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Environmental Earth Sciences

, Volume 74, Issue 2, pp 1125–1135 | Cite as

Characterization and adsorptive capacity of coal fly ash from aqueous solutions of disperse blue and disperse orange dyes

  • G. C. Kisku
  • Markandeya
  • S. P. Shukla
  • D. Sen Singh
  • R. C. Murthy
Original Article

Abstract

Discharge of colored industrial effluents into water bodies poses environmental risks to aquatic life. Coal fly ash (CFA) was used as an adsorbent for removal of disperse blue and disperse orange dyes from aqueous solutions. The surface morphology of CFA was characterized using scanning electron microscopy–energy dispersive X-ray and particle size was characterized by particle size analyzer and transmission electron microscopy. The maximum removal capacities of CFA for disperse blue and disperse orange dyes were 71 % (concentration 10−4 M; temp. 45 °C; dosage 4 g/50 mL; pH 6) and 75 % (concentration 10−4 M; temp. 45 °C; dosage 3 g/50 mL; pH 6), respectively. The experiments concluded that CFA was commercially beneficial for adsorption of disperse blue and disperse orange dyes and removes disperse orange dye with greater efficiency. The Langmuir isotherm better fit the adsorption data of both dyes, indicating monolayer adsorption of dyes on the CFA surface. The results of kinetics study revealed that disperse blue and disperse orange dyes follow pseudo-second-order kinetics. The CFA can be used as a potential adsorbent for removal of dyes from aqueous medium.

Keywords

Coal fly ash Disperse dyes Adsorption Isotherm Kinetics 

Notes

Acknowledgments

The authors are grateful to Dr. K. C. Gupta, Director, IITR, Lucknow, for providing necessary facilities and fund for this work. Special thanks are due to Mr. B. D. Bhattacharji and Dr. D. S. Bhargava, Ex-Professor, IIT, Roorkee, Uttrakhand, for their valuable suggestions regarding this paper. The authors also thank Dr. L. K. S. Chauhan and Dr. P. N. Saxena for SEM–EDX and TEM photomicrographs.

