Abstract
Sanitary landfill is a common method for the treatment of municipal solid waste. The landfill leachate contains a large amount of NH4+, which will affect the physicochemical properties of bentonite, and subsequently change the anti-seepage function of the bentonite enhanced cutoff wall. The permeability tests were carried out on bentonite-clay mixed soil infiltrated by the ammonium salt solutions using a head pressure control permeameter. The results show that saturated permeability coefficient of the bentonite-clay mixture increases with the decrease of bentonite content and with the increase of NH4+ concentration. Moreover, the reasonable mass content of bentonite is about 10% if the studied bentonite-clay mixture are used in vertical cutoff wall. The scanning electron microscope (SEM) and the nuclear magnetic resonance (NMR) measurements were conducted on the bentonite-clay mixed soil samples with different bentonite contents, and samples infiltrated by the ammonium salt solutions with different concentrations, and afterwards the variations of the micro pore structure and pore-size distribution were obtained. Connecting the Donnan osmotic pressure with saturated permeability of bentonite-clay mixed soils, the effect mechanism of bentonite content and ammonium solution concentration on the permeability of the bentonite-clay mixture was analyzed.
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Acknowledgements
The authors are grateful to the National Key R&D Program of China (Grant No. 2019YFC1520500), the National Sciences Foundation of China (Grant No. 41977214, 41572284 and 41772300) for the financial supports.
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Sun, WJ., Xu, G., Wei, G. et al. Effects of ammonium ion and bentonite content on permeability of bentonite-clay mixture. Environ Earth Sci 80, 151 (2021). https://doi.org/10.1007/s12665-021-09440-w
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DOI: https://doi.org/10.1007/s12665-021-09440-w