Skip to main content
Log in

Geochemistry of core sediments from Mullipallam creek, South East coast of India

  • Original Article
  • Published:
Environmental Earth Sciences Aims and scope Submit manuscript

Abstract

The Mullipallam creek in Muthupet mangroves region is the only E-W trending coastal strip in the SE coast of India and is very important, as the mangrove acts as a barrier to natural diasters. Natural, anthropogenic signals and accumulation of elements were made by collecting sediment samples at various depths in a core. All sediments were analyzed for carbonates (CaCO3), organic carbon (OC), major (Si, Al, Fe, Na, K, Ca, Mg, P), and trace (Mn, Cr, Cu, Ni, Co, Pb, Zn). Normalization with Al values has been done for all the major and trace elements and enrichment factors have been calculated. The calculated enrichment factors and comparison indicate that the trace metals (especially Pb) are enriched mainly due to the external (anthropogenic) activities in the land as well as in the coastal zone (Palk Strait).

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10

Similar content being viewed by others

References

  • Achyuthan H, Richardmohan D, Srinivasaslu S, Selvaraj K (2002) Trace metals concentrations in the sediment cores of estuary and tidal zones between Chennai and Pondicherry along the east coast of India. Indian J Mar Sci 31(2):141–149

    Google Scholar 

  • Ayyamperumal T, Jonathan MP, Srinivasalu S, Armstrong-Altrin JS, Ram-Mohan V (2006) Assessment of acid leachable trace metals in sediment cores from River Uppanar, Cuddalore, Southeast coast of India. Environ Pollut 143:34–45

    Article  Google Scholar 

  • Beveridge MCM, Ross LG, and Kelly LA (1993) Environmental impacts of aquaculture-disturbances of biotopes and influence of exotic or local species new to aquaculture. World Aquaculture ‘93 Conference Torremolinas, Spain, European Aquaculture Society Special Publication, Oostende, Belgium’, European Aquaculture Society, vol 19, p 494

  • Burton JD (1970) The behaviour of dissolved silicon during estuarine mixing II. Preliminary investigations in the Vellar estuary, Southern India. J Cons Perma Int Explor Mer 33:141–148

    Google Scholar 

  • Calvert SE (1976) The mineralogy and geochemistry of near shore sediments. In: Riley JP, Chester R (eds) Chemical oceanography. Academic Press, London, pp 187–280

    Google Scholar 

  • Calvert SE, Price NB (1972) Diffusion and reaction profiles of dissolved manganese in the pore water of the sediments. Earth Planet Sci Lett 16:245–249

    Article  Google Scholar 

  • Calvert SE, Pedersen TF, Thunell RC (1993) Geochemistry of the surface sediments of the Sulu and South China Seas. Mar Geol 114:207–231

    Article  Google Scholar 

  • Chatterjee M, Silva Filho EV, Sarkar SK, Sella SM, Bhattacharya A, Satpathy KK, Prasad MVR, Chakraborty S, Bhattacharya BD (2007) Distribution and possible source of trace elements in the sediment cores of a tropical macrotidal estuary and their ecotoxicological significance. Environ Int 33:346–356

    Article  Google Scholar 

  • Clark MW, McConchie D, Lewis DW, Saenger P (1998) Redox stratification and heavy metal partitioning in Avicennia-dominated mangrove sediments: a geochemical model. Chem Geol 149:147–171

    Article  Google Scholar 

  • Elderfield HC (1979) Manganese fluxes to the Oceans. Mar Chem 4:103–132

    Article  Google Scholar 

  • Enell M (1987) Environmental impact of cage fish farming with special reference to phosphorus and nitrogen loading, International Council for the Exploration of the Seas (ICES). Report No. 44

  • Ergin M, Yörük R (1990) Distribution and texture of bottom sediments in semienclosed coastal inlet, the Izmit Bay from the eastern sea of Marmara (Turkey). Estuar Coast Shelf Sci 30:647–654

