Abstract
Groundwater is a major source of drinking-water supply in most developing countries including Ghana. Groundwater samples were collected from boreholes from fifty-seven (57) communities in the Northern and Upper East regions of Ghana between October 2016 and March 2017. Physico-chemical parameters and heavy metals, such as Fe, As, Cd, Pb, Mn, and Zn, were determined to evaluate the chemical status and pollution levels of the groundwater sources. The results showed that temperature, total suspended solids, and fluoride ion in groundwater from both regions have most of their values fall above the World Health Organisation (WHO) acceptable values. The heavy metals results show that Fe, Cd, and As from both regions have values above the WHO acceptable limits for drinking water. The principal component analysis reveals dissolved chemical constituents, dissolution of salts from atmospheric precipitation, and anthropogenic activity as the main sources of the measured parameters within the study area. Single-factor analysis of variance analysis indicated significant differences in data sets within and between the detected parameters. The water quality index (WQI) results showed that 96.30 and 44.80% of groundwater sources in the Northern and Upper East regions, respectively, were poor in quality and hence unsuitable for drinking. Moreover, a significant positive correlation of WQI with As, Cd, and Fe indicates that As, Cd, and Fe have a significant impact on the groundwater quality. The degree of contamination, heavy metal evaluation indices, and heavy metal pollution indices showed that most of the groundwater sources were extremely contaminated. The health risk assessments for As, Pb, and Cd as well as, Cd, and Zn showed HQ > 1 in some of the groundwater sources in the Northern and Upper East regions, respectively, in some of the groundwater sources. The carcinogenic risk for As and Pb exceeded the acceptable limit of 10−6. Hence, it can be concluded that adequate treatment regime is required for safe use of groundwater from the Northern and Upper East regions of Ghana.
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Abdesselem K, Azedine H, Lynda C (2016) Groundwater hydrochemistry and effects of anthropogenic pollution in Béchar city (SW Algeria). Desalin Water Treat 57:14034–14043
Agyekum WA, Dapaah-Siakwan S (2008) The occurrence of groundwater in north-eastern Ghana. In: Applied groundwater studies in Africa (S.M.A. Adelana and A.M. Donald, eds). pp. 199–214. IAH Selected papers on Hydrogeology, Volume 13, CRC Press, Balkema, Leiden, The Netherlands
Ahamed AJ, Ananthakrishnan S, Loganathan K, Manikandan K (2013) Assessment of groundwater quality for irrigation use in Alathur block, Perambalur district, Tamilnadu, South India. Appl Water Sci 3:763–771
Akoto O, Bruce TN, Darko G (2010) Chemical and biological characteristics of streams in the Owabi watershed. Environ Monit Assess 161:413–422
Alam MO, Shaikh WA, Chakraborty S, Avishek K, Bhattacharya T (2016) Groundwater arsenic contamination and potential health risk assessment of Gangetic Plains of Jharkhand, India. Expo Health 8:125–142
Ali MM, Ali ML, Islam MS, Rahman MZ (2016) Preliminary assessment of heavy metals in water and sediment of Karnaphuli River, Bangladesh. Environ Nanotechnol Monit Manag 5:27–35
APHA (2005) WEF (2005) Standard methods for the examination of water and wastewater. American Public Health Association, American Water Works Association, and Water Environment Federation
Arumugam K, Elangovan K (2009) Hydrochemical characteristics and groundwater quality assessment in Tirupur region, Coimbatore district, Tamil Nadu. India Environ Geol 58:1509
Asare-Donkor NK, Kwaansa-Ansah EE, Opoku F, Adimado AA (2015) Concentrations, hydrochemistry and risk evaluation of selected heavy metals along the Jimi River and its tributaries at Obuasi a mining enclave in Ghana. Environ Syst Res 4:1–14
