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Pollution assessment of arsenic and other selected elements in the groundwater and soil of the Gulf of Aqaba, Saudi Arabia

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Abstract

Forty-six soil and groundwater samples were collected from the agricultural farms of the Gulf of Aqaba coast. Additionally, 24 granitic and marine sedimentary rock samples were collected from the study area. The collected samples were analyzed for As, Al, Au, B, Ba, Be, Fe, Sb, Se, Sn, Ti, and V using inductively coupled plasma mass spectrometry. Levels of the studied metals in the groundwater samples lie within the acceptable limits of the World Health Organization (WHO). The rock samples exhibit a significant variation in mean metal content from one rock type to another. Concentrations of As and B in the soil samples were determined to be higher than those of Canadian Soil Quality Guidelines (CSQG) and were primarily due to agricultural and seawater inputs. Chemical weathering of various rock units also plays a significant role. The calculations of geoaccumulation index are found to be more reliable than of those of enrichment factor for Arsenic contamination levels assessment. The study area is not significantly affected by As contamination. The correlation coefficient analysis results for the soil and groundwater data reveal a variable degree of correlations between As and other metals in the study area.

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References

  • Adriano DC (2001) Trace elements in terrestrial environments. Biogeochemistry bioavailability and risk of metals. Springer, New York

    Book  Google Scholar 

  • Al-Taani A, Batayneh A, Nazzal Y, Ghrefat H, Elawadi E, Zaman H (2014) Status of trace metals in surface seawater of the Gulf of Aqaba, Saudi Arabia. Mar Pollut Bull 86:582–590

    Article  Google Scholar 

  • Asante KA, Agusa T, Subramanian A, Ansa-Asare OD, Biney CA, Tanabe S (2007) Contamination status of arsenic and other trace elements in drinking water and residents from Tarkwa, a historic mining township in Ghana. Chemosphere 66:1513–1522

    Article  Google Scholar 

  • Batayneh A, Ghrefat H, Zaman H, Mogren S, Zumlot T, Elawadi E, Laboun A, Qaisy S (2012a) Assessment of the physicochemical parameters and heavy metals toxicity: application to groundwater quality in unconsolidated shallow aquifer system. Res J Environ Toxicol 6:169–183

    Article  Google Scholar 

  • Batayneh A, Laboun A, Qaisy S, Ghrefat H, Zumlot T, Zaman H, Elawadi E, Mogren S, Al-Qudah K (2012b) Assessing groundwater quality of the shallow alluvial aquifer system in the Midyan Basin, northwestern Saudi Arabia. Arab Gulf J Sci Res 30:7–13

    Google Scholar 

  • Bhuiyan MAH, Suruvi NI, Dampare SB, Islam MA, Quraishi SB, Ganyaglo S, Suzuki S (2011) Investigation of the possible sources of heavy metal contamination in lagoon and canal water in the tannery industrial area in Dhaka, Bangladesh. Environ Monit Assess 175:633–649

    Article  Google Scholar 

  • Bhumbla DK, Keefler RF (1994) Arsenic mobilization and bioavailability in soils. In: Niragu JO (ed) Arsenic in the environment, part I, cycling and characterization. Wiley, New York, pp 51–82

    Google Scholar 

  • Bowen HJM (1979) Environmental chemistry of the elements. Academic Press, New York

    Google Scholar 

  • Boyle RW, Jonassan IR (1984) Geochemistry of antimony and its use as an indicator element in geochemical prospecting. J Geochem Explor 20:223–302

    Article  Google Scholar 

  • Butterwick L, De Oude N, Raymond K (1989) Safety assessment of boron in aquatic and terrestrial environments. Ecotoxicol Environ Saf 17:339–371

    Article  Google Scholar 

  • CA-SQG. Soil Quality Guidelines Task Group (SQGTG) (2010) Canadian Environmental Quality Guidelines, Canada. http://www.ccme.ca/ourwork/soil.html?category_id=44

  • Çevik F, Göksu MZ, Derici OB, Fındık O (2009) An assessment of metal pollution in surface sediments of Seyhan dam by using enrichment factor, geoaccumulation index and statistical analyses. Environ Monit Assess 152:309–317

    Article  Google Scholar 

  • Chen CW, Kao CM, Chen CF, Dong CD (2007) Distribution and accumulation of heavy metals in the sediments of Kaohsiung Harbor, Taiwan. Chemosphere 66:1431–1440

