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Intra-annual variability in the heavy metal geochemistry of ground waters from the Deccan basaltic aquifers of India

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Abstract

Geochemical baseline (geogenic+anthropogenic) and background (geogenic) levels of heavy metals in the ground waters from basaltic aquifers of Deccan Volcanic Province of India depicted intra-annual variability on spatial scale. Classified into ‘Group I’ (Fe > Mn > Zn > Pb) and ‘Group II’ (Mo > Ni > Cr > Cu), metals depicted contrasting enrichment and depletion patterns seasonally, attributable to geologic controls and water table fluctuations. While, fortification in Mo–Ni in post-monsoon (high water table) is on account of combined lithogenic+anthropogenic contributions, pre-monsoon augmentation in Fe–Mn (low water table) is entirely lithogenic. Positive values of Normalised Difference Dispersal Index, replicates the dominant role of soil/vadose zone as a chief supplier of metals to the groundwater during post-monsoon, while negative figures recommend host rock as a primary source of accretion of metals in pre-monsoon. Higher Ni/Cr ratios for wells in alluvial aquifer (fertile agriculture plain) than the basaltic and dyke aquifers, further suggest enhanced input of the elements (Mo, Ni > Cu) from soil and agriculture land use in post-monsoon season. Values of Ni/Cr ratio above unity for majority of the wells in post-monsoon and nearly 50 % wells in pre-monsoon suggest privileged weathering of olivine, followed by pyroxene > plagioclase feldspar (Ni/Cr <1) as a major cause of heavy metal load to the groundwater. Pearson correlation coefficients authenticate these inferences by means of elemental associations. The study unveils multi-source derivation of heavy metals related to seasonal fluctuation in the water table conditions leading to range of heavy metals in the groundwater from the study area. The target hazard quotient (THQ) values of heavy metals closer to unity and above unity highlight the possible health risk hazard associated with the consumption of metal contaminated groundwater. The study thus highlights the importance of baseline geochemical mapping to assess the state of near surface environment as heavy metals are closely linked to human health.

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References

  • Adomako D, Nyrko BJB, Dampare SB, Serfor-Armah Y, Osae S, Fianko JR, Akoho EHK (2008) Determination of toxic elements in waters and sediments from River Subin in the Ashanti Region of Ghana. Environ Monit Assess 141:165–175. doi:10.1007/s10661-007-9885-x

    Article  Google Scholar 

  • Alam MGM, Snow ET, Tanaka A (2003) Arsenic and heavy metal contamination of vegetables grown in Samta village, Bangladesh. Sci Total Environ 308:83–96

    Article  Google Scholar 

  • Albanese S, Vivo BD, Lima A, Cicchella D (2007) Geochemical background and baseline values of toxic elements in stream sediments of Campenia region (Italy). J Geochem Explor 93:21–34

    Article  Google Scholar 

  • APHA, AWWA, WPCF (2005) Standard methods for the examination of water and waste water, 14th edn. American Public Health Association

  • Arinze IE, Igwe O, Una CO (2015) Analysis of heavy metals contamination in soils and water at automobile junk markets in Obosi and Nnewi, Anambra State, Southeastern Nigeria. Arab J Geosci. doi:10.1007/s12517-015-2001-6

  • Bean JE, Turner CA, Hooper PR, Subbarao KV, Walsh JN (1986) Stratigraphy, composition and form of Deccan Basalts, Western Ghats, India. Bull Volcano 48:61–83

    Article  Google Scholar 

  • Challenger E (2007) Heavy metals in the environment—historical trends. Treatise in Geochemistry ISBN (SET) 9 (ISBN: 0-08-044344-3) 67–105

  • Das A, Krishnaswami S (2007) Elemental geochemistry of river sediments from Deccan Traps, India: implications to sources of elements and their mobility during basalt–water interaction. Chem Geol 242:232–254

    Article  Google Scholar 

  • De AK (1990) Environmental geochemistry. Wiley, New Delhi 361p

    Google Scholar 

  • Drever J (1982) The geochemistry of natural waters. Prentice Hall, New York 182

    Google Scholar 

  • Edmunds WM, Carrillo-Rivera JJ, Cardona A (2002) Geochemical evolution of groundwater beneath Mexico City. J Hydrol 258:1–24

    Article  Google Scholar 

  • Engin MS, Uyanik A, Kutbay HG (2015) Accumulation of heavy metals in water, sediments and wetland plants of Kizilirmak Delta (Samsun, Turkey). Int J Phytorem 17(1):66–75. doi:10.1080/15226514.2013.828019