Avvannavar SM, Shrihari S (2008) Evaluation of water quality index for drinking purposes for river Netravathi, Mangalore, South India. Environ Monit Assess 143:279–290
Backman B, Bodis D, Lahermo P, Rapant S, Tarvainen T (1997) Application of a groundwater contamination index in Finland and Slovakia. Environ Geol. https://doi.org/10.1007/s002540050320
Backman B, Bodiš D, Lahermo P, Rapant S, Tarvainen T (1998) Application of a groundwater contamination index in Finland and Slovakia. Environ Geol 36:55–64
Boateng TK, Opoku F, Acquaah SO, Akoto O (2016) Groundwater quality assessment using statistical approach and water quality index in Ejisu-Juaben Municipality, Ghana. Environ Earth Sci 75:1–14
Cassanego M, Droste A (2017) Assessing the spatial pattern of a river water quality in southern Brazil by multivariate analysis of biological and chemical indicators. Braz J Biol 77:118–126
Castaing B, Geiger A, Seliger H, Nehls P, Laval J, Zelwer C, Boiteux S (1993) Cleavage and binding of a DNA fragment containing a single 8- oxoguanine by wild type and mutant FPG protens. Nucleic Acids Res 21:2899–2905
Chapman D (1997) Water Quality Assessment. A Guide to the use of Biota, Sediments and water in Environmental Monitoring. Hydrology and Water Quality of Lake Merced. University Press, Cambridge
Chatterjee R (2010) Municipal solid waste management in kohima city-india. J Environ Health Sci Eng 7:173–180
Chen J, Wu H, Qian H (2016) Groundwater nitrate contamination and associated health risk for the rural communities in an agricultural area of Ningxia. Exposure and Health, Northwest China. https://doi.org/10.1007/s12403-016-0208-8
Chen J, Qian H, Wu H, Gao Y, Li X (2017a) Assessment of arsenic and fluoride pollution in groundwater in Dawukou area, Northwest China, and the associated health risk for inhabitants. Environ Earth Sci 76:314
Chen J, Wu H, Qian H, Gao Y (2017b) Assessing nitrate and fluoride contaminants in drinking water and their health risk of rural residents living in a semiarid region of Northwest China. Expo Health 9:183–195
Chen J, Qian H, Gao Y, Wang H (2020) Zhang M (2020) Insights into hydrological and hydrochemical processes in response to water replenishment for lakes in arid regions. J Hydrol 581:124386
Christensen TH et al (2001) Biogeochemistry of landfill leachate plumes. Appl Geochem 16:659–718
Cobbina S, Nyame F, Obiri S (2012) Groundwater quality in the sahelian region of northern ghana, West Africa. Res J Environ Earth Sci 4:482–491
Custodio E, Manzano (2007) Groundwater quality background levels.In: Quevauviller P (Eds) Groundwater science and policy: an international overview. The Royal Society of Chemistry RSC Publ. 193 216
Dart F (1974) The hazard of iron. Water and Pollution Control, Ottawa
Edet A, Offiong O (2002) Evaluation of water quality pollution indices for heavy metal contamination monitoring. A study case from Akpabuyo-Odukpani area, Lower Cross River Basin (southeastern Nigeria). GeoJ 57:295–304
Edmunds WM, Shand P (eds) (2008) The natural groundwater quality. Blackwell, Oxford, pp 1–469
Elisante E, Muzuka AN (2016) Assessment of sources and transformation of nitrate in groundwater on the slopes of Mount Meru. Tanzania Environ Earth Sci 75:277
Elumalai V, Nwabisa DP, Rajmohan N (2019) Evaluation of high fluoride contaminated fractured rock aquifer in South Africa–geochemical and chemometric approaches. Chemosphere 235:1–11. https://doi.org/10.1016/j.chemosphere.2019.06.065
Etim E, Odoh R, Itodo A, Umoh S, Lawal U (2013) Water quality index for the assessment of water quality from different sources in the Niger Delta Region of Nigeria. Front Sci 3:89–95
Flyhammar P (1995) Leachate quality and environmental effects at active Swedish municipal landfill. In: vol 95. Proceedings Sardinia, pp 549–557
Freeze RA, Cherry JA (1979) Groundwater Prentice Hall Englewood Cliffs. In. Prentice Hall, Inc., Englewood Cliffs, New Jersey, p 603
Ghana Districts (2006) Upper West region. Accessed 16 August, 2017
