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Hydrogeochemistry and groundwater quality assessment of the multilayered aquifer in Lower Kelantan Basin, Kelantan, Malaysia

  • Anuar Sefie
  • Ahmad Zaharin Aris
  • Mohammad Firuz Ramli
  • Tahoora Sheikhy Narany
  • Mohd Khairul Nizar Shamsuddin
  • Syaiful Bahren Saadudin
  • Munirah Abdul Zali
Original Article

Abstract

Continual expansion of population density, urbanization, agriculture, and industry in most parts of the world has increased the generation of pollution, which contributes to the deterioration of surface water quality. This causes the dependence on groundwater sources for their daily needs to accumulate day by day, which raises concerns about their quality and hydrogeochemistry. This study was carried out to increase understanding of the geological setup and assess the groundwater hydrogeochemical characteristics of the multilayered aquifers in Lower Kelantan Basin. Based on lithological data correlation of exploration wells, the study area can be divided into three main aquifers: shallow, intermediate and deep aquifers. From these three aquifers, 101 groundwater samples were collected and analyzed for various parameters. The results showed that pH values in the shallow, intermediate and deep aquifers were generally acidic to slightly alkaline. The sequences of major cations and anions were Na+ > Ca2+ > Mg2+ > K+ and HCO3 > Cl > SO42− > CO32−, respectively. In the intermediate aquifer, the influence of ancient seawater was the primary factor that contributed to the elevated values of electrical conductivity (EC), Cl and total dissolved solids (TDS). The main facies in the shallow aquifer were Ca–HCO3 and Na–HCO3 water types. The water types were dominated by Na–Cl and Na–HCO3 in the intermediate aquifer and by Na–HCO3 in the deep aquifer. The Gibbs diagram reveals that the majority of groundwater samples belonged to the deep aquifer and fell in the rock dominance zone. Shallow aquifer samples mostly fell in the rainfall zone, suggesting that this aquifer is affected by anthropogenic activities. In contrast, the results suggest that the deep aquifer is heavily influenced by natural processes.

Keywords

Hydrogeochemistry Multilayered aquifer Sequences of major ions Hydrochemical facies Seawater remnant 

Notes

Acknowledgements

The authors would like to thank the Ministry of Natural Resources and Environment (NRE) for providing research funds to this study under the National Water Resources Council (P23101110117300). The authors also wish to thank the Minerals and Geoscience Department of Malaysia for allowing the use of their groundwater quality data and assistance during the collection of groundwater samples from their monitoring wells.