    Article  Google Scholar 

  • Fazeli MS, Khosravan F, Hossini M, Satyanarayan S, Satish PN (1998) Enrichment of heavy metals in paddy crops irrigated by paper mill effluents near Nanjangud, Mysore district, Karnataka, India. Environ Geol 34(94):287–302

    Google Scholar 

  • Fernandez M, Nayak GN (2015) S[peciation of metals and their distribution in tropical estuarine mudflat sediments, southwest coast of India. Ecotoxicol Environ Saf 122:68–75

    Article  Google Scholar 

  • Frieberg L, Elinder CG, Kjellstroem T, Nordberg CF (eds) (1986) Cadmium and health: a toxicological and epidemiological appraisal, effects and response, vol 11. CRC, Boca-Raton

    Google Scholar 

  • Galan E, Fernandez-Caliani JC, Gonzalez I, Aparicio P, Romero A (2008) Influence of geological setting on geochemical baselines of trace elements in soils. Application to soils of South-West Spain. J Geochem Explor 98:89–106

    Article  Google Scholar 

  • Ghosh NC (1983) The trace element studies on Deccan basalts and co-magmatic rocks: a review. Geol Surv India Rec 113(2):71–95

    Google Scholar 

  • Gupta SK, Chabukdhara M, Singh J, Bux F (2015) Evaluation and Potential Health hazard of selected metals in water, sediments and fish from Gomati River. Hum Ecol Risk Assess 21(1):227–240

    Article  Google Scholar 

  • Hague T, Petroczi A, Andrews PLR, Barker J, Naughton DP (2008) Determination of metal ion content of beverages and estimation of target hazard quotients: a comparative study. Chem Central J 2:13

    Article  Google Scholar 

  • Han WY, Zhao FJ, Shi YZ, Ma LF, Ruan JY (2006) Scale and causes of lead contamination in Chinese Sea. Environ Pollut 139:125–132

    Article  Google Scholar 

  • Hem JD (1991) Study and interpretation of chemical characteristics of natural water. US Geol Survey. Water Supply Paper No. 2254

  • IS (1993) Indian Standard Specifications for Drinking Water, IS: 10500

  • Kafri U, Lang B, Halicz L, Yoffe O (2002) Geochemical characterization and pollution phenomenon of aquifer waters in northern Israel. Environ Geol 42:370–386

    Article  Google Scholar 

  • Kelepertzis E (2014) Accumulation of heavy metals in agricultural soils of Mediterranean: insights from Argolida basin, Peloponnese, Greece. Geoderma 221–222(2014):82–90

    Article  Google Scholar 

  • Khadri SFR, Subbarao KV, Hooper PR, Walsh JN (1989) Stratigraphy of Thakurwadi Formation, Western Deccan basaltic Province, India. In: Subbarao KV (Ed) Deccan flood basalts. Mem. Geol. Soc. Ind., vol 10, pp 281–304

  • Koljonen T (1992) Results of the mapping. In: Koljonen T (ed) The geochemical atlas of Finland, part 2: Till. Geological Survey of Finland, Espoo, pp 106–218

  • Krishna AK, Govil PK (2007) Soil contamination due to heavy metals from an industrial area of Surat, Western India. Environ Monit Assess. doi:10.1007/s10661-006-9224-7

  • Larocque ACL, Rasmussen PE (1998) An overview of trace metals in the environment, from mobilization to remediation. Environ Geol 33(2/3):85–91

    Article  Google Scholar 

  • Liu WX, Shen LF, Liu JW, Wang YW, Li SR (2011) Uptake of toxic heavy metals by rice (Oryza sativa L.), cultivated in the agricultural soil near Zhengzhou City, People’s Republic of China. Bull Environ Contam Toxicol 79:209–213

    Article  Google Scholar 

  • Michalec BK, Lenart-Boroń AM, Cupak AK, Wałęga AS (2014) The evaluation of heavy metal content in water and sediments of small reservoirs in light of various environmental quality regulations. J Environ Sci Health Part A 49:827–832. doi:10.1080/10934529.2014.882645

    Article  Google Scholar 

  • Mysen BD, Kushiro I (1976) Partioning of iron, nickel and magnesium between metal oxides and silicates in Allende meteorite as a function of CO2. Ann Rep Director Geophys Lab 1975–1976(1700):656–659

    Google Scholar 

  • Naik PK, Awasthi AK (2003) Groundwater resources assessment of Koyna River basin, India. J Hydrol 11(5):582–594

    Google Scholar 

  • Naughton DP, Petróczi A (2008) Heavy metal ions in wines: meta-analysis of target hazard quotients reveal health risks. Chem Central J Res 2:22. doi:10.1186/1752-153X-2-22

