Abstract
The concept of treating waste with waste is of great significance to realize the sustainable development of human society. In this work, the high metals-containing coal gasification fine slag (CGFS) from the coal gasification industry is directly transformed into an excellent adsorbent for malachite green wastewater adsorption. CGFS exhibits a rough and porous structure, which is mainly composed of SiO2 and various metal compounds. Numerous spherical structures which are generated by the melting of inorganic substances are distributed on the surface of CGFS with a large number of flocculent carbon structures covering the substrate or interspersed. Experiments confirm that CGFS is a competitive adsorbent for the removal of malachite green due to its low cost and high adsorption performance. The theoretical maximum adsorption capacity of CGFS at 298 K predicted by the Langmuir model reached as high as 1787 mg/g and the capacity increases with the temperature. The removal efficiency reached 100% for CGFS at a solid–liquid ratio of 0.05 g/100 mL and a malachite green concentration of 100 mg/L. A dominant role of chemisorption was confirmed by the analytical results of the pseudo-second-order model and the Freundlich model combined with the characterization results. The metal oxides and carbon structures in CGFS are presumed to be the main active adsorption sites. From the fitting of the intraparticle diffusion model, the adsorption rate was limited first by membrane diffusion and then by intraparticle diffusion as the adsorption process proceeded.
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References
Fayazi, M., Afzali, D., Ghanei-Motlagh, R., et al.: Synthesis of novel sepiolite-iron oxide-manganese dioxide nanocomposite and application for lead(II) removal from aqueous solutions. Environ. Sci. Pollut. Res. 26, 18893–18903 (2019). https://doi.org/10.1007/s11356-019-05119-9
Fayazi, M., Taher, M.A., Afzali, D., et al.: Enhanced Fenton-like degradation of methylene blue by magnetically activated carbon/hydrogen peroxide with hydroxylamine as Fenton enhancer. J. Mol. Liq. 216, 781–787 (2016). https://doi.org/10.1016/j.molliq.2016.01.093
Gupta, V.K., Pathania, D., Agarwal, S., et al.: De-coloration of hazardous dye from water system using chemically modified Ficus carica adsorbent. J. Mol. Liq. 174, 86–94 (2012). https://doi.org/10.1016/j.molliq.2012.07.017
Pei, Y., Wang, M., Tian, D., et al.: Synthesis of core-shell SiO2@MgO with flower like morphology for removal of crystal violet in water. J. Colloid Interface Sci. 453, 194–201 (2015). https://doi.org/10.1016/j.jcis.2015.05.003
Asfaram, A., Ghaedi, M., Ghezelbash, G.R., et al.: Application of experimental design and derivative spectrophotometry methods in optimization and analysis of biosorption of binary mixtures of basic dyes from aqueous solutions. Ecotoxicol. Environ. Saf. 139, 219–227 (2017). https://doi.org/10.1016/j.ecoenv.2017.01.043
Zhang, J., Li, Y., Zhang, C., et al.: Adsorption of malachite green from aqueous solution onto carbon prepared from Arundo donax root. J. Hazard. Mater. 150, 774–782 (2008). https://doi.org/10.1016/j.jhazmat.2007.05.036
Srivastava, S., Sinha, R., Roy, D.: Toxicological effects of malachite green. Aquat. Toxicol. 66, 319–329 (2004). https://doi.org/10.1016/j.aquatox.2003.09.008
Rao, K.V.: Inhibition of DNA synthesis in primary rat hepatocyte cultures by malachite green: a new liver tumor promoter. Toxicol. Lett. 81, 107–113 (1995). https://doi.org/10.1016/0378-4274(95)03413-7