References

  1. Aghazadeh N, Mogaddam AA (2011) Investigation of hydrochemical characteristics of groundwater in the Harzandat aquifer, Northwest of Iran. Environ Monit Assess 176(1):183–195CrossRefGoogle Scholar
  2. Ahamed AJ, Loganathan K, Jayakumar R (2015) Hydrochemical characteristics and quality assessment of groundwater in Amaravathi river basin of Karur district, Tamil Nadu, South India. Sustain Water Resour Manag 1(3):273–291.  https://doi.org/10.1007/s40899-015-0026-3 CrossRefGoogle Scholar
  3. Ahmad AK, Mushrifah I, Othman MS (2009) Water quality and heavy metal concentrations in sediment of Sungai Kelantan, Kelantan, Malaysia: a baseline study. Sains Malays 38(4):435–442Google Scholar
  4. American Public Health Association (APHA) (1995) Standard methods for the examination of water and wastewater. American Public Health Association, American Water Works Association, Water Environment Federation, WashingtonGoogle Scholar
  5. Amiri V, Sohrabi N, Dadgar MA (2015) Evaluation of groundwater chemistry and its suitability for drinking and agricultural uses in the Lenjanat plain, central Iran. Environ Earth Sci 74(7):6163–6176CrossRefGoogle Scholar
  6. Ang NK, Mohamad IC (1996) Groundwater monitoring report Peninsular Malaysia 1995 (Kelantan). Geological Survey of Malaysia, Report GPH 4/96, Kuala LumpurGoogle Scholar
  7. Appelo CAJ, Postma D (2004) Geochemistry, groundwater and pollution. CRC press, Boca RatonGoogle Scholar
  8. Aris AZ, Abdullah MH, Kim KW (2007) Hydrogeochemistry of groundwater in Manukan Island, Sabah. Malays J Anal Sci 11(2):407–413Google Scholar
  9. Bachik AR (1989) Groundwater monitoring system in the eastern Sungai Kelantan Delta, Kelantan. Geological Survey of Malaysia, Report GPH 05/1989, Kuala LumpurGoogle Scholar
  10. Back W, Baedecker MJ, Wood WW (1993) Scales in chemical hydrogeology: a historical perspective. In: Alley W (ed) Regional ground water quality. Van Nostrand Reinhold, New York, pp 111–128Google Scholar
  11. Bosch JHA (1986) Young Quaternary sediments in the coastal plain of Kelantan, Peninsular Malaysia. Geological Survey Malaysia, Quaternary Geology Section Report No. QG/2. 42, Kuala LumpurGoogle Scholar
  12. Cheong JY, Hamm SY, Lee JH, Lee KS, Woo NC (2012) Groundwater nitrate contamination and risk assessment in an agricultural area, South Korea. ‎Environ Earth Sci 66(4):1127–1136CrossRefGoogle Scholar
  13. Chidambaram S, Senthil Kumar G, Prasanna MV, John Peter A, Ramanthan AL, Srinivasamoorthy K (2009) A study on the hydrogeology and hydrogeochemistry of groundwater from different depths in a coastal aquifer: Annamalai Nagar, Tamilnadu, India. Environ Geol 57(1):59–73.  https://doi.org/10.1007/s00254-008-1282-4 CrossRefGoogle Scholar
  14. Connor R (2015) The United Nations world water development report 2015: water for a sustainable world (vol 1). UNESCO Publishing, ParisGoogle Scholar
  15. Deutsch WJ, Siegel R (1997) Groundwater geochemistry: fundamentals and applications to contamination. CRC Press, Boca RatonGoogle Scholar
  16. DOS (2010) Population distribution and basic demographic characteristic report. Department of Statistics, Kuala LumpurGoogle Scholar
  17. Drever JI (1988) The geochemistry of natural waters (vol 437). Prentice Hall, Englewood CliffsGoogle Scholar
  18. Ferguson G, Gleeson T (2012) Vulnerability of coastal aquifers to groundwater use and climate change. Nat Clim Change 2(5):342–345CrossRefGoogle Scholar
  19. Freeze AR, Cherry JA (1979) Ground Water. Prentice Hall, Inc., Englewood CliffsGoogle Scholar