    Article  Google Scholar 

  • Fedo CM, Eriksson K, Krogstad EJ (1996) Geochemistry of shales from the Archean Buhwa Greenstone Belt, Zimbabwe: implications for provenance and source-area weathering. Geochim Cosmochim Acta 60:1751–1763

    Article  Google Scholar 

  • Forstner U, Salomons W (1980) Trace metal analysis on polluted sediments. Part 1. Assessment of sources and intensities. Environ Technol Lett 1:494–505

    Article  Google Scholar 

  • Froelich PN, Klinkhammer GP, Bender ML, Luedtke NA, Heath GR, Cullen D, Dauphin P, Hammond D, Hartman B, Maynard V (1979) Early oxidation of organic matter in pelagic sediments of the eastern equatorial Atlantic: suboxic diagenesis. Geochim Cosmochim Acta 43:1075–1090

    Article  Google Scholar 

  • Gaillard JF, Pauwels H, Michard G (1989) Chemical diagenesis in coastal marine sediments. Oceanol Acta 12(3):175–187

    Google Scholar 

  • Gaudette HE, Flight WR, Toner L, Folger DW (1974) An inexpensive titration method for the determination of organic carbon in recent sediments. J Sediment Petrol 44:249–253

    Google Scholar 

  • Gesamp (1991), ‘The impact of carcinogenic substances on marine organisms and implications concerning public health preliminary study (IMO/FAO UNESCO/WMO/WHO/IAEA/UN/UNEP) Joint Group of Experts on the Scientific Aspects of Marine Pollution Reducing environmental impacts of coastal aquaculture’. Rep Stud GESAMP 47:35

  • Harbison P (1986) Mangrove muds: a sink and a source for trace metals. Mar Pollut Bull 17:246–250

    Article  Google Scholar 

  • Heaton MG, Dayal R (1985) Metals in interstitial waters of the New York bight dredged: material deposits. In: Ketchuar BH, Capuzzo JM, Burk WV, Duedall IW, Park PK, Ester DRK (eds) Wastes in the Ocean’, Nearshore waste disposal. Wiley, New York

    Google Scholar 

  • Huc AY (1980) Origin and formation of organic matter in recent sediments and its relation to Kerogen. In: Durand B (ed) Kerogen: Matiére organique insoluble de roches sédimentaries, Technip, Paris, pp 446–474

  • Ingram RL (1970) Procedures in Sedimentary Petrology. Wiley, NewYork,USA

    Google Scholar 

  • Janaki-Raman D, Jonathan MP, Srinivasalu S, Armstrong-Altrin JS, Mohan SP, Ram-Mohan V (2007) Trace metal enrichments in core sediments in Muthupet mangroves, SE coast of India: application of acid leachable technique. Environ Poll 145:245–257

    Article  Google Scholar 

  • Jonathan MP (2001) Geochemical characteristics of surface and core sediments, off Tuticorin, Gulf of Mannar, South India: implications for metal pollution. Ph.D. Thesis, University of Madras, Chennai, p 199 (Unpublished)

  • Jonathan MP, Ram-Mohan V (2003) Heavy metals in sediments of the innershelf off Gulf of Mannar, southeast coast of India. Mar Pollut Bull 46:263–268

    Article  Google Scholar 

  • Jonathan MP, Ram-Mohan V, Srinivasalu S (2004) Geochemical variations of major and trace elements in recent sediments, off the Gulf of Mannar, the southeast coast of India. Environ Geol 45:466–480

    Article  Google Scholar 

  • Kemp ALW, Thomas RL, Dell CI, Jaquet JM (1976) Cultural impact on the geochemistry of sediments in Lake Erie. Can J Fish Aquat Sci 33:440–462

    Google Scholar 

  • Koldijk WS (1968) On environment-sensitive grain size parameters. Sedimentology 10:57–69