References

  1. Ahamad R (2013) Adsorption of dyes by non-conventional adsorbents. In: Bharati PK, Gajananda K (eds) Environmental health and problems. Discovery Publishing House Pvt Ltd., New Delhi, pp 107–140Google Scholar
  2. An C, Huang G (2012) Stepwise adsorption of phenanthrene at the fly ash-water interface as affected by solution chemistry: experimental and modeling studies. Env Sci Tech 46(22):12742–12750CrossRefGoogle Scholar
  3. Andersson KI, Eriksson M, Norgren M (2012) Lignin removal by adsorption to fly ash in wastewater generated by mechanical pulping. Ind Eng Chem Res 51(8):3444–3451CrossRefGoogle Scholar
  4. Atar N, Olgun A, Wang SB, Liu SM (2011) Adsorption of anionic dyes on boron industry waste in single and binary solutions using batch and fixed-bed systems. J Chem Eng Data 56:508–516CrossRefGoogle Scholar
  5. Boycheva S, Zgureva D, Vassilev V (2013) Kinetic and thermodynamic studies on the thermal behaviour of fly ash from lignite coals. Fuel 108:639–646CrossRefGoogle Scholar
  6. Carvalho TEM, Fungaro DA, Magdalena CP, Cunico P (2011) Adsorption of indigo carmine from aqueous solution using coal fly ash and zeolite from fly ash. J Radioanal Nucl Chem 289(2):617–626CrossRefGoogle Scholar
  7. Cheung WH, Szeto YS, McKay G (2007) Intraparticle diffusion processes during acid dye adsorption onto chitosan. Biores Technol 98:2897–2904CrossRefGoogle Scholar
  8. Choy KKH, Porter JF, McKay G (2004) Single and multicomponent studies for the adsorption of acidic dyes on carbon from effluents. Langmuir 20:9646–9656CrossRefGoogle Scholar
  9. Dogan M, Abak H, Alkan M (2009) Adsorption of methylene blue onto hazelnut shell: kinetics, mechanism and activation parameters. J Hazard Mater 164(1):172–181CrossRefGoogle Scholar
  10. Eren ZP, Acar FN (2006) Adsorption of reactive black 5 from an aqueous solution: equilibrium and kinetic studies. Desalination 194:1–10CrossRefGoogle Scholar
  11. Faria PCC, Orfao JJM, Pereira MFR (2004) Adsorption of anionic and cationic dyes on activated carbons with different surface chemistries. Water Res 38:2043–2052CrossRefGoogle Scholar
  12. Hameed BH, Din ATM, Ahmad AL (2007) Adsorption of methylene blue onto bamboo-based activated carbon: kinetics and equilibrium studies. J Hazard Mater 141(3):819–825CrossRefGoogle Scholar
  13. Ho YS, Chiang CC (2001) Sorption studies of acid dye by mixed sorbents: adsorption. J Int Adsorpt Soc 7(2):139–147CrossRefGoogle Scholar
  14. Huang H, Xiao X, Yan B, Yang L (2010) Ammonium removal from aqueous solutions by using natural Chinese (Chende) zeolite as adsorbent. J Hazard Mater 175:247–252CrossRefGoogle Scholar
  15. Kao PC, Tzeng JH, Huang TL (2000) Removal of chlorophenols from aqueous solution by fly ash. J Hazard Mater 76(2–39):237–249CrossRefGoogle Scholar
  16. Lange CR, Mendez-Sanchez N (2010) Biological and abiotic color reduction of paper mill effluents during anaerobic composting. J Environ Eng 136:701–708CrossRefGoogle Scholar
  17. Lian L, Gue L, Gue C (2009) Adsorption of Congo red from aqueous solutions onto Ca-bentonite. J Hazard Mater 161:126–131CrossRefGoogle Scholar
  18. Lu J, Alakangas L, Jia Y, Gotthardsson J (2013) Evaluation of the application of dry covers over carbonate-rich sulphide tailings. J Hazard Mater 244–245:180–194CrossRefGoogle Scholar
  19. Ma J, Jia Y, Jing Y, Yao Y, Sun J (2012) Kinetics and thermodynamics of methylene blue adsorption by cobalt–hectorite composite. Dyes Pigment 93(1–3):1441–1446CrossRefGoogle Scholar
  20. Malik PK (2003) Use of activated carbons prepared from sawdust and rice-husk for adsorption of acid dyes: a case study of acid yellow 36. Dyes Pigment 56(3):239–249CrossRefGoogle Scholar
  21. Mohan D, Singh KP (2002) Removal of dyes from wastewater using fly ash, a low-cost adsorbent. Indus Eng Chem Res 41:3688–3695CrossRefGoogle Scholar
  22. Ozacar M, Sengil IA (2006) A two stage batch adsorber design for methylene blue removal to minimize contact time. J Environ Manag 80(4):372–379CrossRefGoogle Scholar
  23. Robinson T, McMullan G, Marchant R, Nigam P (2001) Remediation of dyes in textile effluent: a critical review on current treatment technologies with a proposed alternative. Biores Technol 77:247–255CrossRefGoogle Scholar
  24. Roy A, Chakraborty S, Kundu SP, Adhikari B, Majumder SB (2013) Lignocellulosic jute fiber as a bio-adsorbent for the removal of azo dye from its aqueous solution: batch and column studies. J Appl Polym Sci 129(1):15–27CrossRefGoogle Scholar
  25. Soco E, Kalembkiewicz J (2013) Adsorption of nickel (II) and copper (II) ions from aqueous solution by coal fly ash. JEnviron Chem Eng 1:581–588Google Scholar
  26. Terezinha EMC, Denise AF, Carina PM, Patricia C (2011) Adsorption of indigo carmine from aqueous solution using coal fly ash and zeolite from fly ash. J Radioanal Nucl Chem 289:617–626CrossRefGoogle Scholar
  27. Vassilev SV, Vassileva CG (2005) Method for characterization of composition of fly ashes from coal- fired power stations: a critical overview. Energy Fuels 19:1084–1098CrossRefGoogle Scholar
  28. Visa M, Duta A (2013) Methyl-orange and cadmium simultaneous removal using fly ash and photo-Fenton systems. J Hazard Mater 244–245:773–779CrossRefGoogle Scholar
  29. Weber WJ, Morris JC (1962) Advances in water pollution research: removal of biologically resistant pollutant from wastewater by adsorption. In: Proceedings of 1st international conference on water pollution symposium, vol 2. Pergamon Press, Oxford, pp 231–266Google Scholar
  30. Wei L, Wang K, Zhao Q, Xie C, Qiu W, Jia T (2011) Kinetics and equilibrium of adsorption of dissolved organic matter fractions from secondary effluent by fly ash. J Environ Sci 23(7):1057–1065CrossRefGoogle Scholar
  31. Yan L, Wang Y, Ma H, Han Z, Zhang Q, Chen Y (2013) Feasibility of fly ash-based composite coagulant for coal washing wastewater treatment. J Hazard Mater 203–204:221–228Google Scholar
  32. Yu J, Hu J (2011) Adsorption of perfluorinated compounds onto activated carbon and activated sludge. J Environ Eng 10:945–951CrossRefGoogle Scholar
  33. Zahrim AY, Tizaoui C, Hilal N (2011) Coagulation with polymers for nanofiltration pre-treatment of highly concentrated dyes: a review. Desalination 266:1–16CrossRefGoogle Scholar

Copyright information

© Springer-Verlag Berlin Heidelberg 2015

Authors and Affiliations

  • G. C. Kisku
    • 1
  • Markandeya
    • 2
  • S. P. Shukla
    • 2
  • D. Sen Singh
    • 3
  • R. C. Murthy
    • 4
  1. 1.Environmental Monitoring DivisionCSIR-Indian Institute of Toxicology ResearchLucknowIndia
  2. 2.Department of Civil EngineeringInstitute of Engineering and TechnologyLucknowIndia
  3. 3.Department of GeologyUniversity of LucknowLucknowIndia
  4. 4.Analytical Chemistry DivisionCSIR-Indian Institute of Toxicology ResearchLucknowIndia

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