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Environmental Earth Sciences

, 76:181 | Cite as

Major factors influencing boron adsorption in sediments—a case study of modern sediments in Qinghai Lake

  • Changyong WangEmail author
  • Shiguo Lin
  • Yaqiong Wei
  • Yi Zhou
  • Hailiang Chang
  • Jiang Liu
Original Article

Abstract

Because the boron (B) concentration in water has an apparent positive correlation with salinity, the B content adsorbed in sediments is often regarded as an important indicator to reconstruct the water salinity in a sedimentary environment. The premise of the quantitative reconstruction of paleosalinity is that the B uptake in sediments is proportional to the B concentration in water; however, the study showed that there is no direct relationship. The B absorption in sediments can be affected by both the content of the clay minerals and the total organic carbon content. The data from testing modern sediments and water samples in the Qinghai Lake show that a higher content in clay minerals is beneficial for B adsorption. Furthermore, the organic carbon from halophiles has a strong effect on the enrichment of B. Therefore, the organic carbon content in sediments should be considered when the paleosalinity of water is reconstructed using its B content. It is also thought that the Adams and Couch formulas are not suitable for reconstructing the salinity of water with a high organic carbon content in sediments because they consider only the effect of clay minerals on the adsorbed B without the contribution of organic carbon.

Keywords

Paleosalinity Trace elements Halophile Organic carbon Saline lake 

Notes

Acknowledgements

We thank Jian Wei and Lei Wang from Chengdu University of Technology for sample collection and pretreatment. This work was supported financially by the National Natural Youth Science Foundation of China (Grant no. 41302088). Professor Wenwu Liu and other reviewers are acknowledged for his critical reviews, which led to improvement of this work.

