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Environmental Earth Sciences

, Volume 67, Issue 7, pp 1987–2001 | Cite as

Evaluation of water quality pollution indices for heavy metal contamination monitoring: a case study from Curtin Lake, Miri City, East Malaysia

  • M. V. PrasannaEmail author
  • S. M. Praveena
  • S. Chidambaram
  • R. Nagarajan
  • A. Elayaraja
Original Article

Abstract

An integrated approach of pollution evaluation indices and statistical techniques was employed to assess the intensity and sources of pollution in Curtin Lake water, Miri City, East Malaysia. Fe, Pb and Se concentrations in most of the water samples exceed the maximum admissible concentration. The heavy metal evaluation index (HEI) shows strong correlations with heavy metal pollution index (HPI) and degree of contamination (C d), and gives a better assessment of pollution levels. Samples from all the 25 locations in the lake were classified as high in C d and low in HPI compared with the respective critical values. The modified schemes of HPI and C d show comparable results with HEI and indicate that about 48 % of the samples with values lower than mean were classed as low contamination and the remaining samples (52 %) with values greater than the mean were classed as medium contamination. Cluster analysis, principal component analysis and pollution indices reveal that the quality of water is mainly controlled by natural/geogenic processes with minor anthropogenic input. US Salinity Laboratory plot and EC classification were also been used to assess the suitability of lake water for agricultural purpose. The current distribution level of heavy metal in the lake water is of environmental and health concerns and needs attention.

Keywords

Heavy metal pollution index Degree of contamination Water quality Principal component analysis Curtin Lake 

Notes

Acknowledgments

The authors wish to express their thanks to Curtin Sarawak Research Fund (CSRF) for providing necessary financial support to carry out this study. They are also thankful to the School of Science and Technology, Universiti Malaysia Sabah, Kota Kinabalu, Malaysia for helping in the analysis of heavy metals in the water samples.

