Abstract
Multivariate statistical analysis has been widely used for hydrogeochemical characterization of groundwater quality. In this study, hydrochemical data from three hydrological basins were used and two methods (factor and cluster analyses) were applied. The first area is the coastal area of Eastern Thermaikos Gulf where groundwater is influenced by seawater intrusion and geothermal fluids. The other two areas are the inland basins of Gallikos and Perdikas in which agricultural and industrial activities constitute the main anthropogenic pollution sources of groundwater. Initially, the aforementioned methods were applied for each area separately and resulted in a different number of significant factors and clusters, while the natural and anthropogenic influences were spatially determined in each area. Additionally, factor and cluster analyses were applied coupling data from all areas. Therefore, five clusters and three major factors were determined distinguishing the hydrochemical processes and impacts from anthropogenic activities in more detail. It is worth mentioning that the application of cluster analysis in the coupled groundwater samples of all studied areas resulted beneficially in the most hydrochemically complex area. Salinization dominates in the coastal area, while in Gallikos and Perdikas basins high concentrations of NO3 occur mainly due to agricultural activities and small livestock units. The numerous hydrochemical samples are identified as the main issue for the higher discretization and reliability of the second approach. Nevertheless, this study is associated with a number of limitations of multivariable statistical analysis regarding extreme concentrations of Cl and Na. This issue stimulates further research in overcoming and understanding these drawbacks.
Similar content being viewed by others
References
Adams S, Titus R, Pietersen K, Tredoux G, Harris C (2001) Hydrochemical characteristics of aquifers near Sutherland in the Western Karoo, South Africa. J Hydrol 241:91–103
Aeschbach-Hertig W, Gleeson T (2012) Regional strategies for the accelerating global problem of groundwater depletion. Nat Geosci 5:853–861
Alberto WD, del Pilar DM, Valeria AM, Fabiana PS, Cecilia HA, de los Angles BM (2001) Pattern recognition techniques for the evaluation of spatial and temporal variations in water quality, a case study: Suquia river basin (Cordoba–Argentina). Water Resour 35:2881–2894
Anazawa K, Ohmori H (2005) The hydrochemistry of surface waters in Andesitic Volcanic area, Norikura volcano, central Japan. Chemosphere 59:605–615
Appelo AJ, Postma D (2005) Geochemistry, groundwater and pollution, 2nd edn. A.A. Balkema, Amsterdam
Back W, Hanshaw BB (1965) Chemical geohydrology. Adv Hydrosci 2:49–109
Batabyal AK (2014) Correlation and multiple linear regression analysis of groundwater quality data of Bardhaman District, West Bengal, India. Int J Res Chem Environ 4(4):42–51
Belkhiri L, Narany TS (2015) Using multivariate statistical analysis, geostatistical techniques and structural equation modeling to identify spatial variability of groundwater quality. Water Resour Manag 29:2073–2089
Belkhiri L, Boudoukha A, Mouni L, Baouz T (2010) Application of multivariate statistical methods and inverse geochemical modeling for characterization of groundwater—a case study: Ain Azel plain (Algeria). Geoderma 159:390–398
Boniol D (1996) Summary of groundwater quality in the St. Johns River Water Management District. Special Publication SJ96-SP13. St. Johns River Water Management District, Palatka
Briz-Kishore BH, Murali G (1992) Factor analysis for revealing hydrochemical characteristics of a watershed. Environ Geol 19:3–9
Brown CE (1998) Applied multivariate statistics in geohydrology and related sciences. Springer, New York
Cao Y, Tang C, Song X, Liu C, Zhang Y (2014) Identifying the hydrochemical characteristics of rivers and groundwater by multivariate statistical analysis in the Sanjiang Plain, China. Appl Water Sci. doi:10.1007/s13201-014-0215-5
Cattell RB (1978) The scientific use of factor analysis in behavioral and life sciences. Plenum Press, New York
Chowdary VM, Rao NH, Sarma PBS (2005) Decision support frame work for assessment of non-point-source pollution of groundwater in large irrigation projects. Agric Water Manag 75:194–225
Clesceri L, Greenberg A, Trussell R (1989) Standard methods for the examination of water and wastewater, 17th edn. APHA-AWWA-WEF, Washington, DC
