Abstract
Utilization of wastes from some biomass-based industries in production of nanomaterials is vital in the green chemistry field. This work deals with valorization of lignin from paper making by-product for synthesizing lignin nanoparticles (LNPs) and evaluating its role on performance of film made from liquid crystal hydroxypropyl cellulose (HPC), in comparison withdifferent carbon nanoallotropes. In this respect LNPs, graphene oxide and bagasse-based carbon quantum dots and carbon oxide were synthesized and incorporated with HPC during film formation. The effective behavior of LNPs, especially that produced from using highly polar solvent, on performance of HPC film was evidenced, from examiningpolarized light microscope together with TEM, SEM, XRD, FTIR, TGA as well as mechanical tests. The results showed that LNPs provided the HPC-nanocomposite film with acceptable thermal stability and mechanical properties, together with distinct complex mixed colorful texture, lines nearly like Grandjean-Cano lines aligned (PO images) and the planar layered morphology.
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Abdel-Hadi, A.K., Hosny, W.M., Basta, A.H., El-Saied, H.: Metal chelates with some cellulose derivatives. II. Preparation and characterization of Co(II)-CMC complexes. Polym. Plast. Technol. Eng. 33(6), 781–791 (1994)
Thakur, V.K., Thaku, M.K., Gupta, R.K.: Development of functionalized cellulosic biopolymers by graft copolymerization. Int. J. Biol. Macromol. 62, 44–51 (2013)
Basta, A.H., Khwaldia, K., Aloui, H., El-Saied, H.: Enhancing the performance of carboxymethyl cellulose by chitosan in producing barrier coated paper sheets. NPPRJ 30(4), 617–625 (2015)
Basta, A.H., El-Saied, H., Baraka, A.M.: Performance of carbon xerogels in the production of environmentally friendly urea formaldehyde-bagasse composites. Clean 45(6), e201600524 (2017)
Lotfy, V.F., Fathy, N.A., Basta, A.H.: Novel approach for synthesizing different shapes of carbon nanotubes from rice straw residue. J. Environ. Chem. Eng. 6, 6263–6274 (2018)
Basta, A.H., Lotfy, V.F., Hasanin, M.S., Trens, P., El-Saied, H.: Efficient treatment of rice byproducts for preparing high-performance activated carbons. J. Clean. Prod. 207, 284–295 (2019)
Hanna, D.H., Lotfy, V.F., Basta, A.H., Saad, G.R.: Comparative evaluation for controlling release of niacin from protein-and cellulose-chitosan based hydrogelsInt. J. Biol. Macromol. 150, 228–237 (2020)
Ates, B., Koytepe, S., Ulu, A., Gurses, C., Thakur, V.K.: Chemistry, structures, and advanced applications of nanocomposites from biorenewable resources. Chem. Rev. 120, 9304–9362 (2020)
Basta, A.H., Lotfy, V.F., Micky, J.A., Salem, A.M.: Liquid crystal behavior of cellulose nanoparticles-ethyl cellulose composites: preparation, characterization, and rheology. J. Appl. Polym. Sci. 138(12), 1–13 (2021)
Nair, S.S., Yan, N.: Effect of high residual lignin on the thermal stability of nanofibrils and its enhanced mechanical performance in aqueous environments. Cellulose 22, 3137–3150 (2015)
Tian, D., Hu, J., Bao, J., Chandra, R.P., Saddler, J.N., Lu, C.: Lignin valorization: lignin nanoparticles as high-value bio-additive for multifunctional nanocomposites. Biotechnol. Biofuels 10, 1–11 (2017)