Gyau-Boakye P, Kankam-Yeboah K, Darko PK, Dapaah-Siakwan S, Duah AA (2008) Grounwater as a vital resource for rural development: An example from Ghana. In: Adelena A, MacDonald TA, Alemayedu and Tiridimugaya C, eds Applied groundwater studies in Africa, IAH selected papers Q3 on hydrogeologyvol. 13
Hetzel BS (1989) The story of iodine deficiency: an international challenge in nutritioncontinued. Oxford University Press, New York
Hu X, Zhang Y, Ding Z, Wang T, Lian H, Sun Y, Wu J (2012) Bioaccessibility and health risk of arsenic and heavy metals (Cd Co, Cr, Cu, Ni, Pb, Zn and Mn) in TSP and PM2.5 in Nanjing. China AtmEn 57:146–152
Jackson LE, Burger M, Cavagnaro TR (2008) Roots, nitrogen transformations, and ecosystem services. Annu Rev Plant Biol 59(1):341–363. https://doi.org/10.1146/annurev.arplant.59.032607.092932
John De Zuane PE (1990) Handbook of drinking water quality-standards and controls. Van Nostrand Reinhold, New York
Jolliffe IT (2002) Principal component analysis. Journal of computational and Graphical Statistics, 2 nd edn. Springer, New York
Junner NR (1940) Geology of the Golg Coast and Western Togoland (with Revised Geologica Map). Gold Coast Geol Surv Bull 11:75p
Junner NR and Hirst T (1946) The geology and hydrogeology of the Volta Basin, Gold Coast Geological Survey, Memoir 8
Kaka E, Akiti T, Nartey V, Bam E, Adomako D (2011) Hydrochemistry and evaluation of groundwater suitability for irrigation and drinking purposes in the southeastern Volta river basin: manya krobo area, Ghana. Agriculture 39:4793–4807
Kaur R, Singh R (2009) Analysis of water quality parameters of ground water near bichhwal industrial area, bikaner in post-monsoon season, November 2008. Int J Chem Sci 7:2519–2534
Kesse GO (1985) The mineral and rock resources of Ghana. Balkeman, Rotterdam
Kortatsi BK (1994) Groundwater utilization in Ghana. In: Future groundwater resources at risk (preceedings of the Heisinki conference) wallingford: IAH Press, IAHS publ. No.222, 149–156
Kumar J, Pal A (2012) Water quality monitoring of Ken River of Banda District, Uttar Pradesh, India. Elixir Pollut 42:6360–6364
Lee J-S, Chon H-T, Kim K-W (2005) Human risk assessment of As, Cd, Cu and Zn in the abandoned metal mine site. Environ Geochem Health 27:185–191
Leube A, Hirdes W, Mauer R, Kesse GO (1990) The early Proterozoic Birimian Supergroup of Ghana and some aspects of its associated gold mineralization. PreR 46:139–165. https://doi.org/10.1016/0301-9268(90)90070-7
Li P, Qian H (2011) Human health risk assessment for chemical pollutants in drinking water source in Shizuishan City, Northwest China. J Environ Health Sci Eng 8:41–48
Lim H-S, Lee J-S, Chon H-T, Sager M (2008) Heavy metal contamination and health risk assessment in the vicinity of the abandoned Songcheon Au–Ag mine in Korea. J Geochem Explor 96:223–230
Longe E, Balogun M (2010) Groundwater quality assessment near a municipal landfill, Lagos, Nigeria. Res J Appl Sci Eng Technol 2:39–44
Mahananda M, Mohanty B, Behera N (2010) Physico-chemical analysis of surface and ground water of Bargarh District, Orissa, India. Int J Res Rev Appl Sci 2:284–295
Martin N (2006) Development of a water balance for the Atankwidi catchment, West Africa: a case study of groundwater recharge in a semi-arid climate. Cuvillier, Göttingen, Germany
Ministry of Food and Agriculture (2003) Agriculture in Ghana: facts and figures. Produced by the statistics Research and Information Directorate, Accra
Mohamed H (2005) Physico-chemical characteristics of Abu Za'baal ponds. Egypt Egypt J Aquat Res 31:1–15
Mohamed EA, Aref L, Nassir A, Abdulaziz A (2015) Groundwater characteristics and pollution assessment using integrated hydrochemical investigations GIS and multivariate geostatistical techniques in arid areas. Water Resour Manag 29:5593–5612
Mohan SV, Nithila P, Reddy SJ (1996) Estimation of heavy metals in drinking water and development of heavy metal pollution index. J Environ Sci Health Part A 31:283–289
Muhammad S, Shah MT, Khan S (2011) Health risk assessment of heavy metals and their source apportionment in drinking water of Kohistan region, northern Pakistan. Microchem J 98:334–343
