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Environmental Earth Sciences

, 75:1479 | Cite as

Geochemical mobility of arsenic in the surficial waters from Argentina

  • Alicia Daniela RoblesEmail author
  • Paula Polizzi
  • María Belén Romero
  • Leila Natalia Chiodi Boudet
  • Sandra Medici
  • Agustín Costas
  • Marcela Gerpe
Thematic Issue
Part of the following topical collections:
  1. 3RAGSU

Abstract

The presence of arsenic (As) in surface water constitutes an important environmental risk, where mobility and adsorption processes are responsible for its behavior in the sediment–water interface. Therefore, the assessment of adsorption, mobility and water availability of arsenic in freshwater sediments, with agricultural, livestock and urban soil uses was performed. Arsenic concentrations in sediments ranged from 5.4 to 15.9 mg kg−1 (total) and 2.8 to 6.5 mg kg−1 (labile), and those of iron and manganese were 11,563–23,500 and 140.6–662.1 mg kg−1, respectively. The As levels in water were significantly lower than those of sediments. Results would suggest that As co-precipitation and adsorption on Fe oxides are probably the major route of immobilization, determining its low lability. Manganese did not present an outstanding contribution to the retention, and cation-exchange capacity, pH and organic matter of sediments did not show an influence on the mobility of As.

Keywords

Arsenic Surface sediment Adsorption Mobility 

Notes

Acknowledgements

This work was partially supported by grants from National Scientific and Technical Research Council, CONICET (PIP0348/2010) and Mar del Plata University (EXA640/13).

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Copyright information

© Springer-Verlag Berlin Heidelberg 2016

Authors and Affiliations

  • Alicia Daniela Robles
    • 1
    • 2
    Email author
  • Paula Polizzi
    • 1
    • 2
  • María Belén Romero
    • 1
    • 2
  • Leila Natalia Chiodi Boudet
    • 1
    • 2
  • Sandra Medici
    • 3
  • Agustín Costas
    • 3
  • Marcela Gerpe
    • 1
    • 2
  1. 1.Toxicología Ambiental, Departamento de Ciencias Marinas, Instituto de Investigaciones Marinas y Costeras, Facultad de Ciencias Exactas y NaturalesUniversidad Nacional de Mar del PlataMar del PlataArgentina
  2. 2.Consejo Nacional de Investigaciones Científicas y Técnicas (CONICET)Buenos AiresArgentina
  3. 3.Laboratorio de Análisis Fares TaieMar del PlataArgentina

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