Skip to main content

Advertisement

Log in

Distribution, enrichment and sources of heavy metals in surface sediments of Hainan Island rivers, China

  • Original Article
  • Published:
Environmental Earth Sciences Aims and scope Submit manuscript

Abstract

Heavy metal concentrations in 36 samples of surface sediments from Hainan Island rivers were determined to evaluate the level of contamination in the region. Heavy metal concentrations (mg/kg) of Hainan Island rivers were in the range of 0.01–0.58 mg/kg for Hg, 0.09–0.70 mg/kg for Cd, 1.80–36.87 mg/kg for As, 15.33–69.32 mg/kg for Pb, 4.46–150.89 mg/kg for Cu, 6.64–104.95 mg/kg for Cr and 22.11–199.11 mg/kg for Zn. Contamination indices including contamination factor, enrichment factor, and geoaccumulation index, and multivariate statistical analyses indicated that Wenlan River was relatively at a considerable pollution level; Nandu, Changhua, Lingshui, Wanquan and Zhubi rivers were at a low-to-moderate pollution level; Beimen and Ningyuan rivers were at a level of relatively low pollution. Principal component analysis indicated that Cd, Pb, Cr and Zn were predominantly sourced from anthropogenic sources; whereas, Cu, As and Hg were from lithogenic sources. This study would be helpful for sustainable land use and marine management in the region.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9

Similar content being viewed by others

References

  • Amin B, Ismail A, Arshad A, Yap CK, Kamarudin MS (2009) Anthropogenic impacts on heavy metal concentrations in the coastal sediments of Dumai, Indonesia. Environ Monit Assess 148:291–305

    Article  Google Scholar 

  • An Q, Wu Y, Wang J, Li Z (2010) Assessment of dissolved heavy metal in the Yangtze river estuary and its adjacent sea, China. Environ Monit Assess 164:173–187

    Article  Google Scholar 

  • Audry S, Schafer J, Blanc G, Jouanneau JM (2004) Fifty-year sedimentary record of heavy metal pollution (Cd, Zn, Cu, Pb) in the Lot river reservoirs (France). Environ Pollut 132:413–426

    Article  Google Scholar 

  • Bacon JR, Davidson CM (2008) Is there a future for sequential chemical extraction? Analyst 133:25–46

    Article  Google Scholar 

  • Bhuiyan MA, Suruvi NI, Dampare SB, Islam MA, Quraishi SB, Ganyaglo S, Suzuki S (2011) Investigation of the possible sources of heavy metal contamination in lagoon and canal water in the tannery industrial area in Dhaka, Bangladesh. Environ Monit Assess 175:633–649

    Article  Google Scholar 

  • Chabukdhara M, Nema AK (2012) Assessment of heavy metal contamination in Hindon River sediments: a chemometric and geochemical approach. Chemosphere 87:945–953

    Article  Google Scholar 

  • Cooke JA, Andrews SM, Johnson MS (1990) Lead, zinc, cadmium and fluoride in small mammals from contaminated grassland established on fluorspar tailings. Water Air Soil Pollut 51:43–54

    Article  Google Scholar 

  • CSBTS (2002) The People’s Republic of China National Standards GB 18668-2002-Marine Sediment Quality. China State Bureau of Quality and Technical Supervision: 10

  • Dassenakis M, Scoullos M, Gaitis A (1997) Trace metals transport and behaviour in the Mediterranean estuary of Acheloos River. Mar Pollut Bull 34:103–111

    Article  Google Scholar 

  • Dou Y, Li J, Zhao J, Hu B, Yang S (2013) Distribution, enrichment and source of heavy metals in surface sediments of the eastern Beibu Bay, South China Sea. Mar Pollut Bull 67:137–145

    Article  Google Scholar 

  • Facchinelli A, Sacchi E, Mallen L (2001) Multivariate statistical and GIS-based approach to identify heavy metal sources in soils. Environ Pollut 114:313–324

    Article  Google Scholar 

  • Fu G, Li M, Zeng W (2000) Geology in Hainan Island. Chinese Geology Press, New York

    Google Scholar 

  • Gaur VK, Gupta SK, Pandey SD, Gopal K, Misra V (2005) Distribution of heavy metals in sediment and water of river Gomti. Environ Monit Assess 102:419–433

    Article  Google Scholar 

  • Hakanson L (1980) An ecological risk index for aquatic pollution control. A sedimentological approach. Water Res 14:975–1001