Nag S, Das S (2017) Assessment of groundwater quality from Bankura I and II Blocks, Bankura District, West Bengal, India. Appl Water Sci 1–16
Napacho Z, Manyele S (2010) Quality assessment of drinking water in Temeke District (part II): Characterization of chemical parameters. Afr J Environ Sci Technol 4:775–789
NSDF Study (2013) based on GSS population census
Nude PM, Arhin E (2009) Overbank sediments as appropriate geochemical sample media in regional stream sediment surveys for gold exploration in the savannah regions of northern Ghana. J Geochem Explor 103:50–56. https://doi.org/10.1016/j.gexplo.2009.06.005
Obuobie E and Barry B. 2012. Ghana. Chapter in P Pavelic, M Giordano, B Keraita, T Rao, and V Ramesh (Eds.), Groundwater availability and use in Sub-Saharan Africa: a review of 15 countries; Ch. 4, pp.43–64. Colombo, Sri Lanka: International Water Management Institute (IWMI). 10.5337/2012.213
Obuobie E, Barry B (2010) Groundwater in sub-Saharan Africa: Implications for food security and livelihoods:country Status on Groundwater, final report Accessed 16 August, 2017
Obuobie E. (2008) Estimation of groundwater recharge in the context of future climate change in the White Volta River Basin, West Africa. Ecology and development series. No 62, 168 p.
Pelig-Ba K, Biney C, Antwi L (1991) Trace metal concentrations in borehole waters from the Upper Regions and the Accra Plains of Ghana. Water Air Soil Pollut 59:333–345
Prasad B, Bose J (2001) Evaluation of the heavy metal pollution index for surface and spring water near a limestone mining area of the lower Himalayas. Environ Geol 41:183–188
Purushotham D, Prakash M, Rao AN (2011) Groundwater depletion and quality deterioration due to environmental impacts in Maheshwaram watershed of RR district, AP (India). Environ Earth Sci 62:1707–1721
Qian H, Li P, Howard KF, Yang C, Zhang X (2012) Assessment of groundwater vulnerability in the Yinchuan Plain, Northwest China using OREADIC. Environ Monit Assess 184:3613–3628. https://doi.org/10.1007/s10661-011-2211-7
Qian H, Chen J, Huang Q, Lin Y, Fang Y, Liu R, Ma H (2019) Hydrogeochemical characteristics and quality assessment of groundwater in an irrigated region. Northwest China Water 11(96):1–18
Ramachandra T, Solanki M (2007) Ecological assessment of lentic water bodies of Bangalore, vol 25. The Ministry of Science and Technology, Bangalore
Rezaei A, Hassani H (2017) Hydrogeochemistry study and groundwater quality assessment in the north of Isfahan, Iran. Environ Geochem Health, 1–26
Ross N (ed) (2010) Clearing the waters, a focus on water quality solutions. UNEP, Nairobi.
Rupal M, Tanushree B, Sukalyan C (2012) Quality characterization of groundwater using water quality index in Surat city, Gujarat, India. Int Res J Environ Sci 1:14–23
Saana SBBM, Fosu SA, Sebiawu GE, Jackson N, Karikari T (2016) Assessment of the quality of groundwater for drinking purposes in the Upper West and Northern regions of Ghana. SpringerPlus 5:2001. 10.1186/s40064–016–3676–1
Sahu P, Sikdar P (2008) Hydrochemical framework of the aquifer in and around East Kolkata Wetlands, West Bengal, India. Environ Geol 55:823–835
Saxena V, Ahmed S (2001) Dissolution of fluoride in groundwater: a water-rock interaction study. Environ Geol 40:1084–1087
Sebiawu GE, Fosu SA, Saana SBBM (2014) A Physico-chemical and bacteriological analysis of borehole water samples from the Wa Municipality of the Upper West Region, Ghana. Int J Eng Res Technol 3:1959–1965
Shemsanga C, Muzuka ANN, Martz L, Komakech HC, Elisante E, Kisaka M, Ntuza C (2017) Origin and mechanisms of high salinity in Hombolo Dam and groundwater in Dodoma municipality Tanzania, revealed. Appl Water Sci, 1–23
Sinha A, Srivastava K, Sexena J (2000) Impact of urbanization on groundwater of Jaipur, Rajasthan. In: Sinha A, Srivastava K (eds) Earth Resources and environmental issue, vol 6. ABD Publishers, Jaipur, pp 173–179