Dil, E.A., Ghaedi, M., Asfaram, A., et al.: Preparation of nanomaterials for the ultrasound-enhanced removal of Pb2+ ions and malachite green dye: chemometric optimization and modeling. Ultrason. Sonochem. 34, 677–691 (2017). https://doi.org/10.1016/j.ultsonch.2016.07.001
Tan, K.B., Vakili, M., Hord, B.A., et al.: Adsorption of dyes by nanomaterials: recent developments and adsorption mechanisms. Sep. Purif. Technol. 150, 229–242 (2015). https://doi.org/10.1016/j.seppur.2015.07.009
Zheng, H., Qi, J., Jiang, R., et al.: Adsorption of malachite green by magnetic litchi pericarps: a response surface methodology investigation. J. Environ. Manage. 162, 232–239 (2015). https://doi.org/10.1016/j.jenvman.2015.07.057
Islam, A., Teo, S.H., Taufiq-Yap, Y.H., et al.: Step towards the sustainable toxic dyes removal and recycling from aqueous solution—a comprehensive review. Resour. Conserv. Recycl. (2021). https://doi.org/10.1016/j.resconrec.2021.105849
Bin Yeamin, M., Islam, M.M., Chowdhury, A.-N., et al.: Efficient encapsulation of toxic dyes from wastewater using several biodegradable natural polymers and their composites. J. Clean. Prod. (2021). https://doi.org/10.1016/j.jclepro.2021.125920
Awual, M.R.: A novel facial composite adsorbent for enhanced copper(II) detection and removal from wastewater. Chem. Eng. J. 266, 368–375 (2015). https://doi.org/10.1016/j.cej.2014.12.094
Awual, M.R.: Novel ligand functionalized composite material for efficient copper(II) capturing from wastewater sample. Compos. Part B 172, 387–396 (2019). https://doi.org/10.1016/j.compositesb.2019.05.103
Awual, M.R.: Mesoporous composite material for efficient lead(II) detection and removal from aqueous media. J. Environ. Chem. Eng. (2019). https://doi.org/10.1016/j.jece.2019.103124
Hasan, M., Shenashen, M.A., Hasan, M.N., et al.: Natural biodegradable polymeric bioadsorbents for efficient cationic dye encapsulation from wastewater. J. Mol. Liq. (2021). https://doi.org/10.1016/j.molliq.2020.114587
Hasana, M.M., Hasan, M.N., Awual, M.R., et al.: Biodegradable natural carbohydrate polymeric sustainable adsorbents for efficient toxic dye removal from wastewater. J. Mol. Liq. (2020). https://doi.org/10.1016/j.molliq.2020.114356
Kubra, K.T., Salman, M.S., Hasan, M.N., et al.: Utilizing an alternative composite material for effective copper(II) ion capturing from wastewater. J. Mol. Liq. (2021). https://doi.org/10.1016/j.molliq.2021.116325
Sheikh, T.A., Rahman, M.M., Asiri, A.M., et al.: 4-Hexylresorcinol sensor development based on wet-chemically prepared Co3O4@Er2O3 nanorods: a practical approach. J. Ind. Eng. Chem. 66, 446–455 (2018). https://doi.org/10.1016/j.jiec.2018.06.012
Znad, H., Abbas, K., Hena, S., et al.: Synthesis a novel multilamellar mesoporous TiO2/ZSM-5 for photo-catalytic degradation of methyl orange dye in aqueous media. J. Environ. Chem. Eng. 6, 218–227 (2018). https://doi.org/10.1016/j.jece.2017.11.077
Wu, S., Huang, S., Wu, Y., et al.: Characteristics and catalytic actions of inorganic constituents from entrained-flow coal gasification slag. J. Energy Inst. 88, 93–103 (2015). https://doi.org/10.1016/j.joei.2014.04.001
Huo, S.-H., Yan, X.-P.: Metal-organic framework MIL-100(Fe) for the adsorption of malachite green from aqueous solution. J. Mater. Chem. 22, 7449–7455 (2012). https://doi.org/10.1039/c2jm16513a
Guo, F., Jiang, X., Li, X., et al.: Synthesis of MgO/Fe3O4 nanoparticles embedded activated carbon from biomass for high-efficient adsorption of malachite green. Mater. Chem. Phys. (2020). https://doi.org/10.1016/j.matchemphys.2019.122240
