Abstract
One of the most famous cultural heritage sites in Iran is the Taq-e Bostan world heritage site (northeast of Kermanshah city). This site includes three monuments that all have been carved on limestone. Limestone is sensitive to dissolution and freeze–thaw weathering. Hence, to assess the deterioration of the limestone, field studies and a number of laboratory tests were performed. During the field survey, types of karren forming a group of karstic surface features were observed. These features have made uneven rock surfaces. Formation of the karren near the monuments can be considered as a serious threat. In another part of this article, some index properties, such as weight loss, porosity, Brazilian tensile strength and point load index, were determined for the two series of rock samples in fresh and freeze–thaw conditions. Based on the results, the percentage of weight loss and porosity changes in the tested samples was low. It was found that the index properties of rocks treated with freeze–thaw decrease in varying levels with respect to initial values. The results showed that these variations are due to the deterioration of calcite cement filling microcracks of the rocks in the first place and increase in the porosity of the rocks after recurrent freezing and thawing in the second place. Statistical analyses were developed for predicting the percentage loss values in the index properties after freeze–thaw cycles. There were statistically direct strong relationships between the porosity and the weight loss parameters with the number of freeze–thaw cycles (exponential function with R 2 = 0.94 and linear function with R 2 = 0.97, respectively). In addition, there were inverse linear relationships between Brazilian tensile strength and point load index with the number of freeze–thaw cycles (R 2 = 0.96 and R 2 = 0.93, respectively). On the basis of the obtained results, the monument stones are at risk of deterioration, and it is imperative to take protective treatment measures in this regard. The authors have proposed some physical and chemical preservation methods for the protection of the monuments.










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References
Altindag R, Alyildiz IS, Onargan T (2004) Mechanical property degradation of ignimbrite subjected to recurrent freeze–thaw cycles. Int J Rock Mech Min Sci 41:1023–1028
American Society for Testing and Materials (ASTM) (2001b) Standard method for determination of the point load strength index of rock, ASTM Standards on Disc 04.08. Designation D5731
American Society for Testing and Materials (ASTM) (2004) Standard test method for evaluation of durability of rock erosion control under freezing and thawing conditions, D 5312-92 (1997)
Bayram F (2012) Predicting mechanical strength loss of natural stones after freeze–thaw in cold regions. Cold Reg Sci Technol 83–84:98–102
Beck K, Al-Mukhtar M (2010) Evaluation of the compatibility of building limestones from salt crystallization experiments. Geological Society, London, Special Publications 2010 (Natural Stone Resources for Historical Monuments) vol 333, pp 111–118
Beier NA, Sego DC (2009) Cyclic freeze–thaw to enhance the stability of coal tailings. Cold Reg Sci Technol 55:278–285
Berberian M (1995) Master ‘‘Blind’’ thrust faults hidden under the Zagros folds: active basement tectonics and surface morphotectonics. Tectonophysics 241:193–224
Bögli A (1960) Kalklösung und Karrenbildung. Zeits f Geomorph N E Suppl 2:4–21
Bögli A (1980) Karst hydrology and physical speleology. Springer, Berlin
Bortz S, Stecich J, Wonneberger B, Chin L (1993) Accelerated weathering in building stone. Int J Rock Mech Min Sci Geomech Abstr 30(7):1559–1562
Chen TC, Yeung MR, Mori N (2004) Effect of water saturation on deterioration of welded tuff due to freeze–thaw action. Cold Reg Sci Technol 38:127–136
Chorley RJ (1962) Geomorphology and general systems theory, United States Geological Survey Professional Paper, 500-B
Darot M, Reuschlé T (2000) Acoustic wave velocity and permeability evolution during pressure cycles on a thermally cracked granite. Int J Rock Mech Min 37:1019–1026
Dunham RJ (1962) Classification of carbonate rocks according to depositional texture. In: Ham WD (ed) Classification of carbonate rocks, A Symposium, Tulsa, OK. American Association of Petroleum Geologists Memoir, pp 108–121
Fookes PG, Dearman WR, Franklin JA (1971) Some engineering aspects of rock weathering. Q J Eng Geol 4:139–185
Hori M, Morihiro H (1998) Micromechanical analysis on deterioration due to freezing and thawing in porous brittle materials. Int J Rock Mech Min Sci 36(4):511–522
Iñigo AC, Talegón JG, Tavera SV, González SM, Marín SC, Muñoz MV, Rodríguez JLP (2013) Colour and ultrasound propagation speed changes by different ageing of freezing/thawing and cooling/heating in granitic materials. Cold Reg Sci Technol 85:71–78
International Society for Rock Mechanics (ISRM) (1978) Suggested methods for determining tensile strength of rock materials, Suggested method for determining indirect tensile strength by Brazilian test, Commission on Standardization of Laboratory and Field Tests, Z.T. Bieniawski and I. Haweks. Int J Rock Mech Min Sci Geomech Abstr 15:102–103
