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Potential risks to freshwater resources as a result of leakage from CO2 geological storage: a batch-reaction experiment

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Abstract

In assessing the feasibility of widespread deployment of CO2 geological storage, it is prudent to first assess potential consequences of an error or accident that could lead to CO2 leakage into groundwater resources above a sequestration interval. Information about the sensitivity of the groundwater system to introduction of CO2 is needed in order to design groundwater monitoring program. A laboratory-batch experiment was conducted to explore the range of CO2 impact on groundwater quality of a spectrum of representative aquifers, in the Gulf Coast region, USA. Results show that CO2 elevated concentrations of many cations within hours or days. Two types of cations were recognized according to their concentration trends. Type I cations—Ca, Mg, Si, K, Sr, Mn, Ba, Co, B, Zn—rapidly increased following initial CO2 flux and reached stable concentrations before the end of the experiment. Type II cations—Fe, Al, Mo, U, V, As, Cr, Cs, Rb, Ni and Cu—increased at the start of CO2 flux, but declined, in most cases, to levels lower than pre-CO2 concentrations. Dissolution of dolomite and calcite caused the largest increase in concentrations for Ca, Mg, Mn, Ba and Sr. Cation release rates decreased linearly as pH increased during mineral buffering. Experiment results suggest that carbonate minerals are the dominant contributor of changes in groundwater quality. Risk assessments of potential degradation of groundwater and monitoring strategies should focus on these fast-reacting minerals. Mobilization risk of Type II cations, however, may be self-mitigated because adsorption occurs when pH rebounds.

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References

  • Bachu S, Gunter WD, Perkins EH (1994) Aquifer disposal of CO2: hydrodynamic and mineral trapping. Energy Convers Manag 35:269–279

    Article  Google Scholar 

  • Baines SJ, Worden RH (2004) Geological storage of carbon dioxide. In: Baines SJ, Worden RH (eds) Geological storage of carbon dioxide. Special publication 233. Geological Society, London, pp 1–6

  • Bradl HB (2004) Adsorption of heavy metal ions on soils and soils constituents. J Colloid Interface Sci 277:1–18

    Article  Google Scholar 

  • Carmichael SK, Ferry JM, McDonough WF (2008) Formation of replacement dolomite in the Latemar carbonate buildup, Dolomites, northern Italy: part 1. Field relations, mineralogy, and geochemistry. Am J Sci 308:851–884

    Article  Google Scholar 

  • Duckworth OW, Martin ST (2004) Dissolution rates and pit morphologies of rhombohedral carbonate minerals. Am Mineral 89:554–563

    Google Scholar 

  • Edmunds WM, Cook JM, Kinniburgh DG, Miles DL, Trafford JM (1989) Trace-element occurrence in British groundwaters. British Geological Survey Report, Hydrogeology Series, SD/89/3

  • Gillhaus A, Habermann D, Meijer J, Richter DK (2000) Cathodoluminescence spectroscopy and micro-PIXE: combined high resolution Mn-analyses in dolomites—first results. Nucl Instrum Method Phys Res B 161–163:842–845

    Article  Google Scholar 

  • Gunter WD, Perkins EH, McCann TJ (1993) Aquifer disposal of CO2-rich greenhouse gases: reaction design for added capacity. Energy Convers Manag 34:941–948

    Article  Google Scholar 

  • Gunter WD, Wiwehar B, Perkins EH (1997) Aquifer disposal of CO2-rich greenhouse gases: extension of the time scale of experiment for CO2-sequestering reactions by geochemical modeling. Mineral Petrol 59:121–140

    Article  Google Scholar 

  • Gunter WD, Perkins EH, Hutcheon I (2000) Aquifer disposal of acid gases: modeling of water–rock reactions for trapping of acid wastes. Appl Geochem 15:1085–1095

    Article  Google Scholar 

  • Gunter WD, Bachu S, Benson S (2004) The role of hydrogeological and geochemical trapping in sedimentary basins for secure geological storage of carbon dioxide. In: Baines SJ, Worden RH (eds) Geological storage of carbon dioxide. Special publication 233. Geological Society, London, pp 129–145

  • Hillier S (2000) Accurate quantitative analysis of clay and other minerals in sandstones by XRD: comparison of a Rietveld and a reference intensity ratio (RIR) method and the importance of sample preparation. Clay Miner 35:291–302

