India. J Geol Soc India 95:159–168. https://doi.org/10.1007/s12594-020-1405-4
Li F, Pan G, Tang C, Zhang Q, Yu J (2008) Recharge source and hydrogeochemical evolution of shallow groundwater in a complex alluvial fan system, southwest of North China Plain. Environ Geol 55:1109–1122. https://doi.org/10.1007/s00254-007-1059-1
Li Y, Zhang Z, Fei Y, Chen H, Qian Y, Dun Y (2016) Investigation of quality and pollution characteristics of groundwater in the Hutuo River Alluvial Plain, North China Plain. Environ Earth Sci 75:1–10. https://doi.org/10.1007/s12665-016-5366-2
Li J, Shi Z, Wang G, Liu F (2020) Evaluating spatiotemporal variations of groundwater quality in Northeast Beijing by self-organizing map. Water. https://doi.org/10.3390/w12051382
Luo Y, Xiao Y, Hao Q, Zhang Y, Zhao Z, Wang S, Dong G (2021) Groundwater geochemical signatures and implication for sustainable development in a typical endorheic watershed on Tibetan plateau. Environ Sci Pollut Res 28:48312–48329. https://doi.org/10.1007/s11356-021-14018-x
Mal U, Adhikari K (2021) Groundwater quality and hydrological stress induced by Lower Gondwana open cast coal mine. J Earth Syst Sci 130:32. https://doi.org/10.1007/s12040-020-01486-x
Marghade D, Malpe DB, Duraisamy K, Patil PD, Li P (2021) Hydrogeochemical evaluation, suitability, and health risk assessment of groundwater in the watershed of Godavari basin, Maharashtra, Central India. Environ Sci Pollut Res 28:18471–18494. https://doi.org/10.1007/s11356-020-10032-7
Peng C, He J-T, Wang M-l, Zhang Z-g, Wang L (2018) Identifying and assessing human activity impacts on groundwater quality through hydrogeochemical anomalies and NO3−, NH4+, and COD contamination: a case study of the Liujiang River Basin, Hebei Province, P.R. China. Environ Sci Pollut Res 25:3539–3556. https://doi.org/10.1007/s11356-017-0497-x
Qu S, Shi Z, Liang X, Wang G, Han J (2021) Multiple factors control groundwater chemistry and quality of multi-layer groundwater system in Northwest China coalfield—using self-organizing maps (SOM). J Geochem Explor 227:106795. https://doi.org/10.1016/j.gexplo.2021.106795
Rahman M, Tushar MAN, Zahid A, Ahmed KMU, Siddique MAM, Mustafa MG (2021) Spatiotemporal distribution of boron in the groundwater and human health risk assessment from the coastal region of Bangladesh. Environ Sci Pollut Res 28:21964–21977. https://doi.org/10.1007/s11356-020-11682-3
Rao MS, Krishan G, Kumar CP, Purushothaman P, Kumar S (2017) Observing changes in groundwater resource using hydro-chemical and isotopic parameters: a case study from Bist Doab, Punjab. Environ Earth Sci 76:175. https://doi.org/10.1007/s12665-017-6492-1
Sheikhy Narany T, Sefie A, Aris AZ (2018) The long-term impacts of anthropogenic and natural processes on groundwater deterioration in a multilayered aquifer. Sci Total Environ 630:931–942. https://doi.org/10.1016/j.scitotenv.2018.02.190
Siddique J, Menggui J, Shah MH, Shahab A, Rehman F, Rasool U (2020) Integrated approach to hydrogeochemical appraisal and quality assessment of groundwater from Sargodha District, Pakistan. Geofluids 2020:6621038. https://doi.org/10.1155/2020/6621038
Singha S, Pasupuleti S, Singha SS, Singh R, Kumar S (2021) Prediction of groundwater quality using efficient machine learning technique. Chemosphere 276:130265. https://doi.org/10.1016/j.chemosphere.2021.130265
Subba Rao N, Sunitha B, Adimalla N, Chaudhary M (2019) Quality criteria for groundwater use from a rural part of Wanaparthy District, Telangana State, India, through ionic spatial distribution (ISD), entropy water quality index (EWQI) and principal component analysis (PCA). Environ Geochem Health 42:579–599. https://doi.org/10.1007/s10653-019-00393-5
Tweed S, Leblanc M, Cartwright I, Favreau G, Leduc C (2011) Arid zone groundwater recharge and salinisation processes; an example from the Lake Eyre Basin, Australia. J Hydrol 408:257–275. https://doi.org/10.1016/j.jhydrol.2011.08.008
USEPA (1989) Risk assessment guidance for superfund, Volume I: human health evaluation manual (Part A). Interim final. (EPA/540/1‐89/002)
USSL (1954) Diagnosis and improvement of saline and alkali soils. Agriculture handbook
Venkatramanan S, Chung SY, Selvam S, Lee SY, Elzain HE (2017) Factors controlling groundwater quality in the Yeonjegu District of Busan City, Korea, using the hydrogeochemical processes and fuzzy GIS. Environ Sci Pollut Res 24:23679–23693. https://doi.org/10.1007/s11356-017-9990-5
