Abstract
The expansion of pure quartz sandstones is investigated during spontaneous imbibition of fluids. The selected Fontainebleau sandstone samples cover a wide variation in their petrophysical properties (e.g., porosity, permeability, P-wave velocity, and effective pore size), and demonstrate expansion and shrinkage during spontaneous imbibition of fluids with different surface tension. The capillary forces cause a spontaneous imbibition of the fluid into the pore space. The wetting of the mineral grains causes a volume strain to the matrix that can be recorded as an expansion. If the rigidity of the matrix is weak, a shrinkage of the sample is observed instead of expansion. The experiments have shown that the relative expansion depends on the surface tension of the imbibing fluid, the degree of saturation, the rigidity, and the effective pore radius of the sandstone sample.






Similar content being viewed by others
References
Bourbie T, Zinszner B (1985) Hydraulic and acoustic properties as a function of porosity in Fontainebleau sandstone. J Geophys Res 90(B13):11524–11532. https://doi.org/10.1029/JB090iB13p11524
Bush JWM (2010) 18.357 Interfacial phenomena, fall. Massachusetts Institute of Technology: MIT OpenCourseWare. Creative Commons BY-NC-SA, License. https://ocw.mit.edu. Accessed 3 Jan 2017
Camuffo D (1995) Physical weathering of stones. Sci Total Environ 167:1–14
de Gennes P-G, Brochard-Wyart F, Quéré D (2004) Capillarity and wetting phenomena: drops, bubbles, pearls, waves. Springer, New York. https://doi.org/10.1007/978-0-387-21656-0
Delgado-Rodrigues J, Charola AE (1996) General report on water repellents. Sci Technol Cult Heritage 5:93–103
Hörenbaum W (2004) Verwitterungsmechanismen und Dauerhaftigkeit von Sandsteinsichtmauer-werk. Dissertation, TH Karlsruhe
Klopfer H (1985) Feuchte. In: Lutz P, Jenisch R, Klopfer H et al (ed) Lehrbuch der Bauphysik. Teubner, Stuttgart
Kocher M (2005) Quelldruckmessungen und thermische Druckmessungen an ausgewählten Sandsteinen. Dissertation, LMU München
Kowalski SJ (2002) Mechanical aspect on drying and wet porous media. In: Ehlers W, Bluhm J (ed) Porous media—theory, experiments and numerical applications. Springer, Berlin, pp 178–181
Kralchevsky PA, Nagayama K (2001) Particles at fluid interfaces and membranes (attachment of colloid particles and proteins to interfaces and formation of two-dimensional arrays). Elsevier, Amsterdam
Künzel HM (1994) Verfahren zur ein- und zweidimensionalen Berechnung des gekoppelten Wärme- und Feuchtetransports in Bauteilen mit einfachen Kennwerten. Dissertation, Universität Stuttgart
Marquis de Laplace PS (1805) Traité de Mécanique Céleste. Supplément au dixième livre du Traité de Mécanique Céleste, vol 4. Courcier, Paris
Page KL, Proffen Th, McLain SE, Darling TW, TenCate JA (2004) Local atomic structure of Fontainebleau sandstone: evidence for an amorphous phase? Geophys Res Lett 31:L24606. https://doi.org/10.1029/2004GL021717
Rüdrich J, Kirchner D, Seidel M, Siegesmund S (2005) Beanspruchungen von Naturwerksteinen durch Salz- und Eiskristallisation im Porenraum sowie hygrische Dehnungsvorgänge. Z dt Ges Geowiss 156/1:59–73. https://doi.org/10.1127/1860-1804/2005/0156-0059
Rüdrich J, Bartelsen T, Dohrmann R, Siegesmund S (2011) Moisture expansion as a deterioration factor for sandstone used in buildings. Environ Earth Sci 63:1545–1564. https://doi.org/10.1007/s12665-010-0767-0
Siegesmund S, Dürrast H (2014) Physical and mechanical properties of rocks. In: Siegesmund S, Snethlage R (eds) (2014) Stone in architecture. Springer, Heidelberg
Siegesmund S, Weiss T, Vollbrecht A (2002) Natural stone, weathering phenomena, conservation strategies and case studies, vol 205. Geological Society, Special Publications, London, pp 1–7
Smits AJ (2000) A physical introduction to fluid mechanics, 2nd edn. Wiley, New York
Stück H, Koch R, Siegesmund S (2013) Petrographical and petrophysical properties of sandstones: statistical analysis as an approach to predict material behaviour and construction suitability. Environ Earth Sci 69:1299–1332. https://doi.org/10.1007/s12665-012-2008-1
Thiery M, Millot R, Innocent C, Franke C (2015) The Fontainebleau sandstone: bleaching, silicification and calcite precipitation under periglacial conditions. Technical Report, AIG-11 Applied Isotope Geochemistry Conference 2015, Orléans, France
Weiss T, Siegesmund S, Kirchner D, Sippel J (2004) Insolation weathering and hygric dilatation: two competitive factors in stone degradation. Environ Geol 46:402–413. https://doi.org/10.1007/s00254-004-1041-0
Wittmann FH (1977) Grundlagen eines Modells zur Beschreibung charakteristischer Eigenschaften des Betons. Deutscher Ausschuss für Stahlbeton, Heft 290. Verlag Wilhelm Ernst und Sohn, Berlin
Young T (1805) An essay on the cohesion of fluids. Philos Trans R Soc Lond 95:65–87
Acknowledgements
The authors gratefully acknowledges the support from grant no. WE1557/16 funded by the Deutsche Forschungsgemeinschaft (DFG). Special thanks go to Stephan Kaufhold (Bundesanstalt für Geowissenschaften und Rohstoffe, Hannover, Germany) and Matthias Halisch (Leibniz-Institut für Angewandte Geophysik, Hannover, Germany) for providing the results of geochemical and petrophysical investigations on the sandstone samples.
Author information
Authors and Affiliations
Corresponding author
Additional information
This article is part of a Topical Collection in Environmental Earth Sciences on “Stone in the Architectural Heritage: from quarry to monuments—environment, exploitation, properties, and durability”, guest edited by Siegfried Siegesmund, Luís Sousa, and Rubén Alfonso López-Doncel.
Rights and permissions
About this article
Cite this article
Möller, M., Buntebarth, G. & Weller, A. Expansion and shrinkage of sandstones during spontaneous imbibition of fluids. Environ Earth Sci 77, 571 (2018). https://doi.org/10.1007/s12665-018-7753-3
Received:
Accepted:
Published:
DOI: https://doi.org/10.1007/s12665-018-7753-3


