Skip to main content

Advertisement

Log in

Assessment of the geochemical evolution of groundwater quality near the El Kharga Oasis, Egypt using NETPATH and water quality indices

  • Original Article
  • Published:
Environmental Earth Sciences Aims and scope Submit manuscript

Abstract

The Nubian Sandstone Aquifer (NSA) has been the main source of water in the western desert of Egypt since 1985. This aquifer is subject to excessive groundwater withdrawal in the region, causing declines in potentiometric heads and a deterioration of groundwater quality. Consequently, investigations were undertaken to provide baseline water quality information for groundwater management. Water quality data from wells in the study area were manipulated using a Geographic Information System (GIS), statistical analyses (SPSS), graphical simulations (such as Piper and Gibbs diagrams), water quality index (WQI) and a simple geochemical model (NETPATH). This assessment and the use of hydrochemical indices indicated that chemical reactions between the aquifer matrix and groundwater are likely to be the main factors controlling the chemical composition of groundwater in the area. Also, the results of WQI showed that the majority of the collected water points (about 89%) were unsuitable for potable use due to elevated iron concentrations. The NETPATH modeling results suggest that dedolomitization, silicate weathering and dissolution of halite processes are the main geochemical processes that influence changes in the chemical composition along groundwater flow-paths.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11

Similar content being viewed by others

References

  • Aeschbach-Hertig W, Gleeson T (2012) Regional strategies for the accelerating global problem of groundwater depletion. Nature 5(12):853–861

    Google Scholar 

  • General Authority for Rehabilitation Projects and Agricultural Development (GARPAD) (1998)–2001. Lithologic logs and geophysical logs of water wells, Darb El Arbaein, Southwestern Desert

  • Berry K (1995) Spatial reasoning for effective GIS. GIS World Books, Fort Collins

    Google Scholar 

  • Brown E, Skougstad MW, Fishman MJ (1970) Methods for collection and analysis of water samples for dissolved minerals and gases: techniques of water resources. Investig US Geol Surv 5:160

    Google Scholar 

  • Brown RM, McCleiland NJ, Deininger RA, Oconnor MF (1972) A water quality index—crossing the psychological barrier. In: Proceedings of the International Conference on Water Pollution Research, Jerusalem, pp. 787–797

  • Custodio E, Bruggeman GA (1987) Groundwater problems in coastal areas. UNESCO

  • Custodio E, Llamas MR (1983) Hydrogeoquimica. In: Editores, Hidrología Subterránea, 2ª edición. Ed. Omega, Barcelona

  • Dawoud MA, Darwish MM, El-Kady MM (2005) GIS-based groundwater management model for Western Nile Delta. Water Resour Manag 19(5):585–604. https://doi.org/10.1007/s11269-005-5603-z

    Article  Google Scholar 

  • Duffield GM (2007) AQTESOLV for windows version 4.5 User's guide. HydroSOLVE, Inc., Reston, VA

  • El Osta M (2018) Maximizing the management of groundwater resources in the Paris-Abu Bayan reclaimed area, Western Desert. Egypt. Arab J Geosci 11:642. https://doi.org/10.1007/s12517-018-3945-0

    Article  Google Scholar 

  • El Kashouty M, El Sayed E (2008) Geochemical modeling of the Nubian Sandstone aquifer in Darb El Arbaein area, western Desert Egypt. Assiut Univ J Geol 37(2):1–23

    Google Scholar 

  • El Bastawesy M, Ali R, Faid A, El Osta MM (2013) Assessment of waterlogging in agricultural megaprojects in the closed drainage basins of the Western Desert of Egypt. Hydrol Earth Syst Sci 17:1493–1501

    Article  Google Scholar 

  • El Kadi A, Plummer L, Aggarwal P (2011) NETPATH-WIN: an interactive user version of the mass-balance model. NETPATH. Ground Water 49(4):593–599

    Article  Google Scholar 

  • El Osta M, Hussein H, Tomas K (2018) Numerical simulation of groundwater flow and vulnerability in wadi El-Natrun depression and vicinities, west Nile Delta Egypt. J Geol Soc India 92:235–247

    Article  Google Scholar 

  • Elango L, Kannan R (2007) Rock-water interaction and its control on chemical composition of groundwater. Chapter 11. Vol. 5. Developments in Environmental Science: Elsevier.