    Article  Google Scholar 

  • Kotmire SY, Bhosale LJ (1979) Some aspects of chemical composition of mangrove leaves and sediments. Mahasagar Bull Natl Inst Oceanogr 12:149–151

    Google Scholar 

  • Lakshumanan C (2001) Modeling organic carbon deposition, degradation and preservation in sediments of Pichavaram mangrove wetlands, southeast coast of India. Ph.D. thesis, Anna University, Chennai, India, p 188

  • Li YH, Bischoff J, Mathieu G (1969) The migration of manganese in the Arctic basin sediments. Earth Planet Sci Lett 7:265–270

    Article  Google Scholar 

  • Liss PS (1976) Conservative and non-conservative behaviour of dissolved constituents during estuarine mixing. In: Burton JD, Liss PS (eds) Estuarine chemistry. Academic Press, London, pp 93–174

    Google Scholar 

  • Loring DH (1991) Normalization of heavy-metal data from estuarine and coastal sediments. ICES J Mar Sci 48:101–115

    Article  Google Scholar 

  • Loring DH, Rantala RTT (1992) Manual for the geochemical analyses of marine sediments and suspended particulate matter. Earth Sci Rev 32:235–283

    Article  Google Scholar 

  • McCave IN (1972) Transport and escape of fine-grained sediment from shelf areas. In: Swift DJP, Duane DB, Pilkey OH (eds) Shelf sediment transport, Strousburg, Pennsylvania, Dowden, Hutchinson and Ross, pp 225–248

  • Mohanachandran G (1988) Heavy metal distribution in deltaic and coastal sediments inbetween Palar and Cauvery rivers. M.Phil. Dissertation, Jawaharlal Nehru University, New Delhi, India (Un Publ.)

  • Mohanachandran G, Subramanium V (1990) Texture, mineralogy and elemental composition of sediments along the south east coast of India. Indian J Mar Sci 19:128–132

    Google Scholar 

  • Murthy PSN, Veerayya M (1972) Studies on the sediment of Vembanad Lake, Kerala State, Part–I. Distribution of organic matter. Indian J Mar Sci 1:45–51

    Google Scholar 

  • Nair RR, Hashimi NH (1980) Holocene climatic inferences from the sediments of the western Indian continental shelf. Proc Indian Acad Sci 89:299–315

    Article  Google Scholar 

  • Nath BN, Kunzendorf H, Pluger WL (2000) Influence of provenance, weathering, and sedimentary processes on the elemental ratios of the fine-grained fraction of the bed load sediments from the Vembanad Lake and the adjoining continental shelf, southwest coast of India. J Sediment Res 70(50):1081–1094

    Article  Google Scholar 

  • Nesbitt HW, Young GM (1982) Early Proterozoic climates and platemotions inferred from major element chemistry of lutites. Nature 299:715–717

    Article  Google Scholar 

  • Nesbitt HW, Young GM, McLennan SM, Keays RR (1996) Effects of chemical weathering and sorting on the petrogenesis siliclastic sediments with implications for provenance studies. J Geol 104:525–542

    Article  Google Scholar 

  • Nittrouer CA, Sharara MT, De Master DJ (1983) Variations of sediment texture on the Amazon continental shelf. J Sediment Petrol 53(1):179–191

    Google Scholar 

  • Oenema O, Steneker R, Reynders J (1988) The soil environment of the intertidal area in the Westerschelde. Hydrobiol Bull 22:21–30

    Article  Google Scholar 

  • Paropkari AL (1979) Distribution of organic carbon in sediments of the northwestern continental shelf of India. Indian J Mar Sci 8:127–129

    Google Scholar 

  • Periakali P, Eswaramoorthi S, Subramanian S, Jaisankar P (2000) Geochemistry of Pichavaram mangrove sediments, southeast coast of India. J Geol Soc India 55:387–394