Soil Research Institute (1998) The 1997 Annual Report Accra
Soumya BS, Sekhar M, Riotte J, Banerjee A, Braun J-J (2013) Characterization of groundwater chemistry under the influence of lithologic and anthropogenic factors along a climatic gradient in Upper Cauvery basin, South India. Environ Earth Sci 69:2311–2335
Su H, Kang W, Xu Y, Wang J (2017) Assessing Groundwater Quality and Health Risks of Nitrogen Pollution in the Shenfu Mining Area of Shaanxi Province, Northwest China. Expo Health, 1–21
Suthar S, Bishnoi P, Singh S, Mutiyar PK, Nema AK, Patis NS (2009) Nitrate contamination in groundwater of some rural areas of Rajasthan, India. J Hazard Mater 171(1–3):189–199. https://doi.org/10.1016/j.jhazmat.2009.05.111
Tirkey P, Bhattacharya T, Chakraborty S, Baraik S (2017) Assessment of groundwater quality and associated health risks: a case study of Ranchi city, Jharkhand. Groundwater for Sustainable Development, India
Tiwari TN, Mishra MA (1985) A preliminary assignment of water quality index of major Indian rivers. Indian J Environ Prot 5:276–279
Todd DK, Larry W (2005) Ground-water hydrology. Wiley, New York
UNESCO (2012) World’s groundwater resources are suffering from poor governance. In: UNESCO Natural Sciences Sector News. United Nations Educational, Scientific and Cultural Organization, Paris
USEPA (1989) Risk assessment guidance for Superfund. Human health evaluation manual, (part A) vol 1. Office of emergency and remedial response, Washington, DC
USEPA IRIS (2011) Integrated Risk Information System. Environmental Protection Agency Region I US EP, Washington DC
Venkateswaran S, Prabhu M, Rafi M, Vallel K (2011) Assessment of groundwater quality for irrigational use in cumbum valley, Madurai District, Tamilnadu, India. Nat Environ Pollut Technol 10:207–212
Vyas H, Sawant V (2008) Seasonal variations in drinking water quality of some Borewell waters in urban area of Kolhapur city. Nat Envir Pollut Technol 7:261
Wasserman GA et al (2006) Water manganese exposure and children’s intellectual function in Araihazar. Bangladesh Environ Health Perspect 114:124
WHO (2011) Guidelines for Drinking-Water Quality, 4th edn. World health organization, Geneva
WHO (2004) Information products: water sanitation and health. World Health Organization Geneva, Switzerland
Wilding L Spatial variability: its documentation, accommodation and implication to soil surveys. In: Nielsen D, Bouma J (eds) Soil spatial variability, Wageningen, 1985. Pudoc, pp 166–194
Wongsasuluk P, Chotpantarat S, Siriwong W, Robson M (2014) Heavy metal contamination and human health risk assessment in drinking water from shallow groundwater wells in an agricultural area in Ubon Ratchathani province, Thailand. Environ Geochem Health 36(1):169–182
Wu J, Li P, Qian H, Duan Z, Zhang X (2014) Using correlation and multivariate statistical analysis to identify hydrogeochemical processes affecting the major ion chemistry of waters: a case study in Laoheba phosphorite mine in Sichuan, China. Arab J Geosci 7:3973–3982
Wu J, Li P, Qian H (2015) Hadrochemical characterization of drinking groundwater with special reference to fluoride in an arid area of China and the control of aquifer leakage on its concentrations. Environ Earth Sci 73:8575–8588. https://doi.org/10.1007/s12665-015-4018-2
Acknowledgements
The authors are very grateful to the National Council for Tertiary Education (NTCE), Ghana for a research Grant under the Teaching and Learning Innovation Fund (TALIFKNUSTR/3/005/2005). We also want to acknowledge DR. D. D. Wemengah of the Department of Physics, Kwame Nkrumah University of Science and Technology, Kumasi, for drawing the geological maps of the two regions.
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Asare-Donkor, N.K., Adimado, A.A. Groundwater quality assessment in the Northern and Upper East Regions of Ghana. Environ Earth Sci 79, 205 (2020). https://doi.org/10.1007/s12665-020-08956-x
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DOI: https://doi.org/10.1007/s12665-020-08956-x