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Water chemistry and heavy metal distribution in an AMD highly contaminated river

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Abstract

Environmental impacts of acid mine drainage (AMD) from Dexing Copper Mine, the largest open pit copper mine in Asia, on Le An River were well documented 10 years ago. However, ore production of the mine has increased fourfold and the contamination situation of the river now is unknown. Our studies indicated that heavy metal concentrations in riverwaters (dissolved), suspended solids (SS) and sediments all showed highly localized distribution patterns closely associated with two AMD-contaminated tributaries (Dawu River and Ji River) and are significantly different from the previous findings. Compared with the previous reports, most of the sampling sites in Le An River displayed lower contents of sediments of 2005 because several historical upstream and downstream heavy metal sources disappeared or became unimportant. The surprised decrease of copper contents in sediments at the mixing location with Dawu River was mainly due to dilution from the sufficient input of poor copper ore (<0.3%).

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References

  • Agemian H, Chau ASY (1975) An atomic absorption method for the determination of 20 elements in lake sediments after acid digestion. Anal Chim Acta 80:61–66

    Article  Google Scholar 

  • Battaglia M, Hose GC, Turak E, Warden B (2005) Depauperate macroinvertebrates in a mine affected stream: clean water may be the key to recovery. Environ Pollut 138:132–141

    Article  Google Scholar 

  • Boult S, Collins DN, White KN, Curtis CD (1994) Metal transport in a stream polluted by acid mine drainage—the Afon Goch, Anglesey, UK. Environ Pollut 84:279–284

    Article  Google Scholar 

  • Calmano W, Hong J, Fostner U (1992) Influence of pH value and redox potential on binding and mobilization of heavy metals in contaminated sediments. Vom Wasser 78:245–257

    Google Scholar 

  • Cherry DS, Currie RJ, Soucek DJ, Latimer HA, Trent GC (2001) An integrative assessment of a watershed impacted by abandoned mined land discharges. Environ Pollut 111:377–388

    Article  Google Scholar 

  • DeNicola DM, Stapleton MG (2002) Impact of acid mine drainage on benthic communities in streams: the relative roles of substratum vs. aqueous effects. Environ Pollut 119:303–315

    Article  Google Scholar 

  • Hart BT (1982) Uptake of trace metals by sediments and suspended particulates: a review. Hydrobiologia 91(92):299–313

    Google Scholar 

  • He M, Wang Z, Tang H (1997) Spatial and temporal patterns of acidity and heavy metals in predicting the potential for ecological impact on the Le An river polluted by acid mine drainage. Sci Total Environ 206:67–77

    Article  Google Scholar 

  • He M, Wang Z, Tang H (1998) The chemical, toxicological and ecological studies in assessing the heavy metal pollution in Le An river, China. Water Res 32:510–518

    Article  Google Scholar 

  • Jain CK, Singhal DC, Sharma MK (2005) Metal pollution assessment of sediment and water in the River Hindon, India. Environ Monit Assess 105:193–207

    Article  Google Scholar 

  • Kemper T, Sommer S (2002) Estimate of heavy metal contamination in soils after a mining accident using reflectance spectroscopy. Environ Sci Technol 36:2742–2747

    Article  Google Scholar 

  • Le XH, Zhang ZH (2001) Geology and ore-forming fluid typys of the Yinshan copper-lead-zinc deposit, Jiangxi. Geol Contrib Geol Min Resour Res 16(1):28–31 (in Chinese)

    Google Scholar 

  • Lin YH, Li Q (1992) Effects of acid mine drainage on Le An River water quality. Chin J Environ Sci 13(4):9–14 (in Chinese)

    Google Scholar 

  • Liu MS (2000) Quality and quantity variation of acid mine drainage from Yinshan lead and zinc mine. Copp Eng (4):59–63 (in Chinese)

  • Liu C (2001) Study on the cause of formation of acidic waste water in Dexing Copper Mine. Nonferr Mines 30(4):49–53 (in Chinese)

