Abstract
Various marbles from both historic quarries and historical artefacts of the Czech Republic were examined in order to make determinations of their provenance. The methodology used was based upon a combination of petrographic image analysis (PIA) of thin sections, stable isotope geochemistry of carbonates, and cathodoluminescence. Multivariate statistical methods (i.e. cluster analysis and discriminant analysis) confirmed the geoscientific relevance of the marble’s different characteristics with a high degree of consistency as well as the enhanced significance of stable C and O isotopes in correlation with the petrographic data. The qualitative cathodoluminescence data provided a useful additional tool to help recognise the fingerprinting of marbles with similar petrographic and/or geochemical characteristics.
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References
Antonelli F, Lazzarini L, Rasplus L, Turi B (2002) Petrographic and geochemical characterization of cipollino mandolato marble from the French central Pyrenees. In: Herrmann J, Herz N, Newman R (eds) ASMOSIA V. Interdisciplinary studies on ancient stone. Archetype Publications, London, pp 77–90
Attanasio D (2003) Ancient white marbles: analysis and identification by paramagnetic resonance spectroscopy. L’erma di Bretschneider, Rome
Attanasio D, Brilli M, Ogle N (2006) The isotopic signature of classical marbles. L’erma di Bretschneider, Rome
Barbin V (1999) An unidentified but probably identical origin of several white marble artefacts from the Walters art gallery (Baltimore, USA): evidence from petrographic, cathodoluminescence and stable isotope studies. In: Schvoerer M (ed) ASMOSIA IV. Archéomatériaux: Marbres et autres roches. CRPAA-Presses Universitaires de Bordeaux, Bordeaux, pp 39–43
Barbin V, Ramseyer K, Decrouez D, Burns SJ, Chamay J, Maier JL (1992) Cathodoluminescence of white marbles: an overview. Archaeometry 34:175–183
Cabral JMP, Vieira MCR, Carreira PM, Figueiredo MO, Pena TP, Tavares A (1992) Preliminary study on the isotopic and chemical characterization of marbles from Alto Alentejo (Portugal). In: Waelkens M, Herz N, Moens L (eds) ASMOSIA II. Ancient stones: quarrying, trade and provenance. Acta Archaeologica Lovaniensia, Monographiae 4. Leuven University Press, Leuven, pp 191–198
Chlupáč I, Brzobohatý R, Kovanda J, Stráník Z (2002) Geological history of the Czech Republic. Academia, Prague (in Czech)
Corazza M, Pratesi G, Cipriani C, Lo Giudice A, Rossi P, Vittone E, Manfredotti C, Pecchioni E, Manganelli Del Fá C, Fratini F (2001) Ionoluminescence and cathodoluminescence in marbles of historic and architectural interest. Archaeometry 43:439–446
Craig H, Craig V (1972) Greek marbles: determination of provenance by isotopic analysis. Science 176:401–403
Cramer T (2004) Multivariate Herkunftsanalyse von Marmor auf petrographischer und geochemischer Basis—Das Beispiel kleinasiatischer archaischer, hellenistischer und römischer Marmorobjekte der Berliner Antikensammlung und ihre Zuordnung zu mediterranen und anatolischen Marmorlagerstätten, Dissertation FG Lagerstättenforschung, Berlin, p 340. http://nbn-resolving.de/urn:nbn:de:kobv:83-opus-7426; http://opus.kobv.de/tuberlin/volltexte/2004/742/
Cramer T, Germann K, Heilmeyer W-D (2002) Petrographic and geochemical characterization of the Pergamon Altar marble in the Pergamon Museum, Berlin. In: Lazzarini L (ed) ASMOSIA VI. Interdisciplinary studies on ancient stones. Bottega d’Erasmo Aldo Ausilio Editore, Padova, pp 285–292
Cramer T, Germann K, Kästner V (2004) Provenance determination of marble from Pergamon in the Berlin Collection of Classical Antiquities—methods and results. In: Přikryl R, Siegl P (eds) Architectural and sculptural stone in cultural landscape. The Karolinum Press, Prague, pp 53–71