    Article  Google Scholar 

  • Christophoridis C, Dedepsidis D, Fytianos K (2009) Occurrence and distribution of selected heavy metals in the surface sediments of Thermaikos Gulf, N. Greece. Assessment using pollution indicators. J Hazard Mater 15:1082–1091

    Article  Google Scholar 

  • Clark, M (1986) Explanatory notes to the geologic map of the Al Bad Quadrangle, sheet 28A, Kingdom of Saudi Arabia. Saudi Arabian Deputy Ministry for Mineral Resources. Geoscience Map Series GM-81A, C, scale 1:250,000, with text, p 46

  • Dotsika E, Poutoukis D, Kloppmann W, Raco B, Psomiadis D (2011) Distribution and origin of boron in fresh and thermal waters in different areas of Greece, 2011. Water Secur Mediterr Region NATO Sci Peace Secur Ser C Environ Secur 11:209–228

    Article  Google Scholar 

  • Dowdle PR, Laverman AM, Oremland RS (1996) Bacterial dissimilatory reduction of arsenic (V) to arsenic (III) in anoxic sediments. Appl Environ Microbiol 62:1664–1669

    Google Scholar 

  • Edmunds, WM, Cook JM, Kinniburgh DG, Miles DL (1989) Trafford JM. Trace element Occurrence in British Groundwaters. Res. Report SD/89/3, British Geological Survey, Keyworth

  • Elawadi E, Zaman H, Batayneh A, Mogren S, Laboun A, Ghrefat H, Zumlot T (2013) Structural interpretation of the Ifal Basin in north-western Saudi Arabia from aeromagnetic data: hydrogeological and environmental implications. Explor Geophys 44:251–263

    Article  Google Scholar 

  • Ergin M, Saydam C, Basturk O, Erdem E, Yoruk R (1991) Heavy metal concentrations in surface sediments from the two coastal inlets (Golden Horn Estuary and Izmit Bay) of the northeastern Sea of Marmara. Chem Geol 91:269–285

    Article  Google Scholar 

  • Garcia-Sanchez A, Alvarez-Ayuso E (2003) Arsenic in soils and waters and its relation to geology and mining activities (Salamanca Province, Spain). J Geochem Explor 80:69–79

    Article  Google Scholar 

  • García-Sánchez A, Alonso-Rojo P, Santos-Francés F (2010) Distribution and mobility of arsenic in soils of a mining area (Western Spain). Sci Total Environ 408:4194–4201

    Article  Google Scholar 

  • Garelick H, Jones H, Dybowska A, Valsami-Jones E (2008) Arsenic pollution sources. Springer, New York, pp 17–60

    Google Scholar 

  • Ghrefat HA, Abu Rukah Y, Rosen MA (2011) Application of geoaccumulation index and enrichment factor for assessing metal contamination in the sediments of Kafrain Dam, Jordan. Environ Monit Assess 178:95–109

    Article  Google Scholar 

  • Ghrefat HA, Batayneh A, Zaman H, Zumlot T, Elawadi E, Nazzal Y (2013) Major ion chemistry and weathering processes in the Midyan Basin, northwestern Saudi Arabia. Environ Monit Assess 185:8695–8705

    Article  Google Scholar 

  • Ghrefat H, Nazzal Y, Batayneh A, Zumlot T, Zaman H, Elawadi E, Qaisy S (2014) Geochemical assessment of groundwater contamination with special emphasizes on fluoride, a case study from Midyan Basin, northwestern Saudi Arabia. Environ Earth Sci 71:1495–1505

    Article  Google Scholar 

  • Jarvis KE, Gray AL, Houk RS (1991) Handbook of inductively coupled plasma mass spectrometry

  • Karim RA, Hossain SM, Miah MM, Nehar K, Mubin MSH (2008) Arsenic and heavy metal concentrations in surface soils and vegetables of Feni district in Bangladesh. Environ Monit Assess 145:417–425

    Article  Google Scholar 

  • Masscheleyn PH, Delaune RD, Patrick WH Jr (1991) Effect of redox potential and pH on arsenic speciation and solubility in a contaminated soil. Environ Sci Technol 25:1414–1419

    Article  Google Scholar 

  • McGeehan SL, Naylor DV (1994) Sorption and redox transformations of arsenite and arsenate in two flooded soils. Soil Sci Soc Am J 58:337–342

    Article  Google Scholar 

  • Meza-Figueroa D, Maier RM, de la O-Villanueva M, Gómez-Alvarez A, Moreno-Zazueta A, Rivera J, Campillo A, Grandlic C, Anaya R, Palafox-Reyes J (2009) The impact of unconfined mine tailings in residential areas from a mining town in a semi-arid environment: Nacozari, Sonora, Mexico. Chemosphere 77:140–147