References

  1. Al-Ami MY, Al-Nakib SM, Ritha NM, Nouri AM, Al-Assina A (1987) Water quality index applied to the classification and zoning of Al-Jaysh canal, Bagdad, Iraq. J Environ Sci Health A(22):305–319Google Scholar
  2. Aqeel Ashraf M, Jamil Maah M, Yuoff I (2010) Water quality characterization of Varsity Lake, University of Malaya, Kuala Lumpur, Malaysia. E J Chem 7(S1):S245–S254CrossRefGoogle Scholar
  3. Astel A, Tsakovski S, Barbieri P, Simeonov V (2007) Comparison of self-organizing maps classification approach with cluster and principal components analysis for large environmental data sets. Water Res 41:4566–4578. doi: 10.1016/j.watres.2007.06.030 CrossRefGoogle Scholar
  4. Astel A, Tsakovski S, Simeonov V, Reisenhofer E, Piselli S, Barbieri P (2008) Multivariate classification and modeling in surface water pollution estimation. Anal Bioanal Chem 390:1283–1292. doi: 10.1007/s00216-007-1700-6 CrossRefGoogle Scholar
  5. Backman B, Bodis D, Lahermo P, Rapant S, Tarvainen T (1997) Application of a groundwater contamination index in Finland and Slovakia. Environ Geol 36:55–64. doi: 10.1007/s002540050320 CrossRefGoogle Scholar
  6. Bahar MdM, Reza MdS (2010) Hydrochemical characteristics and quality assessment of shallow groundwater in a coastal area of Southwest Bangladesh. Environ Earth Sci 61:1065–1073CrossRefGoogle Scholar
  7. Bhuiyan MAH, Parvez L, Islam MA, Dampare SB, Suzuki S (2010) Heavy metal pollution of coal mine-affected agricultural soils in the northern part of Bangladesh. J Hazard Mater 173:384–392. doi: 10.1016/j.jhazmat.2009.08.085 CrossRefGoogle Scholar
  8. Brown-Adiuku ME, Ogezi AE (1991) Heavy metal pollution from mining practices: a case study of Zurak. J Min Geol 27(2):205–211Google Scholar
  9. Caboi R, Cidu R, Fanfani L, Lattanzi P, Zuddas P (1999) Environmental mineralogy and geochemistry of the abandoned Pb–Zn Montevecchio-Ingurtosu mining district, Sardinia, Italy. Chron Rech Miniere 534:21–28Google Scholar
  10. Dragovíc S, Mihailovíc N, Gajíc B (2008) Heavy metals in soils: distribution, relationship with soil characteristics and radionuclides and multivariate assessment of contamination sources. Chemosphere 72(3):491–549. doi: 10.1016/j.chemosphere.2008.02.063 CrossRefGoogle Scholar
  11. Edet AE, Ntekim EEU (1996) Heavy metal distribution in groundwater from Akwa Ibom State, eastern Niger delta-A preliminary pollution assessment. Global J Pure Appl Sci 2(1):67–77Google Scholar
  12. Edet AE, Offiong OE (2002) Evaluation of water quality pollution indices for heavy metal contamination monitoring. A study case from Akpabuyo–Odukpani area, Lower Cross River Basin (southeastern Nigeria). GeoJournal 57:295–304. doi: 10.1023/B:GEJO.0000007250.92458.de CrossRefGoogle Scholar
  13. Erondu ES, Nduka EC (1993) A model for determining water quality index (WQI) for the classification of the New Calabar River at Aluer-Port Harcourt, Nigeria. J Environ Stud A44:131–134CrossRefGoogle Scholar
  14. Ficklin DJWH, Plumee GS, Smith KS, McHugh JB (1992) Geochemical classification of mine drainages and natural drainages in mineralized areas. In: Kharaka YK, Maest AS (eds) Water–rock interaction, vol 7. Balkema, Rotterdam, pp 381–384Google Scholar
  15. Franco-Uría A, López-Mateo C, Roca E, Fernández-Marcos ML (2009) Source identification of heavy metals in pastureland by multivariate analysis in NW Spain. J Hazard Mater 165(1–3):1008–1015. doi: 10.1016/j.jhazmat.2008.10.118 CrossRefGoogle Scholar
  16. Gotelli NJ, Ellison AM (2004) A primer of ecological statistics, 1st edn. Sinauer Associates, SunderlandGoogle Scholar
  17. Handa BK (1981) An integrated water-quality index for irrigation use. Indian J Agric Sci 51:422–426Google Scholar
  18. Hanssen JE, Rambaek JP, Semb A, Steinnes E (1980) Atmospheric deposition of trace elements in Norway. In: Darblos D, Tollan A (eds) Ecological impact of acid precipitation. SNSF-project, Oslo-As, pp 116–117Google Scholar
  19. Hem JD (1985) Study and interpretation of the chemical characteristics of natural water. USGS Water Supply Paper 2254:117–120Google Scholar
  20. Holloway JM, Dahlgren RA, Hansen B, Casey WH (1998) Contribution of bedrock nitrogen to high nitrate concentrations in stream water. Nature 395:785–788. doi: 10.1038/27410 CrossRefGoogle Scholar
  21. Horton RK (1965) An index system for rating water quality. J Water Pollut Control Fed 37:300–306Google Scholar
  22. Howitt D, Cramer D (2005) Introduction to SPSS in psychology: with supplement for releases 10, 11, 12 and 13. Pearson, HarlowGoogle Scholar
  23. Hutchison CS (2005) Geology of North-West Borneo; Sarawak. Brunei and Sabah. Elsevier, AmsterdamGoogle Scholar
  24. Imperato M, Adamo P, Naimo D, Arienzo M, Stanzione D, Violante P (2003) Spatial distribution of heavy metals in urban soils of Naples city (Italy). Environ Pollut 124:247–256. doi: 10.1016/s0269-7491(02)00478-5 CrossRefGoogle Scholar