    Google Scholar 

  • Pillay TVR (1992) Aquaculture and the environment. Fishing News Books, Oxford, UK, p 189

    Google Scholar 

  • Pillnac RB (1992) Multiuse conflicts in aquaculture, sociocultural aspects. World Aquac 23(2):16–29

    Google Scholar 

  • Purnachandra Rao V, Mohan Rao K, Vora KH, Almeida F, Subramaniam MM, Souza CGA (1998) A potential phosphorite deposit on the continental margin off Chennai. Curr Sci 74(7):574–577

    Google Scholar 

  • Ramanathan AL (1997) Sediment characteristics of the Pichavaram mangrove environment, southeast coast of India. Indian J Mar Sci 26:319–322

    Google Scholar 

  • Ramanathan AL, Subramanian V, Ramesh R, Chidambaram S, James A (1997) Environmental geochemistry of the Pichavaram mangrove ecosystem (tropical), southeast coast of India. Environ Geol 37(3):223–233

    Article  Google Scholar 

  • Rao CHM, Murty PSN (1990) Geochemistry of the continental margin sediments of the Central West Coast of India. J Geol Soc India 35:19–37

    Google Scholar 

  • Rao NVND, Rao MP (1969) Calcium carbonate in the sediments of the eastern part of Bay of Bengal. Curr Sci 38(8):195–196

    Google Scholar 

  • Rao MSS, Rao MP (1975) Distribution patterns of calcium carbonate and organic matter in the shelf sediments off the Mangalore coast’, India. In: Proceedings of the Symposium on Sediment, sedimentation and sedimentary environments, University of Delhi, Delhi, pp 149–157

  • Ravichandran M, Baskaran M, Santschi PH, Bianchi TS (1995) History of trace-metal pollution in Sabine-Neches estuary, Beaumount, Texas. Environ Sci Technol 29(6):1495–1503

    Article  Google Scholar 

  • Ray AK, Tripathy SC, Patra S, Sarma VV (2006) Assessment of Godavari estuarine mangrove ecosystem through trace metal studies. Environ Int 32:219–223

    Article  Google Scholar 

  • Ross A (1989) Nuvan use in salmon farming: the antithesis of the precautionary principle. Mar Pollut Bull 20:372–374

    Article  Google Scholar 

  • Ross A, Horsman PV (1988) The use of Nuvan 500 EC in the Salmon farming industry. Report by the Marine Conservation Society’, In: Shepherd CJ, Bromage NR (ed) Intensive fish farming, Oxford’ BSP Professional Books, p 404

  • Santschi PH, Hohener P, Benoit G, Bucholtz-ten Brink M (1990) Chemical processes at the sediment-water interface. Mar Chem 30:269–315

    Article  Google Scholar 

  • Sarangi RK, Kathiresan K, Subramanian AN (2002) Metal concentrations in five mangrove species of the Bhitarkanika, Orissa, east coast of India. Indian J Mar Sci 31(3):251–253

    Google Scholar 

  • Sarin MM, Borole DV, Krishnaswami S (1979) Geochemistry and geochronology of sediments from the Bay of Bengal and equatorial Indian Ocean. Proc Indian Acad Sci 88:131–154

    Article  Google Scholar 

  • Sarkar SK, Franciscovic-Bilinski S, Bhattacharya A, Saha M, Bilinski H (2004) Levels of elements in the surficial estuarine sediments of the Hugli River, northeast India and their environmental implications. Environ Int 30:1089–1098

    Article  Google Scholar 

  • Selvam V (2003) Environmental classification of mangrove wetlands of India. Curr Sci 84(6):757–765

    Google Scholar 

  • Selvaraj K, Ram-Mohan V, Srinivasalu S, Jonathan MP, Siddartha R (2003) Distribution of nondetrital trace metals in sediments cores from Ennore Creek, south east coast of India. J Geol Soc India 62:191–204