    Article  Google Scholar 

  • Orlov DS (1992) Soil chemistry. Oxford and IBH publishing Co. Pvt. Ltd, New Delhi, p 390

  • Patino LC, Velbel MA, Price JR, Wade JA (2003) Trace element mobility during spheroidal weathering of basalts and andesites in Hawaii and Guatemala. Chem Geol 202:343–364

    Article  Google Scholar 

  • Pawar NJ, Nikumbh JD (1999) Trace element geochemistry of groundwaters from Behedi basin, Nasik district, Maharashtra. J Geol Soc India 54:501–514

    Google Scholar 

  • Pawar NJ, Shaikh IJ (1995) Nitrate pollution of groundwaters from shallow basaltic aquifers. Deccan Trap Hydrogeologic Province, India. Environ Geol 25:197–204

    Article  Google Scholar 

  • Pawar NJ, Pawar JB, Suyash K, Supekar Ashwini (2008a) Geochemical eccentricity of groundwater allied to weathering of basalts from the Deccan Volcanic province, India: insinuation on CO2 consumption. Aquat Geochem 14:41–71

    Article  Google Scholar 

  • Pawar NJ, Pawar JB, Supekar A, Karmalkar NR, Suyash K, Erram V (2008b) Indian Dykes Editors: Rajesh K. Srivastava, Ch. Sivaji and N. V. Chalapathi Rao. Narosa Publishing House Pvt. Ltd., New Delhi

  • Petroczi A, Naughton DP (2009) Mercury, cadmium and lead contamination in seafood: a comparative study to evaluate the usefulness of target hazard quotients. Food Chem Toxicol 47(2):298–302

    Article  Google Scholar 

  • PuYang X, Gao C, Han L (2015) Risk assessment of heavy metals in water and two fish species from Golf Course Ponds in Beijing, China. Bull Environ Contam Toxicol 94:437–443

    Article  Google Scholar 

  • Rabemanana V, Violette S, de Marsily G, Robain H, Deffontaines B, Andrieux P, Bensimon M, Parraux A (2005) Origin of high variability of water mineral content in the bedrock aquifers of Southern Madagaskar. J Hydrol 310:143–156

    Article  Google Scholar 

  • Rajmohan N, Elango L (2005) Distribution of iron, manganese, zinc and attrazine in groundwater in parts of palar and cheyyar rivers basins, south India. Environ Monit Assess 107:115–131

    Article  Google Scholar 

  • Robertson WD, Blows DW (1995) Major ion and trace metal geochemistry of an acidic septic system plume in silt. Groundwater 33(2):275–283

    Article  Google Scholar 

  • Salonen VP, Neimi KK (2007) Influence of parent sediments on the concentration of heavy metals in urban and suburban soils in Turku, Finland. Appl Geochem 22:906–918

    Article  Google Scholar 

  • Sen G (1986) Mineralogy and petrogenesis of the Deccan Trap Lava Flows around Mahabaleshwar, India. J Petrol 27(3):627–663

    Article  Google Scholar 

  • Sethna SF, Ateeq K, Javeri P (1996) Petrology of basic intrusives in the Deccan Volcanic Province South of Tapti Valley and their comparison with those along the west coast. Gondwana Geol Mag Special 2:225–232

    Google Scholar 

  • Sharma SK, Subramanium V (2010) Source and distribution of trace metals and nutrients in Narmada and Tapti river basins, India. Environ Earth Sci 61(7):1337–1352

    Article  Google Scholar 

  • Sharma RK, Agrawal M, Marshall F (2007) Heavy metal contamination of soil and vegetables in suburban areas of Varanasi, India. Ecotoxicol Environ Saf 66(2007):258–266

    Article  Google Scholar 

  • Shirke KD, Pawar NJ (2015) Enrichment of arsenic in the Quaternary sediments from Ankaleshwar industrial area, Gujarat, India: an anthropogenic influence. Environ Monit Assess 187:593. doi:10.1007/s10661-015-4815-9

    Article  Google Scholar 

  • Smoulders APJ, Hudson-Edwards KA, Vander Velde G, Roelofs JGM (2004) Controls on water chemistry of the Pilcomayo river (Bolivia, South-america). Appl Geochem 19:1745–1758

    Article  Google Scholar 

  • Storelli MM (2008) Potential human health risks from metals (Hg, Cd, and Pb) and polychlorinated biphenyls (PCBs) via seafood consumption: estimation of target hazard quotients (THQs) and toxic equivalents (TEQs). Food Chem Toxicol 46(8):2782–2788

    Article  Google Scholar 

  • Storelli MM, Barone G, Cuttone G, Giungato D, Garofalo R (2010) Occurrence of toxic metals (Hg, Cd and Pb) in fresh and canned tuna: public health implications. Food Chem Toxicol 48(11):3167–3170