References

  1. Adams TD, Haynes JR, Walker CT (1965) Boron in holocene illites of the dovey estuary, wales, and its relationship to palaeosalinity in cyclothems. J Sedimentol 4:189–195CrossRefGoogle Scholar
  2. Brooks DJ, Dewall AE (1976) Boron concentration in Chesapeake Bay sediments, paleosalinity and baymouth uplift. J Chesap Sci 3:221–224CrossRefGoogle Scholar
  3. Chinese Academy of Sciences (1979) Comprehensive investigation report of Qinghai Lake. Science Press, Beijing, pp 1–268 (in Chinese) Google Scholar
  4. Couch EL (1971) Calculation of paleosalinities from boron and clay mineral data. J AAPG 55(10):1829–1837Google Scholar
  5. Cui CZ, Ma L, Shi J, Lin KF, Luo QS, Liu YD (2014) Metabolic pathway for degradation of anthracene by halophilic Martelella sp. AD-3. J Int Biodeterior Biodegrad 89:67–73CrossRefGoogle Scholar
  6. Dong H, Song Y (2011) Shrinkage history of Lake Qinghai and causes during the last 52 years. In: Collected papers of international symposium on water resource and environmental protection (ISWREP), pp 446-449Google Scholar
  7. Eliana L, Tassi Pedron F, Barbafieri M (2011) Evaluating the absorption of boron by plants—a potential tool to remediate contaminated sediments from Cecina River Basin in Italy. J Water Air Soil Pollut 216:275–287CrossRefGoogle Scholar
  8. Eskenazy G, Delibaltova D, Mincheva E (1994) Geochemistry of boron in Bulgarian coals. Int J Coal Geol 25:93–110CrossRefGoogle Scholar
  9. Frederickson AF, Reynolds RC (1960) Geochemical method for determining paleosalinity. J Clays Clay Miner 8:203–213CrossRefGoogle Scholar
  10. Furst MJ (1981) Boron in siliceous materials as a paleosalinity indicator. J Geochim et Cosmochim Acta 45(1):1–13CrossRefGoogle Scholar
  11. Gao CL, Yu JQ, Zhan DP, Zhang LS, Cheng AY (2009) Formation and distribution characteristics of B resource in salt lakes of Qaidam basin. J J Salt Lake Res 4:6–13 (in Chinese) Google Scholar
  12. Goodarzi F, Swaine DJ (1994) The influence of geological factors on the concentration of boron in Australian and Canadian coals. J Chem Geol 118:301–318CrossRefGoogle Scholar
  13. Holloway MD, Sime LC, Singarayer JS, Tindall JC, Valdes PJ (2016) Reconstructing paleosalinity from δ18O: coupled model simulations of the Last Glacial Maximum, Last Interglacial and Late Holocene. J Quat Sci Rev 131:350–364CrossRefGoogle Scholar
  14. Hower JC, Ruppert LF, Williams DA (2002) Controls on boron and germanium distribution in the low-sulfur Amos coal bed, Western Kentucky coalfield. J Int J Coal Geol 53:27–42CrossRefGoogle Scholar
  15. Kushner DJ (1978) Life in high salt and solute concentrations: halophilic bacteria. In: Kushuner DJ (ed) Microbial life in extreme environments. Academic Press, London, pp 317–368Google Scholar
  16. Lerman A (1966) Boron in clays and estimation of paleosalinities. J Sedimentol 6(4):267–286CrossRefGoogle Scholar
  17. Li SY, Yu BS, Dong HL (2006) Study on organic matters in the sediments from the bottom of the Qinghai Lake, China. J Pet Geol Exp 28(4):375–379 (in Chinese with English abstract) Google Scholar
  18. Li ML, Mo DW, Mao LJ, Sun GP, Zhou KS (2010) Paleosalinity in the Tianluoshan site and the correlation between the Hemudu culture and its environmental background. J Geogr Sci 20(3):441–454CrossRefGoogle Scholar
  19. Liu YS, Zong KQ, Kelemen PB, Gao S (2008) Geochemistry and magmatichistory of eclogites and ultramafic rocks from the Chinese continental scientific drill hole: subduction and ultrahigh-pressure metamorphism of lower crustal cumulates. J Chem Geol 247:133–153CrossRefGoogle Scholar
  20. Liu WG, Li XZ, Zhang L (2009) Evaluation of oxygen isotopes in carbonate as an indicator of lake evolution in arid areas: the modem Qinghai Lake, Qinghai–Tibet Plateau. J Chem Geol 268:126–136CrossRefGoogle Scholar
  21. Rohling EJ (2000) Paleosalinity: confidence limits and future applications. J Mar Geol 163(1):1–11CrossRefGoogle Scholar
  22. Sampei Y, Matsumoto E, Dettman DL, Tokuoka T, Abe O (2005) Paleosalinity in a brackish lake during the Holocene based on stable oxygen and carbon isotopes of shell carbonate in Nakaumi Lagoon, southwest Japan. J Palaeogeogr Palaeoclimatol Palaeoecol 224(4):352–366CrossRefGoogle Scholar
  23. Shen GP, Zhu DR, Liu J, Han R, Long QF (2012) Isolation and characteristics of halophile microorganisms from Lake Qinghai. J Lake Sci 24:313–319 (in Chinese with English abstract) CrossRefGoogle Scholar
  24. Sun JC (1938) Qinghai Lake. J Geol Rev 3:507–517 (in Chinese) Google Scholar
  25. Walker CT (1968) Evaluation of boron as a paleosalinity indicator and its application to offshore prospects. J AAPG Bull 52(5):751–766Google Scholar
  26. Wang JT (2015) Who says Qinghai Lake will become Lop Nor. N People’s Daily 9:28 (in Chinese) Google Scholar
  27. Wang CY, Zheng RC, Liu Z, Liang XW, Li TY, Zhang JW, Li YL (2014) Paleosalinity of Chang 9 reservoir in Longdong area, Ordos Basin and its geological significance. J Acta Sedimentol Sin 32:159–165 (in Chinese with English abstract) Google Scholar
  28. Wingard GL, Hudley JW (2012) Application of a weighted-averaging method for determining paleosalinity: a tool for restoration of south Florida’s estuaries. J Estuar Coasts 35(1):262–280CrossRefGoogle Scholar
  29. Wu JJ, Wang JP, Chen L, Zhao SL, Wang YF (2014) The area change of Buha river estuary delta during the period of 1970–2010. J Salt Lake Res 22(2):8–13 (in Chinese with English abstract) Google Scholar
  30. Zhu DR, Liu J, Han R, Shen GP, Yang F, Long QF, Liu DL (2012) Population diversity and phylogeny of halophiles in the Qinghai Lake. J Biodivers Sci 20(4):495–504 (in Chinese with English abstract) Google Scholar

Copyright information

© Springer-Verlag Berlin Heidelberg 2017

Authors and Affiliations

  • Changyong Wang
    • 1
    Email author
  • Shiguo Lin
    • 2
  • Yaqiong Wei
    • 1
  • Yi Zhou
    • 1
  • Hailiang Chang
    • 1
  • Jiang Liu
    • 1
  1. 1.State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation, Sedimentary Geology InstituteChengdu University of TechnologyChengduChina
  2. 2.Langfang Branch, Research Institute of Petroleum Exploration and DevelopmentPetroChinaLangfangChina

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