Wang Y, Zheng C, Ma R (2018) Review: safe and sustainable groundwater supply in China. Hydrogeol J 26:1301–1324. https://doi.org/10.1007/s10040-018-1795-1
Wang Y, Li J, Ma T, Xie X, Deng Y, Gan Y (2020) Genesis of geogenic contaminated groundwater: As, F and I. Crit Rev Environ Sci Technol. https://doi.org/10.1080/10643389.2020.1807452
Wen Y, Shang S, Rahman KU, Xia Y, Ren D (2020) A semi-distributed drainage model for monthly drainage water and salinity simulation in a large irrigation district in arid region. Agric Water Manag 230:105962. https://doi.org/10.1016/j.agwat.2019.105962
WHO (2017) Guidelines for drinking-water quality, 4th edition incorporating the first addendum. World Health Organization
Wu C, Wu X, Zhu G, Qian C, Mu W-P, Zhang Y-z (2018) Influence of a power plant in Ezhou City on the groundwater environment in the nearby area. Environ Earth Sci 77:503. https://doi.org/10.1007/s12665-018-7674-1
Xiao Y, Gu X, Yin S, Pan X, Shao J, Cui Y (2017a) Investigation of geochemical characteristics and controlling processes of groundwater in a typical long-term reclaimed water use area. Water 9:800
Xiao Y, Shao J, Cui Y, Zhang G, Zhang Q (2017b) Groundwater circulation and hydrogeochemical evolution in Nomhon of Qaidam Basin, northwest China. J Earth Syst Sci. https://doi.org/10.1007/s12040-017-0800-8
Xiao Y, Shao J, Frape S, Cui Y, Dang X, Wang S, Ji Y (2018) Groundwater origin, flow regime and geochemical evolution in arid endorheic watersheds: a case study from the Qaidam Basin, northwestern China. Hydrol Earth Syst Sci 22:4381–4400. https://doi.org/10.5194/hess-22-4381-2018
Xiao Y, Yin S, Hao Q, Gu X, Pei Q, Zhang Y (2020) Hydrogeochemical appraisal of groundwater quality and health risk in a near-suburb area of North China. J Water Supply Res Technol AQUA 69:55–69. https://doi.org/10.2166/aqua.2019.101
Xiao Y, Hao Q, Zhang Y, Zhu Y, Yin S, Qin L, Li X (2021a) Investigating sources, driving forces and potential health risks of nitrate and fluoride in groundwater of a typical alluvial fan plain. Sci Total Environ 802:149909. https://doi.org/10.1016/j.scitotenv.2021.149909
Xiao Y, Liu K, Hao Q, Li J, Zhang Y, Cui W, Limao q, Pei Q, (2021b) Hydrogeochemical features and genesis of confined groundwater and health perspectives for sustainable development in Urban Hengshui, North China Plain. J Chem 2021:5578192. https://doi.org/10.1155/2021/5578192
Xiao Y, Xiao D, Hao Q, Liu K, Wang R, Huang X, Liao X, Zhang Y (2021c) Accessible phreatic groundwater resource in the Central Shijiazhuang of North China Plain: perspective from the hydrogeochemical constraints. Front Environ Sci. https://doi.org/10.3389/fenvs.2021.747097
Xu P, Feng W, Qian H, Zhang Q (2019a) Hydrogeochemical characterization and irrigation quality assessment of shallow groundwater in the Central-Western Guanzhong Basin, China. Int J Environ Res Public Health 16:1492
Xu P, Li M, Qian H, Zhang Q, Liu F, Hou K (2019b) Hydrochemistry and geothermometry of geothermal water in the central Guanzhong Basin, China: a case study in Xi’an. Environ Earth Sci 78:87. https://doi.org/10.1007/s12665-019-8099-1
Xu P, Zhang Q, Qian H, Li M, Hou K (2019c) Characterization of geothermal water in the piedmont region of Qinling Mountains and Lantian-Bahe Group in Guanzhong Basin, China. Environ Earth Sci 78:442. https://doi.org/10.1007/s12665-019-8418-6
Xu W, Zhu P, Yang F (2019d) Evaluation of groundwater recharge sources based on environmental tracers in an arid alluvial fan, NW China. J Radioanal Nucl Chem 319:123–133. https://doi.org/10.1007/s10967-018-6272-8
Xu P, Zhang Q, Qian H, Guo M, Yang F (2021a) Exploring the geochemical mechanism for the saturated permeability change of remolded loess. Eng Geol 284:105927. https://doi.org/10.1016/j.enggeo.2020.105927
Xu P, Zhang Q, Qian H, Yang F, Zheng L (2021b) Investigating the mechanism of pH effect on saturated permeability of remolded loess. Eng Geol 284:105978. https://doi.org/10.1016/j.enggeo.2020.105978
Yan J, Chen J, Zhang W (2021) Study on the groundwater quality and its influencing factor in Songyuan City, Northeast China, using integrated hydrogeochemical method. Sci Total Environ 773:144958. https://doi.org/10.1016/j.scitotenv.2021.144958
Yang N, Wang G (2020) Moisture sources and climate evolution during the last 30 kyr in northeastern Tibetan Plateau: insights from groundwater isotopes (2H, 18O, 3H and 14C) and water vapour trajectories modeling. Quatern Sci Rev 242:106426. https://doi.org/10.1016/j.quascirev.2020.106426
