Abstract
The aim of this research is to determine the effective factors on the hydrogeochemistry and assessment of heavy metals pollution indices in the groundwater of Ardestan copper exploration area, Iran. In this study, in total, 111 groundwater samples from one well and several qanats and springs were collected. Piper and Stiff diagrams and statistical methods and quality indices were applied to hydrochemical data. Afterward, the water samples were classified into four groups, namely CaHCO3, CaCl, NaCl, and NaHCO3. According to evaluation indices, considering the fact that only a few points are in the high risk level, the groundwater of the study area has a low level of pollution. On the other hand, the pH of the groundwater of the region was mostly neutral and acid mine drainage was not found. Since the condition of the area is in pre-mining process, two factors are possibly influential: (1) rocks or minerals having sulfides are not exposed to an atmosphere (normally below groundwater) and H+ release does not occur and (2) the existence of minerals containing silicate and carbonate that can rapidly reduce acidification of water. Finally, it seems that during mining and in post-mining conditions, acid rock drainage which results from the oxidation of sulfides will probably influence the quality of water resources in Ardestan city. This is because the groundwater flow direction is from the mine toward Ardestan plain.
Similar content being viewed by others
References
Ahmadi S (2017) Assessment of Hydrochemistry and Heavy Metals of the Water Resources in the Ardestan Copper Mine Area, Isfahan Province, Iran. M.Sc. Dissertation, University of Sistand and Balichestan, Zahedan, Iran
Alberto WD, Del Pilar DM, Valeria AM, Fabiana PS, Cecilia HA, De Los Angeles BM (2001) Pattern recognition techniques for the evaluation of spatial and temporal variations in water quality. A case study: Suquya River Basin (Cordoba–Argentina). Water Res 35:2881–2894
Alcalá FJ, Custodio E (2008) Atmospheric chloride deposition in continental Spain. Hydrol Process. https://doi.org/10.1002/hyp.6965
Alhamed M, Wohnlich S (2014) Environmental impact of the abandoned coal mines on the surface water and the groundwater quality in the south of Bochum Germany. Environ Earth Sci 72(9):3251–3267
APHA (1989) Standard methods for the examination of water and wastewater, 17th edn. American Public Health Association, New York City, pp 4–197
Appelo CAJ, Postma D (2005) Geochemistry, Groundwater and Pollution. Seconded, Balkema, Rotterdam
Ayantobo OO, Awomeso JA, Oluwasanya GO, Bada BS, Taiwo AM (2014) Gold mining in Igun Ijesha, southwest Nigeria: Impacts and implications for water quality. Am J Environ Sci 10(3):289–300
Bagheri R, Nadri A, Raeisi E, Eggenkamp HGM, Kazemi GA, Montaseri A (2014) Hydrochemical and isotopic (δ18O, δ2H, 87Sr/86Sr, δ37Cl and δ81Br) evidence for the origin of saline formation water in a gas reservoir. Chem Geol 384:62–75
Bhuiyan MAH, Parvez L, Islam MA, Dampare SB, Suzuki S (2010) Heavy metal pollution of coal mine-affected agricultural soils in the northern part of Bangladesh. J Hazard Mater 173:384–392
Duane MJ, Pigozzi G, Harris C (1997) Geochemistry of some deep gold mine waters from the western portion of the Witwatersrand Basin, South Africa. J Afr Earth Sc 24(1–2):105–123
Edet AE, Offiong OE (2002) Evaluation of water quality pollution indices for heavy metal contamination monitoring. A study case from Akpabuyo-Odukpani area, Lower Cross River Basin (southeastern Nigeria). Geo J 57:295–304
Flury M, Papritz A (1993) Bromide in the natural environment: occurrence and toxicity. J Environ Qual 22(4):747–758
Hamed Y, Ahmadi R, Demdoum A, Laouar R, Choura A (2014) Use of geochemical, isotopic, and age tracer data to develop models of groundwater flow: A case study of Gafsa mining basin-Southern Tunisia. J Afr Earth Sci 100:418–436
Huisamen A, Wolkersdorfer C (2016) Modelling the hydrogeochemical evolution of mine water in a decommissioned opencast coal mine. Int J Coal Geol 164:3–12
Jahanshahi R, Zare M (2015) Assessment of heavy metals pollution in groundwater of Golgohar iron ore mine area Iran. Environ Earth Sci 74:505–520
Jahanshahi R, Zare M (2016) Hydrochemical investigations for delineating salt-water intrusion into the coastal aquifer of Maharlou Lake Iran. J Afr Earth Sci 121:16–29
Jahanshahi R, Zare M (2017) Delineating the origin of groundwater in the Golgohar Mine Area of Iran using stable isotopes of 2H and 18O and hydrochemistry. Mine Water Environ 36(4):550–563
Jahanshahi R, Zare M, Schneider M (2014) A metal sorption/desorption study to assess the potential efficiency of a tailings dam at the Golgohar Iron Ore Mine Iran. Mine Water Environ 33(3):228–240
Jannesar Malakooti S, Shahhosseini M, Doulati Ardejani F, Ziaeddin Shafaei Tonkaboni S, Noaparast M (2015) Hydrochemical characterisation of water quality in the Sarcheshmeh copper complex SE Iran. Environ Earth Sci 74(4):3171–3190
Lottermoser B (2007) Mine wastes characterization, treatment, environmental impacts. Springer Publisher, New York
Mohan SV, Nithila P, Reddy SJ (1996) Estimation of heavy metal in drinking water and development of heavy metal pollution index. J Environ Sci Health A31:283–289
Neogi B, Singh AK, Pathak DD, Chaturvedi A (2017) Hydrogeochemistry of coal mine water of North Karanpura coalfields, India: implication for solute acquisition processes, dissolved fluxes and water quality assessment. Environ Earth Sci 76(14):489
Prasanna MV, Praveena SM, Chidambaram S, Nagarajan R, Elayaraja A (2012) Evaluation of water quality pollution indices for heavy metal contamination monitoring: a case study from Curtin Lake, Miri City, East Malaysia. Environ Earth Sci 67:1987–2001
Sahraei Parizi H, Samani N (2013) Geochemical evolution and quality assessment of water resources in the Sarcheshmeh copper mine area (Iran) using multivariate statistical techniques. Environ Earth Sci 69:1699–1718
Sillitoe RH (2010) Porphyry Copper Systems. Econ Geol 105:3–41
Sun L, Gui H (2017) Water rock interaction in deep groundwater aquifers of coal mining area: qualitative and quantitative approaches based on hydrochemistry. Indian J Geo Mar Sci 46(5):877–883
World Health Organisation (WHO) (2011) Guidelines for drinking water quality (4th edn.). ISBN 9241546387
Acknowledgements
This work was partially supported by Ardestan Copper Gold Company. The authors would like to thank the Research Council of University of Sistan and Baluchestan for their financial support. Our sincere thanks are extended to Dr. M. Sharif.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Ahmadi, S., Jahanshahi, R., Moeini, V. et al. Assessment of hydrochemistry and heavy metals pollution in the groundwater of Ardestan mineral exploration area, Iran. Environ Earth Sci 77, 212 (2018). https://doi.org/10.1007/s12665-018-7393-7
Received:
Accepted:
Published:
DOI: https://doi.org/10.1007/s12665-018-7393-7