    Article  Google Scholar 

  • Subbarao KV, Hooper PR (1988) Reconnaissance map of the Deccan basalt group in the Western Ghats, India. In: Subbarao KV (ed) Deccan flood basalts. Mem. Geol. Soc. India No. 10

  • Subbarao KV, Chandrashekharam D, Navaneethakrishanan P, Hooper PR (1994) Stratigraphy and structure of parts of the Central Deccan Basalt Province: eruptive models. Volcanism, pp 321–332

  • Suyash K, Pawar NJ (2008) Quantifying spatio-temporal variations in heavy metal enormity of groundwaters from Ankaleshwar area: GIS based Normalised Difference Dispersal Index mapping. Curr Sci 94(7):905–990

    Google Scholar 

  • Suyash K, Pawar NJ (2010) Site-specific accentuation of heavy metals in groundwaters from Ankaleshwar industrial estate. Environ Earth Sci, India. doi:10.1007/s12665-010-0879-6

    Google Scholar 

  • Suyash K, Shirke KD, Pawar NJ (2008) GIS based color composites and overlays to delineate heavy metal contamination zones in the shallow alluvial aquifers, Ankaleshwar Industrial Estate, south Gujarat, India. Environ Geol 54:117–129

    Article  Google Scholar 

  • Tarits C, Aquilina L, Ayraud V, Pauwel H, Davy P, Touchard F, Bour O (2006) Oxido-reduction sequence related to flux variations of groundwater from fractured basement aquifer (Ploemeur area, France). Appl Geochem 21:29–47

    Article  Google Scholar 

  • Tiwari MK, Bajpai S, Dewangan UK, Tamrakar RK (2015) Assessment of heavy metal concentrations in surface water sources in an industrial region of central India. Karbala Int J Modern Sci

  • Tume P, Bech J, Tume L, Bech J, Reverter F, Longan L, Cendoya P (2008) Concentrations and distributions of Ba, Cr, Sr, V, Al and Fe in Torrelles soil profiles (Catalonia, Spain). J Geochem Explor 96:94–105

    Article  Google Scholar 

  • U.S. Environmental Protection Agency (1989) Guidance manual for assessing human health risks from chemically contaminated, fish and shellfish. U.S. Environmental Protection Agency, Washington, D.C. EPA-503/8-89-002

  • U.S.G.S. (1993). National water summary—1990–1991: Stream water quality; U.S. Geol. Sur. Water Supply Paper, 2400, p 590

  • Varian (1989) Analytical methods, flame atomic absorption spectrometry, publication no. 85-100009-00, Mulgrave, p 146

  • Wong CSC, Li X, Thornton I (2006) Urban environmental geochemistry of trace metals. Environ Pollut 142:1–16

    Article  Google Scholar 

  • World Health Organisation (1971) International Standards for drinking water, 3rd edn. WHO, Geneva, p 70

  • Yuan GH, Sun TH, Han P, Li J, Lang XX (2014) Source identification and ecological risk assessment of heavy metals in topsoil using environmental geochemical mapping: typical urban renewal area in Beijing, China. J Geochem Explor 136:40–47

    Article  Google Scholar 

  • Zhang K, Dearing JA, Dawson TP, Dong X, Yang X, Zhang W (2015) Poverty alleviation strategies in eastern China lead to critical ecological dynamics. Sci Total Environ 506–507:164–181

    Article  Google Scholar 

  • Zhou JM, Dang Z, Cai MF, Liu CQ (2007) Soil heavy metal pollution around the Dabaoshan Mine, Guangdong Province, China. Pedosphere 17(5):588–594

    Article  Google Scholar 

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Acknowledgments

The authors gratefully acknowledge the facilities provided by Department of Geology, Savitribai Phule Pune University, Pune. Thanks are also due to DST-FIST funding for equipment and UGC, Government of India for granting study leave to JBP. Assistance in the field by colleagues Dr. N.R. Karmalkar, Suyash Kumar and Dr. Vinit Erram is thankfully acknowledged. The authors sincerely thank the anonymous reviewers for making many meaningful suggestions.

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  1. Department of Geology, Savitribai Phule Pune University, Pune, 411 007, India

    N. J. Pawar

  2. Department of Geology, Jaihind College, Dhule, India

    J. B. Pawar

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Pawar, N.J., Pawar, J.B. Intra-annual variability in the heavy metal geochemistry of ground waters from the Deccan basaltic aquifers of India. Environ Earth Sci 75, 654 (2016). https://doi.org/10.1007/s12665-016-5450-7

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