    Article  Google Scholar 

  • Mogren S, Batayneh A, Elawadi E, Al-Bassam A, Ibrahim E, Qaisy S (2011) Aquifer boundaries explored by geoelectrical measurements in the Red Sea coastal plain of Jazan area, southwest Saudi Arabia. Int J Phys Sci 6:3768–3776

    Google Scholar 

  • Müller G (1981) Die Schwermetallbelstung der sedimente des Neckars und seiner Nebenflusse: eine Bestandsaufnahme. Chem Ztg 105:156–164

    Google Scholar 

  • Navoni JA, De Pietri D, Olmos V, Gimenez C, Bori Mitre G, de Titto E, Villaamil Lepori EC (2014) Human health risk assessment with spatial analysis: study of a population chronically exposed to arsenic through drinking water from Argentina. Sci Total Environ 499:166–174

    Article  Google Scholar 

  • Patel KS, Shrivas K, Brandt R, Jakubowski N, Corns W, Hoffmann P (2005) Arsenic contamination in water, soil, sediment and rice of central India. Environ Geochem Health 27:131–145

    Article  Google Scholar 

  • Rubio B, Nombela MA, Vilas F (2000) Geochemistry of major and trace elements in sediments of the Ria de Vigo (NW Spain). Mar Pollut Bull 40:968–980

    Article  Google Scholar 

  • Smedley PL, Kinniburg DG (2002) A review of the source, behavior and distribution of arsenic in natural water. Appl Geochem 17:517–568

    Article  Google Scholar 

  • Smith E, Naidu R, Alston AM (1998) Arsenic in the soil environment. Adv Agron 64:149–195

    Article  Google Scholar 

  • Solgi E, Esmaili-Sari A, Riyahi-Bahntiari A, Hadipor M (2012) Soil contamination of metals in the three industrial Estates, Arak, Iran. Bull Environ Contam Toxicol 88:634–638

    Article  Google Scholar 

  • Tamaki S, Frankenberger WT (1992) Environmental biochemistry of arsenic. Rev Environ Contam Toxicol 124:79–110

    Google Scholar 

  • Tamasi G, Cini R (2004) Heavy metals in drinking waters from Mount Amiata (Tuscany, Italy). Possible risks from arsenic for public health in the Province of Siena. Sci Total Environ 327:41–51

    Article  Google Scholar 

  • Turekian KK, Wedepohl KH (1961) Distribution of the elements in some major units of the earth’s crust. Geol Soc Am 72:175–192

    Article  Google Scholar 

  • Welch AH, Westjohn DB, Helsel DR, Wanty RB (2000) Arsenic in groundwater of the United States: occurrence and geochemistry. Ground Water 38:589–604

    Article  Google Scholar 

  • World Health Organization (WHO) (2008) Guidelines for drinking quality, 3rd edn. WHO, Geneva

    Google Scholar 

  • Wyn Hughes G, Johnson R (2005) Lithostratigraphy of the Red Sea region. GeoArabia 10:140–159

    Google Scholar 

  • Yan XP, Kerrich R Hendry, Hendry MJ (2000) Distribution of arsenic (III), arsenic (V) and total inorganic arsenic in porewaters from a thick till and clay-rich aquitard sequence, Saskatchewan, Canada. Geochim Cosmochim Acta 64:2637–2648

    Article  Google Scholar 

  • Yaqin JI, Yinchang F, Jianhi WU, Tan ZHU, Zhipeng B, Chiqing D (2008) Using geoaccumulation index to study source profiles of soil dust in China. J Environ Sci 20:571–578

    Article  Google Scholar 

  • Zhang J, Liu CL (2002) Riverine composition and estuarine geochemistry of particulate metals in China- Weathering features, anthropogenic impact and chemical fluxes. Estuar Coast Shelf Sci 54:1051–1070

    Article  Google Scholar 

Download references

Acknowledgments

The authors would like to extend their sincere appreciation to the Deanship of Scientific Research at king Saud University for its funding this Research group No. (RG 1435-008).

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Correspondence to Habes Ghrefat.

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Ghrefat, H., Waheidi, M.E., Batayneh, A. et al. Pollution assessment of arsenic and other selected elements in the groundwater and soil of the Gulf of Aqaba, Saudi Arabia. Environ Earth Sci 75, 229 (2016). https://doi.org/10.1007/s12665-015-5020-4

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