    Article  Google Scholar 

  • Hu B, Cui R, Li J, Wei H, Zhao J, Bai F, Song W, Ding X (2013a) Occurrence and distribution of heavy metals in surface sediments of the Changhua river estuary and adjacent shelf (Hainan Island). Mar Pollut Bull 76:400–405

    Article  Google Scholar 

  • Hu B, Li G, Li J, Bi J, Zhao J, Bu R (2013b) Spatial distribution and ecotoxicological risk assessment of heavy metals in surface sediments of the southern Bohai Bay, China. Environ Sci Pollut Res Int 20:4099–4110

    Article  Google Scholar 

  • Idris AM (2008) Combining multivariate analysis and geochemical approaches for assessing heavy metal level in sediments from Sudanese harbors along the Red Sea coast. Microchem J 90:159–163

    Article  Google Scholar 

  • Ip CC, Li XD, Zhang G, Wai OW, Li YS (2007) Trace metal distribution in sediments of the Pearl river estuary and the surrounding coastal area, South China. Environ Pollut 147:311–323

    Article  Google Scholar 

  • Irabien MJ, Velasco F (1999) Heavy metals in Oka river sediments (Urdaibai National Biosphere Reserve, northern Spain): lithogenic and anthropogenic effects. Environ Geol 37:54–63

    Article  Google Scholar 

  • Li L (1992) Hydrological character in Hainan island. Hydrology 6:49–51

    Google Scholar 

  • Li X, Liu L, Wang Y, Luo G, Chen X, Yang X, Gao B, He X (2012) Integrated assessment of heavy metal contamination in sediments from a coastal industrial basin, NE China. PloS one 7:e39690

    Article  Google Scholar 

  • Loring D, Rantala R (1992) Manual for the geochemical analyses of marine sediments and suspended particulate matter. Earth Sci Rev 32:235–283

    Article  Google Scholar 

  • Loska K, Wiechuła D (2003) Application of principal component analysis for the estimation of source of heavy metal contamination in surface sediments from the Rybnik reservoir. Chemosphere 51:723–733

    Article  Google Scholar 

  • Metcalfe I (2009) Late Palaeozoic and Mesozoic tectonic and palaeogeographical evolution of SE Asia. Geol Soc Lond (Spec Publ) 315:7–23

    Article  Google Scholar 

  • Meza-Figueroa D, Maier RM, de la O-Villanueva M, Gomez-Alvarez A, Moreno-Zazueta A, Rivera J, Campillo A, Grandlic CJ, Anaya R, Palafox-Reyes J (2009) The impact of unconfined mine tailings in residential areas from a mining town in a semi-arid environment: Nacozari, Sonora, Mexico. Chemosphere 77:140–147

    Article  Google Scholar 

  • Müller G (1979) Schwermetalle in den Sedimenten des Rheins-Veränderungen seit 1971. Umschau 79:778–783

    Google Scholar 

  • Müller G (1981) Die Schwermetallbelastung der sedimente des Neckars und seiner Nebenflusse: eine Bestandsaufnahme. Chem Zeitung 105:157–164

    Google Scholar 

  • Pekey H (2006) The distribution and sources of heavy metals in Izmit Bay surface sediments affected by a polluted stream. Mar Pollut Bull 52:1197–1208

    Article  Google Scholar 

  • Peng X, Zhou H, Weng H, Pan J, Chen G (2003) Characteristics of major elements' constitutions and distributions in sediments of the Lingdingyang in the Pearl River Estuary and their geochemical implication. J Zhejiang Univ (Science Edition) 30:697–702 (in Chinese with English abstract)

    Google Scholar 

  • Raghunath R, Tripathi RM, Kumar AV, Sathe AP, Khandekar RN, Nambi KS (1999) Assessment of Pb, Cd, Cu, and Zn exposures of 6- to 10-year-old children in Mumbai. Environ Res 80:215–221

    Article  Google Scholar 

  • Reimann C, Filzmoser P, Garrett R, Dutter R (2011) Statistical data analysis explained: applied environmental statistics with R. John Wiley & Sons, Chichester

    Google Scholar 

  • Sakan SM, Dordevic DS, Manojlovic DD, Predrag PS (2009) Assessment of heavy metal pollutants accumulation in the Tisza river sediments. J Environ Manage 90:3382–3390

    Article  Google Scholar 

  • SBSM (2008) Electronic atlas of Hainan province. The state bureau of surveying and mapping in Hainan data information center

