Abstract
Cold mineral water from the Wudalianchi springs (NE China), used in water supply and balneotherapy, attracts thousands of tourists here each year. Better understanding of the origin and hydrochemical processes for protection and sustainable use of the rare and precious resources is timely needed. Based upon the field investigations, the formation of the mineral waters and the hydrochemical evolution were comprehensively characterized using physical and chemical data analysis, ion ratio calculations, multivariate statistical methods and PHREEQC modeling in this work. The water–rock reactions and their possible chemical reactions during the water formation were studies to explain the mineral evolution. The results showed that the Yaoquanshan Mineral Water District in the study area is abundant in bicarbonate-type mineral water. The special physical and chemical evolution made the mineral waters unique for potable and therapeutic purposes owing to the combined effects including leaching, mixing, cation exchange and adsorption effect and anthropogenic activity.
Similar content being viewed by others
References
Cerling TE, Pederson BL, Von Damm KL (1989) Sodium–calcium ion exchange in the weathering of shales: implications for global weathering budgets. Geology 17(6):552
Chadha DK (1999) A proposed new diagram for geochemical classification of natural waters and interpretation of chemical data. Hydrogeol J 7(5):431–439
Chandrajith R, Barth JAC, Subasinghe ND, Merten D, Dissanayake CB (2013) Geochemical and isotope characterization of geothermal spring waters in Sri Lanka: evidence for steeper than expected geothermal gradients. J Hydrol 476(1):360–369
Chang J, Wang G (2010) Major ions chemistry of groundwater in the arid region of Zhangye Basin, northwestern China. Environ Earth Sci 61(3):539–547
Fisher RS, Iii WFM (1997) Hydrochemical evolution of sodium-sulfate and sodium-chloride groundwater beneath the northern Chihuahuan desert, Trans-Pecos, Texas, USA. Hydrogeol J 5(2):4–16
Guo X-M (2011) Mineral water of Wudalianchi and its medical applications. Stud Trace Elem Health 28(2):61–63 (in Chinese)
Hamzaoui-Azaza F, Ketata M, Bouhlila R, Gueddari M, Riberio L (2011) Hydrogeochemical characteristics and assessment of drinking water quality in Zeuss-Koutine aquifer, southeastern Tunisia. Environ Monit Assess 174(1–4):283–298
Kuritani T, Kimura JI, Ohtani E, Miyamoto H, Furuyama K (2013) Transition zone origin of potassic basalts from Wudalianchi volcano, northeast China. Lithos 156–159(1):1–12
Mayo AL, Loucks MD (1995) Solute and isotopic geochemistry and ground water flow in the central Wasatch Range, Utah. J Hydrol 172(1–4):31–59
Menció A, Mas-Pla J (2008) Assessment by multivariate analysis of groundwater–surface water interactions in urbanized mediterranean streams. J Hydrol 352(3–4):355–366
Meybeck M (1987) Global chemical weathering of surficial rocks estimated from river dissolved loads. Am J Sci 287(5):401–428
Pérezgranados AM, Navascarretero S, Schoppen S et al (2010) Reduction in cardiovascular risk by sodium-bicarbonated mineral water in moderately hypercholesterolemic young adults.[J]. J Nutr Biochem 21(10):948–953
Petraccia L, Liberati G, Masciullo SG et al (2006) Water, mineral waters and health[J]. Clin Nutr 25(3):377–385
Qian L-P, Wang X (2007) Geochemical characteristics of gases in springs of Wudalianchi. Yangtze River 38(11):188–191 (in Chinese)
Rajmohan N, Elango L (2004) Identification and evolution of hydrogeochemical processes in the groundwater environment in an area of the Palar and Cheyyar River Basins, Southern India. Environ Geol 46(1):47–61
Sami K (1992) Recharge mechanisms and geochemical processes in a semi-arid sedimentary basin, Eastern Cape, South Africa. J Hydrol 139(1–4):27–48
Wang Y, Chen H (2005) Tectonic controls on the Pleistocene–Holocene Wudalianchi volcanic field (northeastern China). J Asian Earth Sci 24(4):419–431
Wu J, Li P, Qian H, Duan Z, Zhang X (2014) Using correlation and multivariate statistical analysis to identify hydrogeochemical processes affecting the major ion chemistry of waters: a case study in Laoheba phosphorite mine in Sichuan, China. Arab J Geosci 7(10):1–10
Xiao L, Wang C (2009) Geologic features of Wudalianchi volcanic field, northeastern China: implications for martian volcanology. Planet Space Sci 57(5):685–698
Yang Q, Li Z, Ma H, Wang L, Martín JD (2016) Identification of the hydrogeochemical processes and assessment of groundwater quality using classic integrated geochemical methods in the southeastern part of ordos basin, china. Environ Pollut 218:879–888
Zhang Y, Wang Y, Li J, Geng C (1997) Research on isotopes and genesis of Yaoquanshan mineral water in Wudalianch Area. Heilongjiang Geol 8(4):108–122 (in Chinese)
Zhao JC (1985) Formation characteristics of Yaoquan mineral water in Wudalianchi. Heilongjiang Prov Hydrogeol Eng Geol 03:55–63 (in Chinese)
Acknowledgements
The authors would like to thank the National Natural Science Foundation of China (Grant nos. 41472237 and 41703125), Liaoning Innovation Team Project (no. LT2015017) and Research Programs of Heilongjiang Land & Resources for their financial support. We are also grateful for assistance from the Wudaliangchi Reserve Management during the field surveys.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Zhang, H., Yang, Y., Qi, H. et al. Hydrochemical evolution of rare cold mineral waters in the Wudalianchi UNESCO Global Geopark, China. Environ Earth Sci 77, 360 (2018). https://doi.org/10.1007/s12665-018-7543-y
Received:
Accepted:
Published:
DOI: https://doi.org/10.1007/s12665-018-7543-y