  25. Kazi TG, Arain MB, Jamali MK, Jalbani N, Afridi HI, Sarfraz RA, Baig JA, Shah Abdul Q (2009) Assessment of water quality of polluted lake using multivariate statistical techniques: a case study. Ecotoxicol Environ Saf 72:301–309CrossRefGoogle Scholar
  26. Koterba MT, Wilde FD, Lapham WW (1995) Groundwater data collection protocols and procedures for the national water quality assessment program—collection and documentation of water quality samples and related data. US Geological Survey Open-File Report, 95–399, p 113Google Scholar
  27. Krishna AK, Satyanarayanan M, Govil PK (2009) Assessment of heavy metal pollution in water using multivariate statistical techniques in an industrial area: a case study from Patancheru, Medak District, Andhra Pradesh, India. J Hazard Mater 167:366–373. doi: 10.1016/j.jhazmat.2008.12.131 CrossRefGoogle Scholar
  28. Lermontov A, Yokoyama L, Lermontov M, Machado MAS (2009) River quality analysis using fuzzy water quality index: Ribeira do Iguape river watershed, Brazil. Ecol Ind 9:1188–1197. doi: 10.1016/j.ecolind.2009.02.006 CrossRefGoogle Scholar
  29. Li S, Xu Z, Cheng X, Zhang Q (2008) Dissolved trace elements and heavy metals in the Danjiangkou Reservoir, China. Environ Geol 55:977–983. doi: 10.1007/s00254-007-1047-5 CrossRefGoogle Scholar
  30. Li Z, Fang Y, Zeng G, Li J, Zhang Q, Yuan Q, Wang Y, Ye F (2009) Temporal and spatial characteristics of surface water quality by an improved universal pollution index in red soil hilly region of South China: a case study in Liuyanghe River watershed. Environ Geol 58:101–107. doi: 10.1007/s00254-008-1497-4 CrossRefGoogle Scholar
  31. Lorite-Herrera M, Jimenez-Espinosa R, Jimeneze-Millan J, Hiscock KM (2008) Integrated hydrochemical assessment of the Quaternary alluvial aquifer of the Guadalquivir River, Southern Spain. Appl Geochem 23:2040–2054. doi: 10.1016/j.apgeochem.2008.03.013 CrossRefGoogle Scholar
  32. Markert B, Pedrozo F, Geller W, Friese K, Korhammer S, Baffico G, Diaz M, Wolfl S (1997) A contribution to the study of the heavy-metal and nutritional element status of some lakes in the southern Andes of Patagonia (Argentina). Sci Total Environ 206:1–15CrossRefGoogle Scholar
  33. Masresha Alemayehu E, Skipperud L, Rosseland BO, Zinabu GM, Meland S, Teien HC, Salbu B (2011) Speciation of selected trace elements in three Ethiopian Rift Valley Lakes (Koka, Ziway, and Awassa) and their major inflows. Sci Total Environ 409:3955–3970CrossRefGoogle Scholar
  34. Miyai M, Tada F, Nishida H (1985) Analysis of the composition of heavy metal pollution in Japanese river sediments by principal component analysis, Japan. J Limnol 46:169–173CrossRefGoogle Scholar
  35. Mohan SV, Nithila P, Reddy SJ (1996) Estimation of heavy metal in drinking water and development of heavy metal pollution index. J Environ Sci Health A31:283–289Google Scholar
  36. Nimic DA, Moore JN (1991) Prediction of water-soluble metal concentrations in fluvially deposited tailings sediments, Upper Clark Fork Valley, Montana, USA. Appl Geochem 6:635–646. doi: 10.1016/0883-2927(91)90074-Y CrossRefGoogle Scholar
  37. Nriagu JO (1989) A global assessment of natural sources of atmospheric trace metals. Nature 338:47–49. doi: 10.1038/338047a0 CrossRefGoogle Scholar
  38. Nriagu JO (1996) A history of global metal pollution. Science 272:223–224CrossRefGoogle Scholar
  39. Nriagu JO, Pacyna JM (1988) Quantitative assessment of worldwide contamination of air, water and soils by trace-metals. Nature 333:134–139. doi: 10.1038/333134a0 CrossRefGoogle Scholar
  40. Offiong OE, Edet AE (1998a) Water quality assessment in Akpabuyo, Cross River basin, southeastern Nigeria. Environ Geol 34(2–3):167–174. doi: 10.1007/s002540050268 CrossRefGoogle Scholar
  41. Offiong OE, Edet AE (1998b) Surface water quality evaluation in Odukpani, Calabar Flank, southeastern Nigeria. Environ Geol 36(3–4):343–348. doi: 10.1007/s002540050350 CrossRefGoogle Scholar
  42. Palupi K, Sumengen S, Inswiasri S, Agustina L, Nunik SA, Sunarya W, Quraisyn A (1995) River water quality study in the vicinity of Jakarta. Water Sci Technol 39:17–25Google Scholar
  43. Panda UC, Sundaray SK, Rath P, Nayak BB, Bhatta D (2006) Application of factor and cluster analysis for characterization of river and estuarine water systems—a case study: Mahanadi River (India). J Hydrol 331:434–445. doi: 10.1016/j.jhydrol.2006.05.029 CrossRefGoogle Scholar
  44. Peierls BL, Caraco NF, Pace ML, Cole JJ (1998) Human influence on river nitrogen. Nature 350:386–387. doi: 10.1038/.350386b0 CrossRefGoogle Scholar
  45. Pekey H, Karaka D, Bakoglu M (2004) Source apportionment of trace metals in surface waters of a polluted stream using multivariate statistical analyses. Mar Pollut Bull 49:809–818CrossRefGoogle Scholar