Yin S, Xiao Y, Gu X, Hao Q, Liu H, Hao Z, Meng G, Pan X, Pei Q (2019) Geostatistical analysis of hydrochemical variations and nitrate pollution causes of groundwater in an alluvial fan plain. Acta Geophys 67:1191–1203. https://doi.org/10.1007/s11600-019-00302-5
Yin S, Xiao Y, Han P, Hao Q, Gu X, Men B, Huang L (2020) Investigation of groundwater contamination and health implications in a typical semiarid basin of North China. Water 12:1137. https://doi.org/10.3390/w12041137
Yuan R, Wang S, Wang P, Song X, Tang C (2017) Changes in flow and chemistry of groundwater heavily affected by human impacts in the Baiyangdian catchment of the North China Plain. Environ Earth Sci 76:571. https://doi.org/10.1007/s12665-017-6918-9
Zango MS, Sunkari ED, Abu M, Lermi A (2019) Hydrogeochemical controls and human health risk assessment of groundwater fluoride and boron in the semi-arid North East region of Ghana. J Geochem Explor 207:1–21. https://doi.org/10.1016/j.gexplo.2019.106363
Zhang Q, Wang H, Wang Y, Yang M, Zhu L (2017) Groundwater quality assessment and pollution source apportionment in an intensely exploited region of northern China. Environ Sci Pollut Res 24:16639–16650. https://doi.org/10.1007/s11356-017-9114-2
Zhang Q, Xu P, Qian H (2019) Assessment of groundwater quality and human health risk (HHR) evaluation of nitrate in the Central-Western Guanzhong Basin, China. Int J Environ Res Public Health 16:4246
Zhang Q, Xu P, Qian H (2020a) Groundwater quality assessment using improved water quality index (WQI) and human health risk (HHR) evaluation in a semi-arid region of Northwest China. Expos Health 12:487–500. https://doi.org/10.1007/s12403-020-00345-w
Zhang Q, Xu P, Qian H, Yang F (2020b) Hydrogeochemistry and fluoride contamination in Jiaokou Irrigation District, Central China: assessment based on multivariate statistical approach and human health risk. Sci Total Environ 741:140460. https://doi.org/10.1016/j.scitotenv.2020.140460
Zhang Q, Liu H, Zhu P, Xu W, Su X (2021a) Evaluation of the influence of river bank infiltration on groundwater in an inland alluvial fan using spectral analysis and environmental tracers. Hydrogeol J 29:1117–1128. https://doi.org/10.1007/s10040-020-02290-z
Zhang Q, Qian H, Xu P, Li W, Feng W, Liu R (2021b) Effect of hydrogeological conditions on groundwater nitrate pollution and human health risk assessment of nitrate in Jiaokou Irrigation District. J Clean Prod 298:126783. https://doi.org/10.1016/j.jclepro.2021.126783
Zhang Q, Xu P, Chen J, Qian H, Qu W, Liu R (2021c) Evaluation of groundwater quality using an integrated approach of set pair analysis and variable fuzzy improved model with binary semantic analysis: a case study in Jiaokou Irrigation District, east of Guanzhong Basin, China. Sci Total Environ 767:145247. https://doi.org/10.1016/j.scitotenv.2021.145247
Zhang Y, Dai Y, Wang Y, Huang X, Xiao Y, Pei Q (2021d) Hydrochemistry, quality and potential health risk appraisal of nitrate enriched groundwater in the Nanchong area, southwestern China. Sci Total Environ 784:147186. https://doi.org/10.1016/j.scitotenv.2021.147186
Zhu H, Zhou J, Song T, Feng H, Liu Z, Liu H, Ren X (2020) Influences of natural and anthropogenic processes on the groundwater quality in the Dagujia River Basin in Yantai, China. J Water Supply Res Technol AQUA 69:184–196. https://doi.org/10.2166/aqua.2019.113
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This research was funded by the Natural Science Foundation of China (42007183), the Fundamental Research Funds for the Central Universities (2682021ZTPY063; 2682020CX10), the Science and Technology Plan Project of Qinghai Province (2021-ZJ-T08), the Bureau of Qinghai Environmental Geological Prospecting (2021-KJ-001-02; 2021-KJ-011), the Student Research Training Program of Southwest Jiaotong University (210815), and the Research Project on Teaching Reform of Southwest Jiaotong University (20201023-04).
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Xiao, Y., Liu, K., Yan, H. et al. Hydrogeochemical constraints on groundwater resource sustainable development in the arid Golmud alluvial fan plain on Tibetan plateau. Environ Earth Sci 80, 750 (2021). https://doi.org/10.1007/s12665-021-10076-z
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DOI: https://doi.org/10.1007/s12665-021-10076-z