Abstract
The objective of this research is to study the environment and hydrogeology of the Dibdibba aquifer system in the Safwan–Zubair area, southern Iraq, in relation to the study area’s geology and anthropogenic activities. Ten groundwater samples were collected from Safwan–Zubair. Geochemical data, AquaChem, and GIS ArcMap (10.1) were used as tools to identify natural and anthropogenic factors that affect geochemical data. We analyzed water samples for major cations and anions, polycyclic aromatic hydrocarbons (PAHs), total uranium (TU), and heavy metals (Pb, Ni, Cr, Cd, V, Zn, As, Se, Cu, Fe, Mn) as well as the metalloid B. Groundwater composition in the area of study is classified into six types: Ca–Mg–Cl, Ca–Mg–Na–Cl, Ca–Mg–Cl–SO4, Ca–Mg–Na–Cl–SO4, Ca–Na–Mg–SO4–Cl, and Mg–Ca–Cl–SO4. The groundwater is influenced by natural factors, particularly the concentrations of TU and major ions. The concentrations of TU and major ions in some water samples exceed limits for drinking water; however, the average of all examined heavy metals, except for Fe and B, was within the limits for drinking water, as well as the concentrations of PAHs. The potential use of this groundwater for drinking and irrigation is discussed.








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Abiye T, Leshomo J (2013) Groundwater flow and radioactivity in Namaqualand, South Africa. Environ Earth Sci. doi:10.1007/s12665-012-2126-9
Aghazadeh N, Mogaddam A (2010) Assessment of groundwater quality and its suitability for drinking and agricultural uses in the Oshnavieh area, Northwest of Iran. J Environ Prot 1:30–40
Al-Sulaimi J, Pitty A (1995) Origin and depositional model of Wadi Al-Batin and its associated alluvial fan, Saudi Arabia and Kuwait. Sediment Geol 97:203–229
Al-Abadi M (2002) Optimum management model of groundwater resources in Safwan–Zubair area, south of Iraq. Unpublished. M.Sc. thesis, College of Science, University of Basra, 110 p
Al-Bassam K, Yousif M (2014) Geochemical distribution and background values of some minor and trace elements in Iraqi soils and recent sediments. Iraqi Bull Geol Min 10(2):109–156
Al-Naqib K (1970) Geology of Jabal Sanam, south of Iraq. J Geol Soc Iraq 3(1):9–36
Al-Sharbati F, Maala Kh (1983) The regional geological mapping of west of Zubair area (internal report). Iraqi GEOSURV Library. No. 1345. Baghdad
Al-Sulaimi J (1994) Petrological characteristics of clasts in the Dibdibba gravel of Kuwait and their relevance to provenance. Kuwait J Sci Eng 21:117–134
Al-Hamdani A, Al-Marsoumi A (2005) Petrography and mineralogy of jabal sanam gypsum rocks, southern Iraq. Iraqi J Earth Sci 5(1):18–29
Andreoli MAG, Hart R, Ashwal L, Coetzee H (2006) Correlation between U, Th content and metamorphic grade in the western Namaqualand belt, South Africa, with implications for radioactive heating of the crust. J Petrol 47(6):1095–1118
Appelo CAJ, Postma D (2005) Geochemistry, groundwater and pollution, 2nd edn. A.A. Balkema Publishers, Amsterdam, p 649
ATSDR (1992) Toxicological profile for boron. Atlanta, Georgia
Bellen R, Van Dunnington H, Wetzal R, Morton D (1959) Lexique stratigraphique international. Vol. III, Asie, Fasc, 10a, Iraq, Paris, p 336
Brindha K, Elango L (2013) PAHs contamination in groundwater from a part of metropolitan city, India: a study based on sampling over a 10-year period. Environ Earth Sci. doi:10.1007/s12665-013-2914-x
Davis S, Dewiest R (1966) Hydrogeology. Wiley, Hoboken, p 463
Davraz A, Oezdemir A (2014) Groundwater quality assessment and its suitability in C¸eltikci Plain (Burdur/Turkey). Environ Earth Sci. doi:10.1007/s12665-013-3036-1
Edmunds W (2009) Geochemistry’s vital contribution to solving water resource problems. Appl Geochem 24:1058–1073
Ekwere A, Edet A (2012) Trace metals in ground and surface waters of the Oban Massif area, SE Nigeria. Adv Appl Sci Res 3(1):312–318
Farid I, Zouari K, Abid K, Ayachi M (2013) Hydrogeochemical investigation of surface and groundwater composition in an irrigated land in Central Tunisia. J Afr Earth Sci 78:16–27
Glynn P, Plummer L (2005) Geochemistry and the understanding of ground-water systems. Hydrogeol J 13:263–287
Herczeg A, Leaney F (2011) Review: environmental tracers in arid-zone hydrology. Hydrogeol J 19:17–29
Jassim S, Goff J (2006) Geology of Iraq. Dolin and Moravian Museum, Prague
Jia-Qian J, Ashekuzzaman SM, Anlun J, Sharifuzzaman SM, Sayedur RC (2013) Arsenic contaminated groundwater and its treatment options in Bangladesh. Int J Environ Res Public Health 10:18–46
Keesari T, Kulkarni U, Deodhar A, Ramanjaneyulu P, Sanjukta A, Kumar U (2013) Geochemical characterization of groundwater from an arid region in India. J Environ Earth Sci. doi:10.1007/s12665-013-2878-x
Khedr MG (2013) Radioactive contamination of groundwater, special aspects and advantages of removal by reverse osmosis and nanofiltration. Desalination 321:47–54
Kumar M, Ramanathan A, Rao M, Kumar B (2006) Identification and evaluation of hydrogeochemical process in the groundwater environment of Delhi, India. Environ Geol 50:1025–1039
