From coal-mining waste to construction material: a study of its mineral phases
The study from the recycling of coal mining waste from NW of Spain as pozzolans materials in cement industry is the scope of this present study. The thermal activation of coal-mining wastes, the formation of their hydrated phases and their evolution are analyzed, over pozzolanic reactions at 1, 7 and 28 days following activation. The coal-mining waste showed good pozzolanic activity, following thermal activation at 600 and 900 °C for 2 h. Total destruction of kaolinite is produced after treatment at 600 °C/2 h retention in the oven. This temperature and time are best suited for activation of the best environmental way. The compounds arising during the pozzolanic reaction in coal-mining waste activated at 600° and 900° in a Ca(OH)2 system were C–S–H gels, stratlingite (C2ASH8), tetracalcium aluminate hydrate (C4AH13), layered double hydroxides and monosulfoaluminate. When the temperature is 600 °C appeared layered double hydroxides via the metastable phase is favored during the first 7 days of reaction, while stratlingite is present as the major crystalline phase at 28 days into the pozzolanic reaction.
KeywordsCoal-mining waste Layered double hydroxide Activation temperature Mineral phases Pozzolanic activity
This research has been supported by the Spanish Ministry of Economy and Competitiveness (Project Ref. MAT2012-37005-CO3-01/02/03). The authors are also grateful to the Sociedad Anónima Hullera Vasco-Leonesa and to Spanish Cement Institute (IECA) for their help in this research.
- Atkins M, Glasser FK, Kindness A (1991) Phase relations and solubility modelling in the CaO–Al2O3–SiO2–MgO–SO3–H2O system for application in blended cements. In: Materials Research Society, Ed. Proceedings of the Materials Research Society Symposium, vol 2, Pittsburgh, PA, pp 215–220Google Scholar
- Beltramini B, Suarez ML, Guilarducci A, Carrasco MF, Grether R (2010) Aprovechamiento de residuos de la depuración del carbón mineral: obtención de adiciones puzolánicas para el cemento portland. Rev Tecn Ciencia Uni Tecnol Nal Argentina 4:7–18Google Scholar
- Leyva F, Matas J, Rodríguez Fernández LR (1984) Memoria y Hoja del Mapa Geológico de España, Escala 1:50.000, n° 129 (La Robla). 2ª serie Magna, IGME, MadridGoogle Scholar
- Moore DM, Reynolds RC (1987) X-ray diffraction and the identification and analysis of clay minerals, 2nd edn. Oxford University Press, New YorkGoogle Scholar
- Pera J, Ambroise J, Chabannet M (2001) Transformation of waste into complementary cement materials, In: Malhotra, VM (ed) Seventh CANMET/ACI/JCI international conference on fly ash, silica fume, slag and natural pozzolans in concrete, SP199, pp 459–475Google Scholar