De Paepe P, Moens L, Roos P, Waelkens M (1988) Source analysis of the raw materials of four classical marble sculptures using chemical, microscopic and isotopic criteria. In: Herz N, Waelkens M (eds) ASMOSIA I. Classical marble: geochemistry technology trade. Kluwer Academic Publishers, Dordrecht, pp 389–398
De Paepe P, Moens L, Roos P, Barbin V, Decrouez D, Ramseyer K, Thommen L, Berger E, Faltermeier K (1992) An analytical investigation of white marble sculptures from the Basel Museum of Ancient Art and Ludwig Collection, Switzerland. In: Waelkens M, Herz N, Moens L (eds) ASMOSIA II. Ancient stones: quarrying, trade and provenance, Acta Archaeologica Lovaniensia, Monographiae 4. Leuven University Press, Leuven, pp 255–262
Dooley K, Herz N (1995) Provenance determination of early American marbles. In: Maniatis Y, Herz N, Basiakos Y (eds) ASMOSIA III. The study of marble and other stones used in antiquity. Archetype Publications, London, pp 243–251
Dreyer W (1973) The science of rock mechanics. Part I. The strength properties of rocks. In: Series on rock and soil mechanics, 2nd edn. Trans Tech Publications, Clausthal
Franke W (1992) Phanerozoic structures and events in Central Europe. In: Blundell D, Freeman R, Mueller S (eds) A continent revealed: the European Geotraverse. Cambridge University Press, Cambridge, pp 164–179
Germann K, Holzmann G, Winkler FJ (1980) Determination of marble provenance: limits of isotopic analysis. Archaeometry 22:99–106
Germann K, Gruben G, Knoll H, Valis V, Winkler FJ (1988) Provenance characteristics of Cycladic (Paros and Naxos) marbles—a multivariate geological approach. In: Herz N, Waelkens M (eds) ASMOSIA I. Classical marble: geochemistry technology trade. Kluwer Academic Publishers, Dordrecht, pp 251–262
Gorgoni C, Lazzarini L, Pallante P, Turi B (2002) An updated and detailed mineropetrographic and C-O stable isotopic reference database for the main Mediterranean marbles used in antiquity. In: Herrmann J, Herz N, Newman R (eds) ASMOSIA V Interdisciplinary studies on ancient stone. Archetype Publications, London, pp 115–131
Green WA, Young SMM, van der Merwe NJ, Herrmann JJ (2002) Source tracing marble: trace element analysis with inductively coupled plasma-mass spectrometry. In: Herrmann J, Herz N, Newman R (eds) ASMOSIA V. Interdisciplinary studies on ancient stone. Archetype Publications, London, pp 132–142
Herrmann JJ, Barbin V (1993) The exportation of marble from the Aliki quarries on Thasos: cathodoluminescence of samples from Turkey and Italy. American J. Archaeology 97:91–103
Herz N (1988) The oxygen and carbon isotopic data base for classical marble. In: Herz N, Waelkens M (eds) ASMOSIA I. Classical marble: geochemistry technology trade. Kluwer Academic Publishers, Dordrecht, pp 305–314
Jahn JJ (1929) On natural stones used in the St. Vitus’ Cathedral. Kámen 11:1–2 (in Czech)
Johnson RA, Wichern DW (1998) Applied multivariate statistical analysis, 4th edn. Prentice-Hall Inc., New Jersey
Jongste PFB, Jansen JB, Moens L, De Paepe P, Waelkens M (1992) The use of marble in Latium between 70 and 150 A.D. ICPAES for determination of the provenance of white marbles. In: Waelkens M, Herz N, Moens L (eds) ASMOSIA II. Ancient stones: quarrying, trade and provenance. Acta Archaeologica Lovaniensia, Monographiae 4. Leuven University Press, Leuven, pp 263–267
Kokkorou-Alevras G, Mandi V, Grimanis AP, Maniatis Y (1995) The traditional archaeological characterisation of marble sculpture and the results of modern scientific techniques. In: Maniatis Y, Herz N, Basiakos Y (eds) ASMOSIA III. The study of marble and other stones used in antiquity. Archetype Publications, London, pp 95–102
Krčálová J (1994) Renaissance. In: Merhautová A (ed) Saint Vitus’s cathedral of prague. Prague, Academia, pp 133–170 (in Czech)
Lapuente MP (1995) Mineralogical, petrographical and geochemical characterization of white marbles from Hispania. In: Maniatis Y, Herz N, Basiakos Y (eds) ASMOSIA III. The study of marble and other stones used in antiquity. Archetype Publications, London, pp 151–160