    Google Scholar 

  • Liu W, Wang Z, Wen X, Tang H (1999) The application of preliminary sediment quality criteria to metal contamination in the Le An River. Environ Pollut 105:355–366

    Article  Google Scholar 

  • Liu WX, Coveney RM, Chen JL (2003) Environmental quality assessment on a river system polluted by mining activities. Appl Geochem 18:749–764

    Article  Google Scholar 

  • Ma R, Van Mol W, Adams F (1994) Determination of cadmium, copper and lead in environmental samples. An evaluation of flow injection on injection on-line sorbent extraction for flame atomic absorption spectrometry. Anal Chim Acta 285:33–43

    Article  Google Scholar 

  • Mao M, Liu Z, Dong H (1992) Distribution and speciation of metals in sediments along Le An River. J Environ Sci (China) 4(3):72–81

    Google Scholar 

  • Ostlund P, Reeder RJ (1995) Relationship between surface structure, growth mechanism and trace element incorporation in calcite. Geochim Cosmochim Acta 59:735–749

    Article  Google Scholar 

  • Pain DJ, Sanchez A, Meharg AA (1998) The Donana ecological disaster: contamination of a world heritage estuarine marsh ecosystem with acidified pyrite mine waste. Sci Total Environ 222:45–54

    Article  Google Scholar 

  • Schofielda S, Jankowski J (2004) Hydrochemistry and isotopic composition of Na–HCO3 − rich groundwaters from the Ballimore region, central New South Wales. Aust Chem Geol 211:111–134

    Article  Google Scholar 

  • Suteerapataranon S, Bouby M, Geckeis H, Fanghänel T, Grudpan K (2006) Interaction of trace elements in acid mine drainage solution with humic acid. Water Res 40:2044–2054

    Article  Google Scholar 

  • Taylor BE, Wheeler MC, Nordstrom DK (1985) Stable isotope geochemistry of acid mine drainage: experimental oxidation of pyrite. Geochim Cosmochim Acta 48:2669–2678

    Article  Google Scholar 

  • von der Heyden CJ, New MG (2004) Groundwater pollution on the Zambian Copperbelt: deciphering the source and the risk. Sci Total Environ 327:17–30

    Article  Google Scholar 

  • Wen X, Allen HE (1999) Mobilization of heavy metals from Le An River sediment. Sci Total Environ 227:101–108

    Article  Google Scholar 

  • Xiao HY, Liu CQ (2002) Sources of nitrogen and sulfur in wet deposition at Guiyang, Southwest China. Atmos Environ 36:5121–5130

    Article  Google Scholar 

  • Yanagisawa F, Sakai H (1983) Thermal decomposition of barium sulfate-vanadium pentaoxide-silica glass mixtures for preparation of sulfur dioxide in sulfur isotope ratio measurements. Anal Chem 55:985–987

    Article  Google Scholar 

  • Zhu X, Huang CK, Rui ZY, Zhou YH, Zhu XJ, Hu ZS, Mei ZK (1983) Dexing porphyry copper deposits. Geological Press, Beijing (in Chinese)

    Google Scholar 

Download references

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Authors and Affiliations

  1. Environmental Science and Engineering School, Nanchang University, 330029, Nanchang, China

    H. Y. Xiao, W. B. Zhou, F. P. Zeng & D. S. Wu

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  1. H. Y. Xiao
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  2. W. B. Zhou
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  3. F. P. Zeng
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  4. D. S. Wu
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Correspondence to H. Y. Xiao.

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Xiao, H.Y., Zhou, W.B., Zeng, F.P. et al. Water chemistry and heavy metal distribution in an AMD highly contaminated river. Environ Earth Sci 59, 1023–1031 (2010). https://doi.org/10.1007/s12665-009-0094-5

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  • DOI: https://doi.org/10.1007/s12665-009-0094-5

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