  20. Gibbs RJ (1970) Mechanisms controlling world water chemistry. Science 170(3962):1088–1090CrossRefGoogle Scholar
  21. Giridharan L, Venugopal T, Jayaprakash M (2008) Evaluation of the seasonal variation on the geochemical parameters and quality assessment of the groundwater in the proximity of River Cooum, Chennai, India. Environ Monit Assess 143(1):161–178CrossRefGoogle Scholar
  22. Gnanachandrasamy G, Ramkumar T, Venkatramanan S, Vasudevan S, Chung SY, Bagyaraj M (2014) Accessing groundwater quality in lower part of Nagapattinam district, Southern India: using hydrogeochemistry and GIS interpolation techniques. Appl Water Sci 5(1):39–55CrossRefGoogle Scholar
  23. Hem JD (1989) Study and interpretation of the chemical characteristics of natural water. US Geological Survey, Water-Supply Paper 2254, United States Department of the Interior. United States Government Printing Office, Washington, D.C., p 263Google Scholar
  24. Idris AN, Aris AZ, Praveena SM, Suratman S, Tawnie I, Samsuddin MKN, Sefie A (2016) Hydrogeochemistry Characteristics in Kampong Salang, Tioman Island, Pahang, Malaysia. In: IOP Conference Series: Mater Sci Eng Conference Series, pp 012065.   https://doi.org/10.1088/1757-899X/136/1/012065
  25. Isa NM, Aris AZ, Sulaiman WNAW. (2012) Extent and severity of groundwater contamination based on hydrochemistry mechanism of sandy tropical coastal aquifer. Sci Total Environ 438:414–425CrossRefGoogle Scholar
  26. Jeevanandam M, Kannan R, Srinivasalu S, Rammohan V (2007) Hydrogeochemistry and groundwater quality assessment of lower part of the Ponnaiyar River Basin, Cuddalore district, South India. Environ Monit Assess 132(1–3):263–274CrossRefGoogle Scholar
  27. Karanth KR (1987) Ground Water Assessment, Development and Management. Tata McGraw-Hill Publ Com Ltd, New Delhi, IndiaGoogle Scholar
  28. Keesari T, Ramakumar KL, Chidambaram S, Pethperumal S, Thilagavathi R (2016) Understanding the hydrochemical behavior of groundwater and its suitability for drinking and agricultural purposes in Pondicherry area, South India-A step towards sustainable development. Groundw Sustain Dev 2:143–153CrossRefGoogle Scholar
  29. Kumar SK, Rammohan V, Sahayam JD, Jeevanandam M (2009) Assessment of groundwater quality and hydrogeochemistry of Manimuktha River basin, Tamil Nadu, India. Environ Monit Assess 159(1–4):341–351CrossRefGoogle Scholar
  30. Lakshmanan E, Kannan R, Kumar MS (2003) Major ion chemistry and identification of hydrogeochemical processes of ground water in a part of Kancheepuram district, Tamil Nadu, India. Environ Geosci 10(4):157–166CrossRefGoogle Scholar
  31. Larson TE, Buswell AM, Ludwig HF, Langelier WF (1942) Calcium carbonate saturation index and alkalinity interpretations. J Am Water Works Assoc 34(11):1667–1684Google Scholar
  32. Lim FY, Ong SL, Hu J (2017) Recent advances in the use of chemical markers for tracing wastewater contamination in aquatic environment: a review. Water 9(2):143CrossRefGoogle Scholar
  33. MacDonald S (1967) The geology and mineral resources of North Kelantan and North Terengganu. Geological Survey of Malaysia, Memoir 10, Kuala LumpurGoogle Scholar
  34. Malaysian Water Association (MWA) (2011) Malaysia Water Industry Guide 2011. Malaysian Water Association, Kuala LumpurGoogle Scholar
  35. Minerals and Geoscience Department (MGD) (2008) Geological map State of Peninsular Malaysia (1st edn). Ministry of Natural Resources and Environment, Kuala LumpurGoogle Scholar
  36. Ministry of Agriculture (MOA) (2010) Land use map of Peninsular Malaysia. Department of Agriculture, Kuala LumpurGoogle Scholar