Cloutier V, Lefebvre R, Therrien R, Savard MM (2008) Multivariate statistical analysis of geochemical data as indicative of the hydrogeochemical evolution of groundwater in a sedimentary rock aquifer system. J Hydrol 353(3–4):294–313
Dalton MG, Upchurch SB (1978) Interpretation of hydrochemical facies by factor analysis. Ground Water 10:228–233
Davis JC (1986) Statistics and data analysis in geology. Wiley, New York
Davis JC (2002) Statistics and data analysis in geology. Wiley, New York
Einax JW, Zwanziger HW, Geib S (1997) Chemometrics in environmental analysis. VCH Verlagsgesellschaft mbh, Weinheim
Ezekwe IC, Odu NN, Chima GN, Opigo A (2012) Assessing regional groundwater quality and its health implications in the Lokpaukwu, Lekwesi and Ishiagu mining areas of southeastern Nigeria using factor analysis. Environ Earth Sci 67:971–986. doi:10.1007/s12665-012-1539-9
Huang G, Sun J, Zhang Y, Chen Z, Liu F (2013) Impact of anthropogenic and natural processes on the evolution of groundwater chemistry in a rapidly urbanized coastal area, South China. Sci Total Environ 463–464:209–221
Institute of Geology and Mineral Exploration (1983) Geological map of Greece 1:500000. Department of Geological Maps, Athens
Jeen SW, Kim JM, Ko KS, Yum B, Chang HW (2001) Hydrogeochemical characteristics of groundwater in a mid-western coastal aquifer system Korea. Geosci J 5(4):339–348
Kaiser HF (1958) The varimax criterion for analytic rotation in factor analysis. Psychometrika 23:187–200
Kallioras A, Pliakas F, Diamantis I, Emmanouil M (2006) Application of geographical information systems (GIS) for the management of coastal aquifers subjected to seawater intrusion. J Environ Sci Health Part A 41:2027–2044
Kazakis N, Pavlou A, Vargemezis G, Voudouris K, Soulios G, Pliakas F, Tsokas G (2016) Seawater intrusion mapping using electrical resistivity tomography and hydrochemical data. An application in the coastal area of eastern Thermaikos Gulf, Greece. Sci Total Environ 543:373–387
Kazakis N, Kantiranis N, Kalaitzidou K, Kaprara M, Mitrakas M, Frei R, Vargemezis G, Tsourlos P, Zouboulis A, Filippidis A (2017) Origin of hexavalent chromium in groundwater: the example of Sarigkiol Basin, Northern Greece. Sci Total Environ 593–594:552–566
Kim K, Rajmohan N, Kim H, Hwang GS, Cho J (2004) Assessment of groundwater chemistry in a coastal region (Kunsan, Korea) having complex contaminant sources: a stoichiometric approach. Environ Geology 46(6):763–774
Kumar P (2014) Evolution of groundwater chemistry in and around Vaniyambadi industrial area: differentiating the natural and anthropogenic sources of contamination. Chem Erde 74(2014):641–651
Lawley DN, Maxwell AE (1962) Factor analysis as a statistical method. Statistician 12:209–229
Liu C, Lin K, Kuo Y (2003) Application of factor analysis in the assessment of groundwater quality in a blackfoot disease area in Taiwa. Sci Total Environ 313:77–89
Locsey KL, Cox ME (2003) Statistical and hydrochemical methods to compare basalt- and basement rock-hosted groundwaters: Atheron Tablelands, northeastern Australia. Environ Geol 43(6):698–713
Lopez-Chicano M, Bouamama M, Vallejos A, Pulido BA (2001) Factors which determine the hydrogeochemical behavior of karstic springs: a case study from the Betic Cordilleras, Spain. Appl Geochem 16(9–10):1179–1192
MacDonald AM, Bonsor HC, Ahmed KM, Burgess WG, Basharat M, Calow RC, Dixit A, Foster SSD, Gopal K, Lapworth DJ, Lark RM, Moench M, Mukherjee A, RaoMS Shamsudduha M, Smith L, Taylor RG, Tucker J, Steenbergen F, Yadav SK (2012) Groundwater quality and depletion in the Indo-Gangetic Basin mapped from in situ observations. Nat Geosci 9:762–766
Mani A, Tsai F, TC, Kao SC, Naz BS, Ashfaq M, Rastogi D (2016) Conjunctive management of surface and groundwater resources under projected future climate change scenarios. J Hydrol 540:397–411
Masoud A (2014) Groundwater quality assessment of the shallow aquifers west of the Nile Delta (Egypt) using multivariate statistical and geostatistical techniques. J Afr Earth Sci 95:123–137
Mattas C (2009) Hydrogeological research of Gallikos basin. Ph.D. thesis, Department of Geology, Aristotle University of Thessaloniki (in Greek)
Mattas C, Voudouris K, Panagopoulos A (2014) Integrated groundwater resources management using the DPSIR approach in a GIS environment: a case study from the Gallikos River basin, North Greece. Water 6(4):1043–1068
Mencio A, Mas-Pla J (2008) Assessment by multivariate analysis of groundwater–surface water interactions in urbanized Mediterranean streams. J Hydrol 252:255–266