  • Elewa H, Fathy R, Qaddah A (2010) The contribution of geographic information systems and remote sensing in determining priority areas for hydrogeological development, Darb el-Arbain area, Western Desert Egypt. Hydrogeol J 18:1157–1171. https://doi.org/10.1007/s10040-010-0590-4

    Article  Google Scholar 

  • Fathy R, El Nagaty M, Atef A, El Gammal N (2002) Contribution of the hydrogeological and hydrochemical characteristics of Nubian sandstone aquifer in Darb El Arbaein, Southwestern Desert Egypt. Al-Azhar Bull Sci 13(2):69–100

    Google Scholar 

  • Fisher RS, Mullican WF (1997) Hydrochemical evolution of sodium-sulfate and sodium-chloride groundwater beneath the northern Chihuahuan Desert, Trans-Pecos, Texas, USA. Hydrogeol J 5:4–16

    Article  Google Scholar 

  • Furi W, Razack M, Abiye TA, Kebede S, Legesse D (2012) Hydrochemical characterization of complex volcanic aquifers in a continental rifted zone: the Middle Awash basin Ethiopia. Hydrogeol J. https://doi.org/10.1007/s10040-011-0807-1

    Article  Google Scholar 

  • Gheith H, Sultan M (2002) Construction of a hydrologic model for the estimating wadi runoff and groundwater recharge in the Eastern Desert Egypt. J Hydrol 263:36–55

    Article  Google Scholar 

  • Gibbs RJ (1970) Mechanisms controlling world water chemistry. Science 170:1088–1090. https://doi.org/10.1126/science.170.3962.1088

    Article  Google Scholar 

  • Giordano M (2009) Global groundwater Issues and solutions. Annu Rev Environ Resour 34(1):153–178

    Article  Google Scholar 

  • Hem JD (1989) Study and interpretation of chemical characteristics of natura waters. 3rd Edition, US Geological Survey Water Supply Paper 2254.

  • Jalali M (2007) Salinization of groundwater in arid and semi-arid zones: an example from Tajarak Western Iran. Environ Geol 52(6):1133–1149

    Article  Google Scholar 

  • Johnson A, Wichern W (1992) Applied multivariate statistical analysis. Prentice-Hall, Englewood Cliffs

    Google Scholar 

  • Judd G (1980) The use of cluster analysis in the derivation of geotechnical classification. Bull Assoc Eng Geol 17:193–211

    Google Scholar 

  • Kawo N, Karuppannan S (2018) Groundwater quality assessment using water quality index and GIS technique in Modjo River Basin, central Ethiopia. J Afr Earth Sc 147:300–311

    Article  Google Scholar 

  • Masoud M, Schneider M, El Osta M (2013) Recharge flux to the Nubian Sandstone aquifer and its impact on the present development in southwest Egypt. J Afr Earth Sc 85:115–124. https://doi.org/10.1016/j.jafrearsci.2013.03.009

    Article  Google Scholar 

  • Mohamed RF, Hua CZ (2010) Regional groundwater flow modeling in Western Nile Delta Egypt. World Rural Observ 2(2):37–42

    Google Scholar 

  • Mossad A, Mehawed HS, El-Araby A (2014) Seasonal drought dynamics in El-Beheira governorate Egypt. Am J Environ Sci 10(2):140–147. https://doi.org/10.3844/ajessp.2014.140.147

    Article  Google Scholar 

  • Nessim B, Hermine RZ, Amaal EA, Madelyn NM (2015) Chemistry of the Egyptian Mediterranean coastal waters. Egypt J Aquat Res. https://doi.org/10.1016/j.ejar.2015.01.004