  37. MMD (2012) Rainfall monthly data of Kota Bharu from 1989 to 2012. Malaysia Meteorological Department, Kuala LumpurGoogle Scholar
  38. Mohamad D (1983) Report on the environmental isotopic investigations in Lower Kelantan River Basin, Malaysia-Part III. IAEA Regional Cooperative Agreement-MAL 2623/R1/AG, Unit Tenaga Nuklear, Kuala LumpurGoogle Scholar
  39. Mokhtar M, Aris AZ, Abdullah MH, Yusoff MK, Abdullah MP, Idris AR, Raja Uzir RI (2009) A pristine environment and water quality in perspective: Maliau Basin, Borneo’s mysterious world. Water Environ J 23(3):219–228CrossRefGoogle Scholar
  40. Narany TS, Aris AZ, Sefie A, Keesstra S (2017) Detecting and predicting the impact of land use changes on groundwater quality, a case study in Northern Kelantan, Malaysia. Sci Total Environ 599:844–853CrossRefGoogle Scholar
  41. Noor IBM (1980) Prefeasibility study of potential groundwater development in Kelantan, Malaysia. Dissertation. University of Birmingham, United KingdomGoogle Scholar
  42. Park SC, Yun ST, Chae GT, Yoo IS, Shin KS, Heo CH, Lee SK (2005) Regional hydrochemical study on salinization of coastal aquifers, western coastal area of South Korea. J Hydrol 313(3):182–194CrossRefGoogle Scholar
  43. Parkhurst DL, Appelo CAJ (1999) User's guide to PHREEQC (Version 2): A computer program for speciation, batch-reaction, one-dimensional transport, and inverse geochemical calculations, Water-Resources Investigations, Report 99–4259, Denver, Co, USAGoogle Scholar
  44. Piper AM (1944) A graphic procedure in the geochemical interpretation of water-analyses. EOS Am Geophys Union Trans 25(6):914–928CrossRefGoogle Scholar
  45. Polemio M, Dragone V, Limoni PP (2006) Salt contamination in Apulian aquifer: spatial and time trend. In: Proceedings of 1st SWIM-SWICA (19th salt water intrusion meeting–3rd Salt water intrusion in coastal aquifers), CagliariGoogle Scholar
  46. Prasanna MV, Chidambaram S, Srinivasamoorthy K (2010) Statistical analysis of the hydrogeochemical evolution of groundwater in hard and sedimentary aquifers system of Gadilam river basin, South India. J King Saud Univ Sci 22(3):133–145CrossRefGoogle Scholar
  47. Rao NS, Rao PS, Reddy GV, Nagamani M, Vidyasagar G, Satyanarayana NLVV (2012) Chemical characteristics of groundwater and assessment of groundwater quality in Varaha River Basin, Visakhapatnam District, Andhra Pradesh, India. Environ Monit Assess 184(8):5189–5214CrossRefGoogle Scholar
  48. Samsudin AR, Haryono A, Hamzah U, Rafek AG (2008) Salinity mapping of coastal groundwater aquifers using hydrogeochemical and geophysical methods: a case study from north Kelantan, Malaysia. Environ Geol 55(8):1737–1743CrossRefGoogle Scholar
  49. Shamshuddin J, Kang MSK, Fauziah CI, Panhwar QA (2013) On the pyritization of the coastal sediments in the Malay Peninsula during the Holocene and its effects on soil. Malays J Soil Sci 17:1–15Google Scholar
  50. Sheikhy Narany T, Ramli MF, Aris AZ, Sulaiman WN, Juahir H, Fakharian K (2014) Identification of the hydrogeochemical processes in groundwater using classic integrated geochemical methods and geostatistical techniques, in Amol-Babol plain. Iran Sci World J 2014:15Google Scholar
  51. Singh N, Singh RP, Kamal V, Sen R, Mukherjee S (2015) Assessment of hydrogeochemistry and the quality of groundwater in 24-Parganas districts, West Bengal. Environ Earth Sci 73(1):375–386CrossRefGoogle Scholar
  52. Sprinkle CL (1989) Geochemistry of the Floridan aquifer system in Florida and in parts of Georgia, South Carolina, and Alabama. US Geol Surv Prof Pap 1403-I, WashingtonGoogle Scholar