  46. Prasad B, Bose JM (2001) Evaluation of the heavy metal pollution index for surface and spring water near a limestone mining area of the lower Himalayas. Environ Geol 41:183–188. doi: 10.1007/s002540100380 CrossRefGoogle Scholar
  47. Prasad B, Jaiprakas KC (1999) Evaluation of heavy metals in ground water near mining area and development of heavy metal pollution index. J Environ Sci Health A34(1):91–102Google Scholar
  48. Prasad B, Mondal KK (2008) The impact of filling an abandoned open cast mine with fly ash on ground water quality: a case study. Mine Water Environ 27(1):40–45. doi: 10.1007/s10230-007-0021-5 CrossRefGoogle Scholar
  49. Prasanna MV, Chidambaram S, Shahul Hameed A, Srinivasamoorthy K (2010) Study of evaluation of groundwater in Gadilam basin using hydrogeochemical and isotope data. Environ Monit Assess 168:63–90. doi: 10.1007/s10661-009-1092-5 CrossRefGoogle Scholar
  50. Ragunath HM (1987) Groundwater. Wiley Eastern Ltd, New DelhiGoogle Scholar
  51. Rapant S, Raposova M, Bodis D, Marsina K, Slaninka I (1999) Environmental geochemical mapping program in the Slovak Republic. J Geochem Explor 66:151–158. doi: 10.1016/S0375-6742(99)00037-0 CrossRefGoogle Scholar
  52. Reddy SJ (1995) Encyclopaedia of environmental pollution and control, vol 1. Environmental Media, KarliaGoogle Scholar
  53. Shoji H, Yamamota T, Nakakaga N (1966) Factor analysis of stream pollution of the Yodo River system. Air Water Pollut 10:291–299Google Scholar
  54. Shuhaimi-Othman M, Ahmad A, Mushrifah I, Lim EC (2008) Seasonal influence on water quality and heavy metals concentration in Tasik Chini, Peninsular Malaysia. In: Sengupta M, Dalwani R (eds) Proceedings of Tall2007: the 12th World Lake Conference, pp 300–303Google Scholar
  55. Siegel FR (2002) Environmental geochemistry of potentially toxic metals. Springer, BerlinGoogle Scholar
  56. Simeonova P, Simeonov V (2007) Chemometrics to evaluate the quality of water sources for human consumption. Microchim Acta 156:315–320. doi: 10.1007/s00604-006-0643-5 Google Scholar
  57. Singanan M, Wondimu L, Tesso M (2008) Water quality of Wenchi Crater Lake in Ethiopia. Maejo Int J Sci Technol 02(02):361–373Google Scholar
  58. Steinnes E, Henriksen A (1993) Metals in small Norwegian lakes: relation to atmospheric deposition of pollutants. Water Air Soil Pollut 71:167–174CrossRefGoogle Scholar
  59. Teng Y, Ni S, Jiao P, Deng J, Zhang C, Wang J (2004) Eco-environmental geochemistry of heavy pollution in Dexing Mining Area. Chin J Geochem 23(4):349–358. doi: 10.1007/BF02871307 CrossRefGoogle Scholar
  60. Venkata Mohan S, Nithila P, Jayarama Reddy S (1996) Estimation of heavy metals in drinking water and development of heavy metal pollution index. J Environ Sci Health A31(2):283–289Google Scholar
  61. World Health Organisation (WHO) (1993) Guidelines for drinking water quality, Recommmendations. Geneva, SwitzerlandGoogle Scholar
  62. World Health Organisation (WHO) (2004) Guidelines for drinking water quality (3rd edn.) (ISBN: 9241546387). Retrived from http://www.who.int/water_sanitation_health/dwq/guidelines/en/
  63. Xibao C, Shen Z, Licheng Z (1996) A study of the physicochemical speciation of heavy metals in waters of rivers and lakes in the Changjiang River valley, China. GeoJournal 40(1–2):187–195. doi: 10.1007/BF00222544 Google Scholar
  64. Yang W, Liensheng Y, Jianxun Z (1996) Effect of metal pollution on the water quality in Taiku Lake. GeoJournal 40(1–2):197–200. doi: 10.1007/BF00222545 Google Scholar
  65. Yiping H, Min Z (1996) The water quality of Lak Taihu and its protection. GeoJournal 40(1–2):39–44. doi: 10.1007/BF00222529 Google Scholar
  66. Zhang W, Feng H, Chang J, Qu J, Xie H, Yu L (2009) Heavy metal contamination in surface sediments of Yangtze River intertidal zone: an assessment from different indexes. Environ Pollut 157(5):1533–1543. doi: 10.1016/j.envpol.2009.01.1007 CrossRefGoogle Scholar
  67. Zhongyi W (1996) Surface water chemical changes due to human activities in the Tarim Basin. GeoJournal 40(1–2):25–29. doi: 10.1007/BF00222527 Google Scholar

Copyright information

© Springer-Verlag 2012

Authors and Affiliations

  • M. V. Prasanna
    • 1
    Email author
  • S. M. Praveena
    • 2
  • S. Chidambaram
    • 3
  • R. Nagarajan
    • 1
  • A. Elayaraja
    • 4
  1. 1.Department of Applied Geology, School of Engineering and ScienceCurtin UniversityMiriMalaysia
  2. 2.Centre of Marine ScienceUniversiti Putra MalaysiaPort DicksonMalaysia
  3. 3.Department of Earth ScienceAnnamalai UniversityChidambaramIndia
  4. 4.Department of Science and Foundation, School of Engineering and ScienceCurtin UniversityMiriMalaysia

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