Kumar M, Kumari K, Singh U, Ramanathan A (2009) Hydrogeochemical processes in the groundwater environment of Muktsar, Punjab: conventional graphical and multivariate statistical approach. Environ Geol 57:873–884
Ma J, Ding Z, Edmunds W, Gates J, Huang T (2009) Limits to recharge of groundwater from Tibetan plateau to the Gobi desert, implications for water management in the mountain front. J Hydrol 364:128–141
Manhi H (2012) Groundwater Contamination Study of the Upper part of the Dibdibba Aquifer in Safwan area–southern Iraq, Unpublished M.Sc. thesis, University of Baghdad-College of Science, 135P
Meyback M (1987) Global chemical weathering of surficial rocks estimated from river dissolved loads. Am J Sci 287:401–428
MPCA (1999) Selenium, Molybdenum, Vanadium and Antimony in Minnesota’s Ground Water, Environmental Outcomes Division, Ground Water Monitoring & Assessment Program, 2
Ngah SA, Nwankwoala HO (2013) Iron (Fe2+) occurrence and distribution in groundwater sources in different geomorphologic zones of Eastern Niger Delta. Arch Appl Sci Res 5(2):266–272
Numan N (2001) Discussion on dextral transgression in late cretaceous continental collision Sanadaj–Sirjan zone, western Iran. J Struct Geol 23:2033–2034
Rai, D, Zachara JM, Schwab AP, Schmidt R, Girvin D, Rogers D (1986) Chemical attenuation rates, coefficients, and constants in leachate migration. Vol. 1. A critical review. Report to Electric Power Research Institute, Palo Alto, CA by Battelle, Pacific Northwest Laboratories, Richland, WA. Research Project 2198-1 (As cited in ATSDR 1992).
Raju N (2007) Hydrogeochemical parameters for assessment of groundwater quality in the upper Gunjanaeru River basin, Cuddapah District, Andhara Pradesh, South India. Environ Geol 52:1067–1074
Rao N, Rao P (2010) Major ion chemistry of groundwater in a river basin: a study from India. Environ Earth Sci 61:757–775
Richards L (1954) Diagnosis and improvement of saline and alkali soils. US Department of Agriculture, Agriculture Hand book 60, Washington
Sawyer G, McCarty D (1967) Chemistry of sanitary engineers, 2nd edn. McGraw Hill, New York
Scanlon BR, Nicot JP, Reedy RC, Kurtzman D, Mukherjee A, Nordstrom DK (2009) Elevated naturally occurring arsenic in a semiarid oxidizing system, Southern High Plains aquifer, Texas, USA. Appl Geochem 24:2061–2071
Smedley PL, Kinniburgh DG (2002) A review of the source, behaviour and distribution of arsenic in natural waters. Appl Geochem 17:517–568
Sriniva samoorthy K, Vasanthavigar M, Chidambaram S, Anandhan P, Manivannan R, Rajivgandhi R (2012) Hydrochemistry of groundwater from Sarabanga Minor Basin, Tamilnadu, India. Proc Int Acad Ecol Environ Sci 2(3):193–203
Srinivasa Gowd S (2005) Assessment of groundwater quality for drinking and irrigation purpose: a case study of Peddavanka watershed, Anantapur District, Andhra Pradesh, India. Environ Geol 48:702–712
Tay C (2012) Hydrochemistry of groundwater in the Savelugu–Nanton District, Northern Ghana. Environ Earth Sci 67:2077–2087
Titus R, Xu Y, Adams S, Beekman H (2009) A tectonic and geomorphic framework for the development of basement aquifers of Namaqualand––a review. In: Titus R, Beekman R, Adams S, Strachan L (eds) The Basement Aquifers of Southern Africa. WRC Report TT 428/09. ISBN 978-1-77005-898-9
USEPA (1993) Provisional Guidance for Quantitative Risk Assessment of Polycyclic Aromatic Hydrocarbons, EPA/600/R-93/089
Vinson DS, Schwartz HG, Dwyer GS, Vengosh A (2011) Evaluating salinity sources of groundwater and implications for sustainable reverse osmosis desalination in coastal North Carolina, USA. Hydrogeol J. doi:10.1007/s10040-011-0738x
Weight W (2008) Hydrogeology field manual, 2nd edn. McGraw Hill, New York
World Health Organization (WHO) (2006) Guidelines for drinking water quality. 3rd ed, Vol. 1, Recommendations, Geneva, p.515
World Health Organization (WHO) (2011) Guidelines for drinking–water quality, 4th edition http://whqlibdoc.who.int/publications/2011/9789241548151_eng.pdf
Yahaya MI, Mohammad S, Abdullahi BK (2009) Seasonal variations of heavy metals concentratrion in abbatoir dumping site in Nigeria. J Appl Sci Environ Manag 13(4):9–13
Acknowledgements
This work was supported by Ministry of Water Resources/General Commission for Groundwater (Baghdad and Basra Branches)––Iraq, especially Mr. Jabbar, manager of Basra branch, financially supported by DAAD (Deutscher Akademischer Austausch Dienst) German Academic Exchange Service. I want to thank FU Berlin––Geological Institute––Hydrogeology Group for hosting me in his group, Dr. Andreas Winkler for his help with AquaChem software.
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Khwedim, K., Schneider, M., Ameen, N. et al. The Dibdibba aquifer system at Safwan–Zubair area, southern Iraq, hydrogeology and environmental situation. Environ Earth Sci 76, 155 (2017). https://doi.org/10.1007/s12665-017-6469-0
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DOI: https://doi.org/10.1007/s12665-017-6469-0