Lapuente P, Blanc P (2002) Marbles from Hispania: scientific approach based on cathodoluminescence. In: Herrmann J, Herz N, Newman R (eds) ASMOSIA V. Interdisciplinary studies on ancient stone. Archetype Publications, London, pp 143–151
Lapuente MP, Turi B, Blanc P (2000) Marbles from Roman Hispania: stable isotope and cathodoluminescence characterization. App Geochem 15:1469–1493
Lazzarini L, Turi B (1999) Characterisation and differentiation of the Skyros marbles (Greece) and the Medici’s breccias (Italy). In: Schvoerer M (ed) ASMOSIA IV. Archéomatériaux: Marbres et autres roches. CRPAA-Presses Universitaires de Bordeaux, Bordeaux, pp 117–123
Lazzarini L, Masi U, Tucci P (1995) Petrographic and geochemical features of the Carystian marble, ‘Cipollino verde’, from the ancient quarries of Southern Euboea (Greece). In: Maniatis Y, Herz N, Basiakos Y (eds) ASMOSIA III. The study of marble and other stones used in antiquity. Archetype Publications, London, pp 161–169
Lazzarini L, Ponti G, Martinez MP, Rockwell P, Turi B (2002) Historical, technical, petrographic and isotopic features of Aphrodisian marble. In: Herrmann J, Herz N, Newman R (eds) ASMOSIA V. Interdisciplinary studies on ancient stone. Archetype Publications, London, pp 163–168
Luke C, Tykot RH, Scott RW (2006) Petrographic and stable isotope analyses of late classic Ulúa marble vases and potential sources. Archaeometry 48:13–29
Mandi V, Vassiliou A, Maniatis Y, Grimanis AP (1995) An evaluation of the contribution of trace elements to the determination of marble provenance. In: Maniatis Y, Herz N, Basiakos Y (eds) ASMOSIA III. The study of marble and other stones used in antiquity. Archetype Publications, London, pp 207–212
McCrea JM (1950) On the isotopic chemistry of carbonates and a paleotemperature scale. J Chem Phys 18:849–857
Mello E, Meloni S, Monna D, Oddone M (1988) A computer-based pattern recognition approach to the provenance study of Mediterranean marbles through trace elements analysis. In: Herz N, Waelkens M (eds) ASMOSIA I. Classical marble: geochemistry technology trade. Kluwer Academic Publishers, Dordrecht, pp 283–291
Mentzos A, Barbin V, Herrmann JJ (2002) Cathodoluminescence and isotopic analysis of Roman and Early Byzantine architectural decoration in the Rotunda Museum, Thessaloniki. In: Herrmann J, Herz N, Newman R (eds) ASMOSIA V. Interdisciplinary studies on ancient stone. Archetype Publications, London, pp 316–327
Moens L, Roos P, De Paepe P, Scheurleer RL (1992a) Provenance determination of white marble sculptures from the Allard Pierson Museum in Amsterdam, based on chemical, microscopic and isotopic criteria. In: Waelkens M, Herz N, Moens L (eds) ASMOSIA II. Ancient stones: quarrying, trade and provenance. Acta Archaeologica Lovaniensia, Monographiae 4. Leuven University Press, Leuven, pp 269–276
Moens L, De Paepe P, Waelkens M (1992b) Multidisciplinary research and cooperation: keys to a successful provenance determination of white marble. In: Waelkens M, Herz N, Moens L (eds) ASMOSIA II. Ancient stones: quarrying, trade and provenance. Acta Archaeologica Lovaniensia, Monographiae 4. Leuven University Press, Leuven, pp 247–252
Mrázek I (1993) Stone face of Brno. Moravské zemské muzeum, Brno (in Czech)
Oddone M, Meloni S, Genova N, Maccabruni C, Pearce M (1999) The provenance of the white marble from the Torre Civica excavations (Pavia-Italy). In: Schvoerer M (ed) ASMOSIA IV. Archéomatériaux: Marbres et autres roches. CRPAA-Presses Universitaires de Bordeaux, Bordeaux, pp 141–146
Petruk W (1986) Image analysis: an overview of developments. CANMET Report 86-4E, 5 pp
Přikryl R (2001) Some microstructural aspects of strength variation in rocks. Int. J. Rock Mech Min Sci Geomech Abstr 38(5):671–682