    Google Scholar 

  • Selvaraj K, Ram-Mohan V, Szefer P (2004) Evaluation of metal contamination in coastal sediments of the Bay of Bengal, India: geochemical and statistical approaches. Mar Pollut Bull 49:174–185

    Article  Google Scholar 

  • Selvaraj K, Ram-Mohan V, Jonathan MP, Srinivasalu S (2005) Modification of a coastal environment: Vedaranniyam wetland, southeast coast of India. J Geol Soc India 66:535–538

    Google Scholar 

  • Shaw T, Gieskes JM, Jahnke RA (1990) Early diagenesis in differing depositional environments. The responses of transition metals in pore water. Geochim Cosmochim Acta 54:1233–1246

    Article  Google Scholar 

  • Sreenivasa Rao Amaraneni (2006) Distribution of pesticides, PAHs and heavy metals in prawn ponds near Kolleru lake wetland, India. Environ Int 32(3):294–302

    Article  Google Scholar 

  • Subba Rao M (1958) Distribution of calcium carbonate in the shelf sediments off east coast of India. J Sediment Petrol 28:274–285

    Google Scholar 

  • Sundararajan M (2001) Geochemistry of core sediments from the continental slope of Bay of Bengal, Gulf of Mannar, Tamil Nadu. M.Phil. Dissertation, University of Madras, Chennai, p 68 (Unpublished)

  • Szefer P, Skwarzec B (1988) Distribution and possible sources of some elements in the sediment cores of the southern Baltic. Mar Chem 23:109–129

    Article  Google Scholar 

  • Szefer P, Glasby GP, Szefer K, Pempkowiak J, Kaliszan R (1996) Heavy-metal pollution in superficial sediments from the southern Baltic sea of Poland. J Environ Sci Health 31A:2723–2754

    Article  Google Scholar 

  • Tam NFY, Wong YS (1993) Retention of nutrients and heavy metals in mangrove sediments receiving wastewater of different strengths. Environ Technol 14:719–729

    Article  Google Scholar 

  • Tam NFY, Wong YS (1995) Retention and distribution of heavy metals in mangrove soils receiving wastewater. Environ Pollut 94:283–291

    Article  Google Scholar 

  • Tam NFY, Wong YS (2000) Spatial variation of heavy metals in surface sediments of Hong Kong mangrove swamps. Environ Pollut 110:195–205

    Article  Google Scholar 

  • Taylor SR, McLennan SM (1985) The continental crust: its composition and evolution. Blackwell Publishers, London, p 312

    Google Scholar 

  • Thomson-Becker EA, Luoma SN (1985) Temporal fluctuations in grain size, organic materials and iron concentrations in intertidal surface sediment of San Francisco Bay. Hydrobiologia 129:91–107

    Article  Google Scholar 

  • Van Geen A, Luoma SN (1999) The impact of human activities on sediments of San Francisco Bay, California: an overview. Mar Chem 64:1–6

    Article  Google Scholar 

  • VanMetre PC, Callender E (1997) Water-quality trends in white rock creek basin from 1912–1994 identified using sediment cores from white rock lake reservoir, Dallas, Texas. J Paleolimnol 17:239–249

    Article  Google Scholar 

  • Warren LJ (1981) Contamination of sediments by lead, zinc and cadmium: a review. Environ Pollut Ser B2:401–436

    Article  Google Scholar 

  • Zwolsman JJG, Berger GW, Van Eck GTM (1993) Sediment accumulation rates, historical input, post depositional mobility and retention of major elements and trace metals in salt marsh sediments of the Scheldt estuary, SW Netherlands. Mar Chem 44:73–94

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to M. Sundararajan.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Sundararajan, M., Natesan, U. Geochemistry of core sediments from Mullipallam creek, South East coast of India. Environ Earth Sci 61, 947–961 (2010). https://doi.org/10.1007/s12665-009-0414-9

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s12665-009-0414-9

Keywords

Navigation