Kulaksiz, E., Gozmen, B., Kayan, B., et al.: Adsorption of malachite green on Fe-modified biochar: influencing factors and process optimization. Desalin. Water Treat. 74, 383–394 (2017). https://doi.org/10.5004/dwt.2017.20601
Zhang, Y., Wang, R., Qiu, G., et al.: Synthesis of porous material from coal gasification fine slag residual carbon and its application in removal of methylene blue. Molecules (2021). https://doi.org/10.3390/molecules26206116
Tang, R., Hong, W., Srinivasakannan, C., et al.: A novel mesoporous Fe-silica aerogel composite with phenomenal adsorption capacity for malachite green. Sep. Purif. Technol. (2022). https://doi.org/10.1016/j.seppur.2021.119950
Chowdhury, M.F., Khandaker, S., Sarker, F., et al.: Current treatment technologies and mechanisms for removal of indigo carmine dyes from wastewater: a review. J. Mol. Liq. (2020). https://doi.org/10.1016/j.molliq.2020.114061
Zhao, X., Zeng, C., Mao, Y., et al.: The surface characteristics and reactivity of residual carbon in coal gasification slag. Energy Fuels 24, 91–94 (2010). https://doi.org/10.1021/ef9005065
Kim, K.J., Jang, J.S., Lee, J.-H., et al.: Determination of the absolute thickness of ultrathin Al2O3 overlayers on Si (100) substrate. Anal. Chem. 81, 8519–8522 (2009). https://doi.org/10.1021/ac901463m
Qian, B., Wang, Y., Zhao, Q., et al.: Preparation and luminescence properties of Eu3+incorporated in CaCO3 nanocrystals with multiple sites. J. Lumin. (2021). https://doi.org/10.1016/j.jlumin.2021.118344
Yamashita, T., Hayes, P.: Analysis of XPS spectra of Fe2+ and Fe3+ ions in oxide materials. Appl. Surf. Sci. 254, 2441–2449 (2008). https://doi.org/10.1016/j.apsusc.2007.09.063
Islam, A., Teo, S.H., Awual, M.R., et al.: Assessment of clean H-2 energy production from water using novel silicon photocatalyst. J. Clean. Prod. (2020). https://doi.org/10.1016/j.jclepro.2019.118805
Islam, M.A., Angove, M.J., Morton, D.W., et al.: A mechanistic approach of chromium (VI) adsorption onto manganese oxides and boehmite. J. Environ. Chem. Eng. (2020). https://doi.org/10.1016/j.jece.2019.103515
Kabir, M.M., Akter, M.M., Khandaker, S., et al.: Highly effective agro-waste based functional green adsorbents for toxic chromium(VI) ion removal from wastewater. J. Mol. Liq. (2022). https://doi.org/10.1016/j.molliq.2021.118327
Rahman, M.M., Sheikh, T.A., Asiri, A.M., et al.: Development of 3-methoxyaniline sensor probe based on thin Ag2O@La2O3 nanosheets for environmental safety. New J. Chem. 43, 4620–4632 (2019). https://doi.org/10.1039/c9nj00415g
Zhang, X., Gao, J., Zhao, S., et al.: Hexavalent chromium removal from aqueous solution by adsorption on modified zeolites coated with Mg-layered double hydroxides. Environ. Sci. Pollut. Res. 26, 32928–32941 (2019). https://doi.org/10.1007/s11356-019-06410-5
Lu, S., Liu, Q., Han, R., et al.: Core-shell structured Y zeolite/hydrophobic organic polymer with improved toluene adsorption capacity under dry and wet conditions. Chem. Eng. J. (2021). https://doi.org/10.1016/j.cej.2020.128194
Teo, S.H., Ng, C.H., Islam, A., et al.: Sustainable toxic dyes removal with advanced materials for clean water production: a comprehensive review. J. Clean. Prod. (2022). https://doi.org/10.1016/j.jclepro.2021.130039
Altintig, E., Onaran, M., Sari, A., et al.: Preparation, characterization and evaluation of bio-based magnetic activated carbon for effective adsorption of malachite green from aqueous solution. Mater. Chem. Phys. 220, 313–321 (2018). https://doi.org/10.1016/j.matchemphys.2018.05.077