  53. Srinivasamoorthy K, Chidambaram S, Prasanna MV, Vasanthavihar M, Peter J, Anandhan P (2008) Identification of major sources controlling groundwater chemistry from a hard rock terrain-a case study from Mettur taluk, Salem district, Tamil Nadu, India. J Earth Syst Sci 117(1):49–58CrossRefGoogle Scholar
  54. Srinivasamoorthy K, Vasanthavigar M, Chidambaram S, Anandhan P, Sarma VS (2011) Characterisation of groundwater chemistry in an eastern coastal area of Cuddalore district, Tamil Nadu. J Geol Soc India 78(6):549–558CrossRefGoogle Scholar
  55. Sundaram B, Feitz A, Caritat P, de Plazinska A, Brodie R, Coram J, Ransley T (2009) Groundwater sampling and analysis—a field guide. Geoscience Australia, Record 2009/27, AustraliaGoogle Scholar
  56. Suratman S (1997) Groundwater protection in north Kelantan, Malaysia: an integrated mapping approach using modeling and GIS. Dissertation, University of Newcastle Upon Tyne  Google Scholar
  57. Suswanto T, Shamshuddin J, Syed Omar SR, Mat P, Teh CBS (2007) Effects of lime and fertilizer application in combination with water management on rice (Oryza sativa) on an acid sulfate soil. Malays J Soil Sci 11:1–16Google Scholar
  58. Thivya C, Chidambaram S, Thilagavathi R, Prasanna MV, Singaraja C, Adithya VS, Nepolian M (2015) A multivariate statistical approach to identify the spatio-temporal variation of geochemical process in a hard rock aquifer. Environ Monit Assess 187(9):1–19CrossRefGoogle Scholar
  59. Tizro AT, Voudouris KS (2008) Groundwater quality in the semi-arid region of the Chahardouly basin, West Iran. Hydrol Process 22(6):3066–3078CrossRefGoogle Scholar
  60. Todd DK (1980) Groundwater hydrology, 2nd edn. Wiley, New YorkGoogle Scholar
  61. United Nations Educational Scientific and Cultural Organisation (UNESCO) (2012) World’s groundwater resources are suffering from poor governance. UNESCO Natural Sciences Sector News. UNESCO, ParisGoogle Scholar
  62. Van der Gun J (2012) Groundwater and global change: trends, opportunities and challenges. UNESCO Side Publication Series 01, UNESCO, ParisGoogle Scholar
  63. Varol S, Davraz A (2014) Assessment of geochemistry and hydrogeochemical processes in groundwater of the Tefenni plain (Burdur/Turkey). Environ Earth Sci 71(11):4657–4673CrossRefGoogle Scholar
  64. Vasanthavigar M, Srinivasamoorthy K, Prasanna MV (2012) Evaluation of groundwater suitability for domestic, irrigational, and industrial purposes: a case study from Thirumanimuttar river basin, Tamilnadu, India. Environ Monit Assess 184(1):405–420CrossRefGoogle Scholar
  65. Wan Mohd Zamri WI, Ismail Y, Bahaa-eldin EAR (2012) Simulation of horizontal well performance using Visual MODFLOW. Environ Earth Sci 68(4):1119–1126Google Scholar
  66. Yidana SM, Banoeng-Yakubo B, Akabza TM (2010) Analysis of groundwater quality using multivariate and spatial analyses in the Keta basin, Ghana. J Afr Earth Sci 58(2):220–234CrossRefGoogle Scholar

Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2018

Authors and Affiliations

  • Anuar Sefie
    • 1
    • 2
  • Ahmad Zaharin Aris
    • 2
  • Mohammad Firuz Ramli
    • 2
  • Tahoora Sheikhy Narany
    • 2
  • Mohd Khairul Nizar Shamsuddin
    • 1
  • Syaiful Bahren Saadudin
    • 1
  • Munirah Abdul Zali
    • 3
  1. 1.Hydrogeology Research CentreNational Hydraulic Research Institute of MalaysiaSeri KembanganMalaysia
  2. 2.Department of Environmental Sciences, Faculty of Environmental StudiesUniversiti Putra MalaysiaUPM SerdangMalaysia
  3. 3.Environment Section, Department of ChemistryPetaling JayaMalaysia

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