Přikryl R (2006) Assessment of rock geomechanical quality by quantitative rock fabric coefficients: limitation and possible source of misinterpretations. Eng Geol 87:149–162
Přikryl R (2007) Understanding the Earth scientist’s role in the pre-restoration research of monuments: an overview. In: Přikryl R, Smith BJ (eds) Building stone decay: from diagnosis to conservation. Special Publication 271, Geological Society of London, pp 9–21
Ramseyer K, Decrouez D, Barbin V, Burns SJ, Moens L, De Paepe P, Roos P, Chamay J, Maier JL (1992) Provenance investigation of marble artifacts now in the collection of the Museum of Art and History in Geneva. In: Waelkens M, Herz N, Moens L (eds) ASMOSIA II. Ancient stones: quarrying, trade and provenance. Acta Archaeologica Lovaniensia, Monographiae 4. Leuven University Press, Leuven, pp 287–296
Schmid J, Ramseyer K, Decrouez D (1999a) A new element for the provenance determination of white marbles: quantitative fabric analysis. In: Schvoerer M (ed) ASMOSIA IV. Archéomatériaux: Marbres et autres roches. CRPAA-Presses Universitaires de Bordeaux, Bordeaux, pp 171–175
Schmid J, Ambühl M, Decrouez D, Müller S, Ramseyer K (1999b) A quantitative fabric analysis approach to the discrimination of white marbles. Archaeometry 41(2):239–252
Siegesmund S, Kracke T, Ruedrich J, Schwarzburg R (2010) Jewish cemetery in Hamburg Altona (Germany): State of marble deterioration and provenance. Eng Geol 115:200–208
Šťastná A, Přikryl R (2009) Decorative marbles from the Krkonoše-Jizera Terrane (Bohemian Massif, Czech Republic): provenance criteria. Int J Earth Sci 98(2):357–366
Šťastná A, Přikryl R (2010) Determination of source areas of natural stones: a methodology approach applied to impure crystalline limestones. In: Bostenaru Dan M, Přikryl R, Török Á (eds) Materials technologies and practice in historic heritage structures. Springer, Berlin, pp 157–175
Šťastná A, Přikryl R, Jehlička J (2009) Methodology of analytical study for provenance determination of calcitic, calcite-dolomitic and impure marbles from historic quarries in the Czech Republic. J Cult Herit 10(1):82–93
Systat Software Inc. (2010) SigmaScan Pro 5.0.0. http://www.sigmaplot.com/index.php (27-10-2010)
Unterwurzacher M, Polleres J, Mirwald P (2005) Provenance study of marble artefacts from the Roman burial area of Faschendorf (Carinthia, Austria). Archaeometry 47:265–273
Valley JW (1986) Stable isotope geochemistry of metamorphic rocks. In: Valley JW, Taylor HP, O’Neil JR (eds) Stable isotopes in high temperature geological processes. Reviews in Mineralogy, vol 16, pp 445–489
Acknowledgments
Financial support for this study has been provided by a project of the Ministry of the Education, Youth and Sports of the Czech Republic, Project No. MSM 0021620855, and by a postdoctoral project of the Grant Agency in the Czech Republic (GA CR) No. 205/09/P138. Special acknowledgement is given to F. Bůzek (Laboratory of stable isotopes, Czech Geological Society) for their cooperative attitude relating to the measurement of stable isotopes; V. Erban (Laboratory of radiogenic isotopes, Czech Geological Society) for help with the petrographic data visualisation (R program). The authors are also grateful to those conservationists from the National Heritage Institute who contributed artefact samples from selected historical monuments.
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An erratum to this article can be found at http://dx.doi.org/10.1007/s12665-011-1291-6
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Šťastná, A., Přikryl, R. & Černíková, A. Comparison of quantitative petrographic, stable isotope and cathodoluminescence data for fingerprinting Czech marbles. Environ Earth Sci 63, 1651–1663 (2011). https://doi.org/10.1007/s12665-010-0896-5
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DOI: https://doi.org/10.1007/s12665-010-0896-5