Li, X., Zhang, Y., Jing, L., et al.: Novel N-doped CNTs stabilized Cu2O nanoparticles as adsorbent for enhancing removal of malachite green and tetrabromobisphenol A. Chem. Eng. J. 292, 326–339 (2016). https://doi.org/10.1016/j.cej.2016.02.043
Wang, D., Liu, L., Jiang, X., et al.: Adsorption and removal of malachite green from aqueous solution using magnetic beta-cyclodextrin-graphene oxide nanocomposites as adsorbents. Colloids and Surf. A 466, 166–173 (2015). https://doi.org/10.1016/j.colsurfa.2014.11.021
Kan, Y., Yue, Q., Kong, J., et al.: The application of activated carbon produced from waste printed circuit boards (PCBs) by H3PO4 and steam activation for the removal of malachite green. Chem. Eng. J. 260, 541–549 (2015). https://doi.org/10.1016/j.cej.2014.09.047
Mittal, H., Parashar, V., Mishra, S.B., et al.: Fe3O4 MNPs and gum xanthan based hydrogels nanocomposites for the efficient capture of malachite green from aqueous solution. Chem. Eng. J. 255, 471–482 (2014). https://doi.org/10.1016/j.cej.2014.04.098
Znad, H., Awual, M.R., Martini, S.: The utilization of algae and seaweed biomass for bioremediation of heavy metal-contaminated wastewater. Molecules (2022). https://doi.org/10.3390/molecules27041275
Liu, S., Xu, W.-H., Liu, Y.-G., et al.: Facile synthesis of Cu(II) impregnated biochar with enhanced adsorption activity for the removal of doxycycline hydrochloride from water. Sci. Total Environ. 592, 546–553 (2017). https://doi.org/10.1016/j.scitotenv.2017.03.087
Mohamed, R.M., Shawky, A., Mkhalid, I.A.: Facile synthesis of MgO and Ni-MgO nanostructures with enhanced adsorption of methyl blue dye. J. Phys. Chem. Solids 101, 50–57 (2017). https://doi.org/10.1016/j.jpcs.2016.10.009
Lan, Y., Wang, H., Li, X., et al.: The absorption of kitchen waste mixed-base biochar on malachite green. Chem. Lett. 49, 20–23 (2020). https://doi.org/10.1246/cl.190711
Bastami, T.R., Entezari, M.H.: Activated carbon from carrot dross combined with magnetite nanoparticles for the efficient removal of p-nitrophenol from aqueous solution. Chem. Eng. J. 210, 510–519 (2012). https://doi.org/10.1016/j.cej.2012.08.011
Guo, F., Li, X., Jiang, X., et al.: Characteristics and toxic dye adsorption of magnetic activated carbon prepared from biomass waste by modified one-step synthesis. Colloids Surf. A 555, 43–54 (2018). https://doi.org/10.1016/j.colsurfa.2018.06.061
Funding
This work is supported by the project of the key research plan of Ningxia (2021BEE03011) and Foundation of State Key Laboratory of High-efficiency Utilization of Coal and Green Chemical Engineering (Grant No. 2022-K23).
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YD: Formal analysis, Data curation, Software, Investigation, Writing—original draft. FG: Methodology, Conceptualization, Resources, Writing—review & editing, Supervision. RS: Data curation, Software, Writing—review & editing. KD: Resources, Writing—review & editing. QQ: Writing—review & editing. SL: Writing—review & editing. LX: Writing—review & editing. YB: Writing—review & editing.
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Dong, Y., Guo, F., Shu, R. et al. Evaluation of the High Metals-Containing Coal Gasification Fine Slag as a High-Performance Adsorbent for Malachite Green Adsorption. Waste Biomass Valor 13, 4897–4909 (2022). https://doi.org/10.1007/s12649-022-01831-9
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DOI: https://doi.org/10.1007/s12649-022-01831-9