    Article  Google Scholar 

  • Nicoll K (2004) Recent environmental change andprehistoric human activity in Egypt and Northern Sudan. Quaternary Sci Rev 23:561–580

    Article  Google Scholar 

  • Nwankwoala HO, Udom GJ (2011) Studies on major ion chemistry and hydrogeochemical processes of groundwater in Port Harcourt City Southern Nigeria. J Spat Hydrol 11(1):34–40

    Google Scholar 

  • Parkhurst DL, Plummer LN, Thorstenson DC (1982) Balance—a computer program for calculation of chemical mass balance. US Geol Surv WRIR 82–14:29p

    Google Scholar 

  • Piper AM (1944) A graphic representation in the geochemical interpretation of groundwater analyses. Am Geophys Union Trans USA 25:914–923

    Article  Google Scholar 

  • Plummer LN, Prestemon EC, Parkhurst DL (1994) An interactive code (NETPATH) for modeling net geochemical reactions along a flow path Version 2.0. Water-Resources Investigations Report 94–4169. Reston, Virginia: US Geological Survey. https://wwwbrr.cr.usgs.gov/projects/GWCcoupled/netpath/

  • RamyaPriya R, Elango L (2018) Evaluation of geogenic and anthropogenic impacts on spatio-temporal variation in quality of surface water and groundwater along Cauvery River India. Environ Earth Sci. https://doi.org/10.1007/s12665-017-7176-6

    Article  Google Scholar 

  • Rummel J (1970) Applied factor analysis. Northwestern University Press, Evanston

    Google Scholar 

  • Sahu P, Sikdar PK (2008) Hydrochemical framework of the aquifer in and around East Kolkata wetlands, West Bengal, India. Environ Geol 55:823–835

    Article  Google Scholar 

  • Srinivasamoorthy K, Chidambaram M, Prasanna MV, Vasanthavigar M, Peter J, Anandhan P (2008) Identification of major sources controlling groundwater chemistry from a hard rock terrain—a case study from Metturtaluk, Salem district, Tamilnadu, India. J Earth Syst Sci 117:49–58. https://doi.org/10.1007/s12040-008-0012-3

    Article  Google Scholar 

  • Switzman H, Coulibaly P, Adeel Z (2015) Modeling the impacts of dryland agricultural reclamation on groundwater resources in Northern Egypt using sparse data. J Hydrol 520:420–438. https://doi.org/10.1016/j.jhydrol.2014.10.064

    Article  Google Scholar 

  • Wu J, Li P, Qian H, Duan Z, Zhang X (2014) Using correlation and multivariate statistical analysis to identify hydrogeochemical processes affecting the major ion chemistry of waters: case study in Laoheba phosphorite mine in Sichuan China. Arab J Geosci 7(10):3973–3982. https://doi.org/10.1007/s12517-013-1057-4

    Article  Google Scholar 

  • Zammouri M, Siegfried T, El-Fahem T, Kriâa S, Kinzelbach W (2007) Salinization of groundwater in the Nefzawa Oases Region, Tunisia: results of a regional-scale hydrogeologic approach. Hydrogeol J 15(7):1357–1375

    Article  Google Scholar 

Download references

Acknowledgements

This work was supported by the Deanship of Scientific Research (DSR), King Abdulaziz University, Jeddah, under grant No. (D-012-123-1440). The authors, therefore, gratefully acknowledge the DSR technical and financial support.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Maged El Osta.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

El Osta, M., Masoud, M. & Ezzeldin, H. Assessment of the geochemical evolution of groundwater quality near the El Kharga Oasis, Egypt using NETPATH and water quality indices. Environ Earth Sci 79, 56 (2020). https://doi.org/10.1007/s12665-019-8793-z

Download citation

  • Received:

  • Accepted:

  • Published:

  • DOI: https://doi.org/10.1007/s12665-019-8793-z

Keywords

Navigation