Moya C, Raiber M, Taulis M, Cox M (2015) Hydrochemical evolution and groundwater flow processes in the Galilee and Eromanga basins, Great Artesian Basin, Australia: a multivariate statistical approach. Sci Total Environ 508:411–426
Narvaez J, Richter P, Inestoral M (2007) Preliminary physical chemical characterization of river waters and sediments affected by copper mining activity in Central Chile. Application of multivariate analysis. J Chile Chem Soc 52:1261–1265
Niu B, Wang H, Loáiciga HA, Hong S, Shao W (2017) Temporal variations of groundwater quality in the Western Jianghan Plain, China. Sci Total Environ 578(2017):542–550
Omo-Irabor OO, Olobaniyi SB, Oduyemi K, Akunna J (2008) Surface and groundwater water quality assessment using multivariate analytical methods: a case study of the Western Niger Delta, Nigeria. Phys Chem Earth 33:666–673
Patrikaki O (2009) Hydrogeological research of Potamia basin, in Kozani Prefecture, in Northern Greece. PhD thesis, Department of Geology, Aristotle University of Thessaloniki (in Greek)
Patrikaki O, Kazakis N, Voudouris K (2012) Vulnerability map: a useful tool for groundwater protection: an example from Mouriki basin, North Greece. Fresenius Environ Bulletin 21(8c):2516–2521
Pereira HG, Renca S, Sataiva J (2003) A case study on geochemical anomaly identification through principal component analysis supplementary projection. Appl Geochem 18:37–44
Piper AM (1944) A graphical procedure in the geochemical interpretation of water analysis. Trans Am Geophys Union 25:914–923
Qian G, Gabor G, Gupta RP (1994) Principal components selection by the criterion of the minimum mean difference of complexity. J Multivar anal 49:55–75
Razak M, Dazy J (1990) Hydrogeochemical characterization of groundwater mixing sedimentary and metamorphic reservoirs with combined use of pipers principle and factor analysis. J Hydrol 114:371–393
Schilling KE, Wolter CF (2001) Contribution of base flow to non-point source pollution loads in an agricultural watershed. Ground Water 39:49–58
Shang H, Wang W, Dai Z, Duan L, Zhao Y, Zhang J (2016) An ecology-oriented exploitation mode of groundwater resources in the northern Tianshan Mountains, China. J Hydrol 543:386–394
Sibson R (1981) A brief description of natural neighbour interpolation. In: Barnett Vic (ed) Interpreting multivariate data. Wiley, New York, pp 21–35. ISBN 9780471280392
Singh A (2014) Groundwater resources management through the applications of simulation modeling: a review. Sci Total Environ 499:414–423
Slonim N, Atwal GS, Tkacik G, Bialek W (2005) Information-based clustering. Proc Natl Acad Sci 102:18297–18302
Voudouris K, Lambrakis N, Papatheodorou G, Daskalaki P (1997) An application of factor analysis for the study of the hydrogeological conditions in Plio-Pleistocene aquifers of NW Achaia (NW Peloponnesus, Greece). Math Geol 29(1):43–59
Voudouris K, Panagopoulos A, Koumantakis J (2000) Multivariate statistical analysis in the assessment of hydrochemistry of the Northern Korinthia Prefecture alluvial aquifer system (Peloponnesus, Greece). Nat Resour Res 9(2):135–146
Wada Y, Gleeson T, Esnault L (2014) Wedge approach to water stress. Nat Geosci 7:615–617
Weatherill G, Burton PW (2008) Delineation of shallow seismic source zones using K-means cluster analysis, with application to the Aegean region. Geophys J Int 176(2):565–588
Yidana SM, Ophori D, Banoeng-Yakubo B (2008) A multivariate statistical analysis of surface water chemistry data: the Ankobra Basin, Ghana. J Environ Manag 86(1):80–87
Zhang B, Song XF, Zhang YH, Han DM, Tang CY, Yu YL, Ma Y (2012) Hydrochemical characteristics and water quality assessment of surface water and groundwater in Songnen Plain, Northeast China. Water Res 46:2737–2748
Acknowledgements
This research was carried out within the framework of the Post Doc of Nerantzis Kazakis and was funded by the State Scholarships Foundation of Greece (I.K.Y.) through the Program “ΙΚΥ FELLOWSHIPS OF EXCELLENCE FOR POSTGRADUATE STUDIES IN GREECE—SIEMENS PROGRAM.”
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
Conflict of interest
The authors declare that they have no conflict of interest.
Rights and permissions
About this article
Cite this article
Kazakis, N., Mattas, C., Pavlou, A. et al. Multivariate statistical analysis for the assessment of groundwater quality under different hydrogeological regimes. Environ Earth Sci 76, 349 (2017). https://doi.org/10.1007/s12665-017-6665-y
Received:
Accepted:
Published:
DOI: https://doi.org/10.1007/s12665-017-6665-y