    Article  Google Scholar 

  • Hovorka SD, Doughty C, Benson SM, Freifeld BM, Sakurai S, Daley TM, Kharaka YK, Holtz MH, Trautz RC, Nance HS, Myer LR, Knauss KG (2006) Measuring permanence of CO2 storage in saline formations: the Frio experiment. Environ Geosci 13:105–121

    Article  Google Scholar 

  • Hovorka SD, Meckel TA, Trevino RH, Nicot JP, Choi J-W, Romanak K, Lu J, Kordi M (2009) SECARB phase III early test, annual SECARB stakeholders briefing. http://www.secarbon.org/nonpublic/TrevinoP3.pdf

  • Johnson JW, Nitao JJ, Steefel CI, Knauss KG (2001) Reactive transport modeling of geologic CO2 sequestration in saline aquifers: the influence of intra-aquifer shales and the relative effectiveness of structural, solubility, and mineral trapping during prograde and retrograde sequestration. In: Proceedings: first national conference on carbon sequestration. National Energy Technology Laboratory, Washington, DC

  • Kaszuba JP, Janecky DR, Snow MG (2003) Carbon dioxide reaction processes in a model brine aquifer at 200°C and 200 bars: implications for geologic sequestration of carbon. Appl Geochem 18:1065–1080

    Article  Google Scholar 

  • Kaszuba JP, Janecky DR, Snow MG (2005) Experiment evaluation of mixed fluid reactions between supercritical carbon dioxide and NaCl brine: relevance to the integrity of a geologic carbon repository. Chem Geol 217:277–293

    Article  Google Scholar 

  • Kharaka YK, Cole DR, Hovorka SD, Gunter WD, Knauss KG, Freifeld BM (2006) Gas-water-rock interactions in Frio Formation following CO2 injection: implications for the storage of greenhouse gases in sedimentary basins. Geology 34:577–580

    Article  Google Scholar 

  • Kirste DM, Watson MN, Tingate PR (2004) Geochemical modelling of CO2-water-rock interaction in the Pretty Hill formation, Otway Basin. In: Boult PJ, Johns DR, Lang SC (eds) Eastern Australasian basins symposium II. Special publication 19–22. Petroleum Exploration Society of Australia, Adelaide, South Australia, pp 403–411

  • Knauss KG, Johnson JW, Steefel CI (2005) Evaluation of the impact of CO2, co-contaminant gas, aqueous fluid, and reservoir rock interactions on the geologic sequestration of CO2. Chem Geol 217:339–350

    Article  Google Scholar 

  • Lu J (2008) CO2 interaction with aquifer and seal on geological timescales: the Miller oilfield, UK North Sea. PhD thesis, The University of Edinburgh, Scotland, p 194

  • Martínez CE, Motto HL (2000) Solubility of lead, zinc, and copper added to mineral soils. Environ Pollut 107:153–158

    Article  Google Scholar 

  • Matter JM, Takahashi T (2007) Experimental evaluation of in situ CO2-water-rock reactions during CO2 injection in basaltic rocks: implications for geological CO2 sequestration. Geochem Geophys Geosyst 8:Q02001. doi:10.1029/2006GC001427

    Article  Google Scholar 

  • Metcalfe R (1996) CO2 leakage and potable groundwater quality. In: Holloway S (ed) The underground disposal of carbon dioxide. Final Report of JOULE II Project No. CT92-0031. British Geological Survey, pp 139–151

  • Palandri JL, Kharaka YK (2005) Ferric iron-bearing sediments as a mineral trap for CO2 sequestration: iron reduction using sulfur-bearing waste gas. Chem Geol 217:351–364

    Article  Google Scholar 

  • Pearce JM, Holloway S, Wacker H, Nelis MK, Rochelle C, Bateman K (1996) Natural occurrences as analogues for the geological disposal of carbon dioxide. Energy Convers Manag 37:1123–1128

    Article  Google Scholar 

  • Perkins EH, Gunter WD (1995) Aquifer disposal of CO2-rich greenhouse gases: modelling of water-rock reaction paths in a siliciclastic aquifer. In: Kharaka YK, Chudaev OV (eds) VIII international symposium on water-rock interaction. Balkema, Rotterdam, pp 895–898

    Google Scholar 

  • Perkins EH, Gunter WD, Hutcheon I, Shevalier M, Durocher K, Emberley S (2002) Geochemical modelling and monitoring of CO2 storage at the Weyburn site, Saskatchewan, Canada. Geological Society of America Annual Meeting 174(11), Denver, Colorado, October 27–30