International Society for Rock Mechanics (ISRM) (1981) Rock characterization, testing and monitoring. In: Brown ET (ed) ISRM suggested methods. Pergamon Press, Oxford, p 211
Jamshidi A, Nikudel MR, Khamehchiyan M (2013) Predicting the long-term durability of building stones against freeze–thaw using a decay function model. Cold Reg Sci Technol 92:29–36
Karaca Z, Deliormanli AH, Elci H, Pamukcu C (2010) Effect of freeze–thaw process on the abrasion loss value of stones. Int J Rock Mech Min Sci 47(7):1207–1211
Karaca Z, Öztank N, Gökçe MV, Elçi H (2011) Effects of surface-finishing forms and cement-filling on porous dimension limestone deterioration in cold regions. Cold Reg Sci Technol 68(3):124–129
Karimi-Bavandpur A, HaiiHoseini A (1999) Geological map of Kermanshah. Geol Surv Iran (GSI) 1(100):000
Malaga-Starzec K, Akensson U, Lindqvist JE, Schouenborg B (2006) Microscopic and macroscopic characterization of the porosity of marble as a function of temperature and impregnation. Constr Build Mater 20(10):939–947
Martínez-Martínez J, Benavente D, García-del-Cura MA (2011) Spatial attenuation: the most sensitive ultrasonic parameter for detecting petrographic features and decay processes in carbonate rocks. Eng Geol 119:84–95
Martínez-Martínez J, Benavente D, Gomez-Heras M, Marco-Castaño L, García-del-Cura MÁ (2013) Non-linear decay of building stones during freeze–thaw weathering processes. Constr Build Mater 38:443–454
Matsuoka N (1990) Mechanisms of rock breakdown by frost action: an experimental approach. Cold Reg Sci Technol 17:253–270
Moropoulou A, Kouloumbi N, Haralampopoulos G, Konstanti A, Michailidis P (2003) Criteria and methodology for the evaluation of conservation interventions on treated porous stone susceptible to salt decay. Prog Org Coat 48:259–270
Nakamura Y (1996) Experimental study of rock deterioration and weathering. Tsuchi To Kiso JSSMFE 44:55–60
Ozcelik Y, Careddu N, Yilmazkaya E (2012) The effects of freeze–thaw cycles on the gloss values of polished stone surfaces. Cold Reg Sci Technol 82:49–55
Proskin S, Sego D, Alostaz M (2010) Freeze–thaw and consolidation tests on Suncor mature fine tailings (MFT). Cold Reg Sci Technol 63:110–120
Rodríguez-Gordillo J, Sáez-Pérez MP (2006) Effects of thermal changes on Macael marble: experimental study. Constr Build Mater 20:355–365
Ruedrich J, Siegesmund S (2007) Salt and ice crystallisation in porous sandstones. Environ Geol 52:225–249
Ruedrich J, Kirchner D, Siegesmund S (2011) Physical weathering of building stones induced by freeze–thaw action: a laboratory long-term study. Environ Earth Sci 63:1573–1586
Saad A, Guédon S, Martineau F (2010) Microstructural weathering of sedimentary rocks by freeze–thaw cycles: experimental study of state and transfer parameters. CR Geosci 342:197–203
Saedi B (2013) Assessment of deterioration of Bistoon Limestone with emphasis on Darius inscription. M.Sc Thesis, Faculty of Sciences, Bu-Ali Sina University, Hamedan (in Persian)
Siegesmund S, Ullemeyer K, Weiss T, Tschegg EK (2000) Physical weathering of marbles caused by anisotropic thermal expansion. Int J Earth Sci 89:170–182
Stocklin J (1968) Structural history and tectonics of Iran: a review. AAPG Bull 52:1229–1258
Takarli M, Prince W, Siddique R (2008) Damage in granite under heating/cooling cycles and water freeze–thaw condition. Int J Rock Mech Min Sci 45:1164–1175
Tan X, Chen W, Tian H, Cao J (2011) Laboratory investigations on the mechanical properties degradation of granite under freeze–thaw cycles. Cold Reg Sci Technol 68:130–138
Topal TS, Ozmen B (2000) Freeze–thaw resistance of the Yazilikaya tuffs. In: Proceedings of the 9th International Congress on Deterioration and Conservation of Stone, 19–24 June, Venice
UNESCO World Heritage Center (2007) World heritage list, Taq-e Bostan.- [Online] available from: http://whc.unesco.org/en/tentativelists/5182
US Patent No: 6296905., 2001 Method for protecting and consolidating calcareous materials
Veress M (2010) Karst environments; Karren formation in high mountains. Springer, Heidelberg
Werner E (1975) Solution of calcium carbonate and the formation of karren. Cave Geol 1:3–28
Winkler EM (1996) Properties of marble as building veneer. Int J Rock Mech Min Sci 33(2):215–218
Yavuz AB, Topal T (2007) Thermal and salt crystallization effects on marble deterioration: examples from Western Anatolia, Turkey. Eng Geol 90:30–40
Yavuz H, Altindag R, Sarac S, Ugur I, Sengun N (2006) Estimating the index properties of deteriorated carbonate rocks due to freeze–thaw and thermal shock weathering. Int J Rock Mech Min Sci 43:767–775
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This work was supported by the Bu-Ali Sina University. The authors are grateful to Mr. Mirmohammad Miri for helping the authors in the field studies.
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Ghobadi, M.H., Torabi-Kaveh, M. Assessing the potential for deterioration of limestones forming Taq-e Bostan monuments under freeze–thaw weathering and karst development. Environ Earth Sci 72, 5035–5047 (2014). https://doi.org/10.1007/s12665-014-3373-8
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DOI: https://doi.org/10.1007/s12665-014-3373-8