  • Shi X, Kohn B, Spencer S, Guo X, Li Y, Yang X, Shi H, Gleadow A (2011) Cenozoic denudation history of southern Hainan Island, South China Sea: constraints from low temperature thermochronology. Tectonophysics 504:100–115

    Article  Google Scholar 

  • Singh KP, Malik A, Sinha S (2005) Water quality assessment and apportionment of pollution sources of Gomti river (India) using multivariate statistical techniques—a case study. Anal Chim Acta 538:355–374

    Article  Google Scholar 

  • Sun S, Song X, Sun Y, Ma X, Li J, Chen J, Huang T, Cao L (2014) Determination of multiple metallic elements in oceanic sediments by ICP-AES. Chin J Inorg Anal Chem 4:35–38

    Google Scholar 

  • Varol M (2011) Assessment of heavy metal contamination in sediments of the Tigris river (Turkey) using pollution indices and multivariate statistical techniques. J Hazard Mater 195:355–364

    Article  Google Scholar 

  • Wan S, Li A, Clift PD, Stuut J-BW (2007) Development of the east Asian monsoon: mineralogical and sedimentologic records in the northern south China Sea since 20 Ma. Palaeogeogr Palaeoclimatol Palaeoecol 254:561–582

    Article  Google Scholar 

  • Xia P, Meng X, Yin P, Liu L (2008) Heavy metal pollution and its potential ecological risk in the sediments from the Beihai intertidal zone of Guangxi province. Adv Mar Sci 26:471–477

    Google Scholar 

  • Xia P, Meng X, Yin P, Cao Z, Wang X (2011) Eighty-year sedimentary record of heavy metal inputs in the intertidal sediments from the Nanliu river estuary, Beibu Gulf of South China Sea. Environ Pollut 159:92–99

    Article  Google Scholar 

  • Xu Y, Cawood PA, Du Y, Zhong Z, Hughes NC (2014) Terminal suturing of Gondwana along the southern margin of South China Craton: evidence from detrital zircon U-Pb ages and Hf isotopes in Cambrian and Ordovician strata, Hainan island. Tectonics 33:2490–2504

    Article  Google Scholar 

  • Yang S, Li C (1999) Characteristic element compositions of the Yangtze and the Yellow River sediments and their geological background. Mar Geol Quat Geol 19:19–26 (in Chinese with English abstract)

    Google Scholar 

  • Yang W, Lai Z, Wei T (2009) Pollution and ecological hazard evaluation of sediment heavy metals in Pearl River Estuary. J Zhejiang Ocean Univ (Natural Science) 2:188–232 (in Chinese with English abstract)

    Article  Google Scholar 

  • Yu R, Yuan X, Zhao Y, Hu G, Tu X (2008) Heavy metal pollution in intertidal sediments from Quanzhou Bay, China. J Environ Sci 20:664–669

    Article  Google Scholar 

  • Zhang J (1995) Geochemistry of trace metals from Chinese river/estuary systems: an overview. Estuar Coast Shelf Sci 41:631–658

    Article  Google Scholar 

  • Zhang J, Liu C (2002) Riverine composition and estuarine geochemistry of particulate metals in China—weathering features, anthropogenic impact and chemical fluxes. Estuar Coast Shelf Sci 54:1051–1070

    Article  Google Scholar 

  • Zhang H, Shan B (2008) Historical records of heavy metal accumulation in sediments and the relationship with agricultural intensification in the Yangtze-Huaihe region, China. Sci Total Environ 399:113–120

    Article  Google Scholar 

  • Zhang W, Feng H, Chang J, Qu J, Xie H, Yu L (2009) Heavy metal contamination in surface sediments of Yangtze River intertidal zone: an assessment from different indexes. Environ Pollut 157:1533–1543

    Article  Google Scholar 

Download references

Acknowledgments

We thank Dr. Dongfeng Jiao and Mr. Chen for assistance in field work and Xingyan Shen and Xuebo Yin for technical help in laboratory. This work was supported by the National Natural Science Foundation of China (41076033), Chinese Continental Shelf Deep Drilling Program (GZH201100202) and Strategic Priority Research Program of the Chinese Academy of Sciences (XDA11030104).

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Debo Zhao.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Zhao, D., Wan, S., Yu, Z. et al. Distribution, enrichment and sources of heavy metals in surface sediments of Hainan Island rivers, China. Environ Earth Sci 74, 5097–5110 (2015). https://doi.org/10.1007/s12665-015-4522-4

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s12665-015-4522-4

Keywords

Navigation