  • Pokrovsky OS, Golubev SV, Schott J (2004) Dissolution kinetics of calcite, dolomite and magnesite at 25°C and 0 to 50 atm pCO2. Chem Geol 217:239–255

    Article  Google Scholar 

  • Rochelle CA, Czernichowski-Lauriol I, Milodowski AE (2004) The impact of chemical reactions on CO2 storage in geological formations: a brief review. In: Baines SJ, Worden RH (eds) Geological storage of carbon dioxide. Special publication 233. Geological Society, London, pp 87–106

  • Rosenbauer RJ, Koksalan T, Palandri JL (2005) Experimental investigation of CO2–brine–rock interactions at elevated temperature and pressure: implications for CO2 sequestration in deep saline aquifers. Fuel Process Technol 86:1581–1597

    Article  Google Scholar 

  • Schrag DP (2007) Preparing to capture carbon. Science 315:812–813

    Article  Google Scholar 

  • Smyth RC, Hovorka SD, Lu J, Romanak KD, Partin JW, Wong C, Yang C (2009) Assessing risk to freshwater resources from long term CO2 injection—laboratory and field studies. Energy Procedia 1:1957–1964

    Article  Google Scholar 

  • Soong Y, Goodman AL, McCarthy-Jones JR, Baltrus JP (2004) Experimental and simulation studies on mineral trapping of CO2 with brine. Energy Convers Manag 45:1845–1859

    Article  Google Scholar 

  • Temminghoff EJM, van der Zee SEATM, de Haan FAM (1997) Copper mobility in a copper-contaminated sandy soil as affected by pH and solid and dissolved organic matter. Environ Sci Technol 31:1109–1115

    Article  Google Scholar 

  • Veizer J (1983) Trace elements and isotopes in sedimentary carbonates. In: Reeder RJ (ed) Carbonates: mineralogy and chemistry. Rev Mineral 11:265–299

  • Wang S, Jaffe PR (2004) Dissolution of a mineral phase in potable aquifers due to CO2 releases from deep formations; effect of dissolution kinetics. Energy Convers Manag 45:2833–2848

    Article  Google Scholar 

  • White SP, Allis RG, Moore J, Chidsey T, Morgan C, Gwynn W, Adams M (2005) Simulation of reactive transport of injected CO2 on the Colorado Plateau, Utah, USA. Chem Geol 217:387–405

    Article  Google Scholar 

  • Xu T, Apps JA, Pruess K (2004) Numerical simulation to study mineral trapping for CO2 disposal in deep aquifers. Appl Geochem 19:917–936

    Article  Google Scholar 

  • Xu T, Apps JA, Pruess K (2005) Mineral sequestration of carbon dioxide in a sandstone–shale system. Chem Geol 217:295–318

    Article  Google Scholar 

  • Yin Y, Allen HE, Huang CP, Li Y, Sanders PF (1996) Adsorption of mercury (II) by soil: effects of pH, chloride, and organic matter. J Environ Qual 25:837–844

    Article  Google Scholar 

  • Zerai B, Saylor BZ, Matiso G (2006) Computer simulation of CO2 trapped through mineral precipitation in the Rose Run sandstone, Ohio. Appl Geochem 21:223–240

    Article  Google Scholar 

  • Zheng L, Apps JA, Zhang Y, Xu T, Birkholzer JT (2009) Reactive transport simulations to study groundwater quality changes in response to CO2 leakage from deep geological storage. Energy Procedia 1:1887–1894

    Article  Google Scholar 

Download references

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Authors and Affiliations

  1. Gulf Coast Carbon Center, Bureau of Economic Geology, Jackson School of Geosciences, The University of Texas at Austin, P.O. Box X, Austin, TX, 78713, USA

    Jiemin Lu & Susan D. Hovorka

  2. Department of Geological Sciences, Jackson School of Geosciences, The University of Texas at Austin, Austin, TX, 78712, USA

    Judson W. Partin & Corinne Wong

Authors
  1. Jiemin Lu
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  2. Judson W. Partin
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  3. Susan D. Hovorka
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  4. Corinne Wong
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Correspondence to Jiemin Lu.

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Lu, J., Partin, J.W., Hovorka, S.D. et al. Potential risks to freshwater resources as a result of leakage from CO2 geological storage: a batch-reaction experiment. Environ Earth Sci 60, 335–348 (2010). https://doi.org/10.1007/s12665-009-0382-0

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