Shimamoto, S., Uraki, Y., Sano, Y.: Optical properties and photopolymerization of liquid crystalline (acetyl) (ethyl) cellulose/acrylic acid system. Cellulose 7, 347–358 (2000)
Suto, S., Nishibori, W., Kudo, K., Karasawa, M.: Lyotropic liquid crystalline solutions of hydroxypropyl cellulose in water: effect of salts on the turbidity and viscometric behavior. J. Appl. Polym. Sci. 37, 737–749 (1989)
Boott, C.E., Tran, A., Hamad, W.Y., MacLachlan, M.J.: Cellulose nanocrystal elastomers with reversible visible color. Angew. Chem. Int. Ed. 59(1), 226–231 (2020)
Kim, D.Y., Jeong, K.U.: Light responsive liquid crystal soft matters: structures, properties, and applications. Liq. Cryst. Today 28(2), 34–45 (2019)
Li, L.-S., Walda, J., Manna, L., Alivisatos, A.P.: Semiconductor nanorod liquid crystals. Nano Lett. 2, 557–560 (2002)
Thorkelsson, K., Bai, P., Xu, T.: Self-assembly and applications of anisotropic nanomaterials: a review. Nano Today 10, 48–66 (2015)
Paulchamy, B., Arthi, G., Lignesh, B.D.: A simple approach to step wise synthesis of grapheme oxide nanomaterial. J. Nanomed. Nanotechnol. 6(1), 1000253 (2015)
Wojtoniszak, M., Mijowska, E.: Controlled oxidation of graphite to graphene oxide with novel oxidants in a bulk scale. J. Nanopart. Res. 14, 1248 (2012)
Liu, L., An, M., Xing, S., Shen, X., Yang, C., Xu, X.: Preparation of graphene oxide based on expanded graphite. Adv. Mater. Res. 881–883, 1083–1088 (2014)
Yin, P.T., Shah, S., Chhowalla, M., Lee, K.-B.: Design, synthesis, and characterization of graphene−nanoparticle hybrid materials for bioapplications. Chem. Rev. 115(7), 2483–2531 (2015)
Cruz-Silva, R., Endo, M., Terrones, M.: Graphene oxide films, fibers, and membranes. Nanotechnol. Rev. 5(4), 377–391 (2016)
Lin, F., Tong, X., Wang, Y., Bao, J., Wang, Z.M.: Graphene oxide liquid crystals: synthesis, phase transition, rheological property, and applications in optoelectronics and display. Nanoscale Res. Lett. 10, 1–16 (2015)
Arshadi Pirlar, M., Rezaei Mirghaed, M., Honarmand, Y., Movahed, S.M.S., Karimzadeh, R.: Light scattering through the graphene oxide liquid crystal in a micro-channel. Opt. Express 27(17), 23864–23874 (2019)
Kim, J.E., Han, T.H., Lee, S.H., Kim, J.Y., Ahn, C.W., Yun, J.M., Kim, S.O.: Graphene oxide liquid crystals. Angew. Chem. Int. Ed. 50, 3043–3047 (2011)
Baweja, H., Jeet, K.: Economical and green synthesis of graphene and carbon quantum dots from agricultural waste. Mater. Res. Express 6, 0850g8 (2019)
Kim, D., Cheon, J., Kim, J., Hwang, D., Hong, I., Kwon, O.H., Park, W.H., Cho, D.: Extraction and characterization of lignin from black liquor and preparation of biomass-based activated carbon there from. Carbon Lett. 22, 81–88 (2017)
Lievonen, M., Valle-Delgado, J.J., Mattinen, M.L., Hult, E.L., Lintinen, K., Kostiainen, M.A., Paananen, A., Szilvay, G.R., Setälä, H., Österberg, M.: A simple process for lignin nanoparticle preparation. Green Chem. 18, 1416–1422 (2015)
Thambiraj, S., RaviShankaran, D.: Green synthesis of highly fluorescent carbon quantum dots from sugarcane bagasse pulp. Appl. Surf. Sci. 390, 435–443 (2016)
Levdik, I., Inshakov, M.D., Misyurova, E.P., Nikitin, V.N.: Study of pulp structure by infrared spectroscopy. Vses. Nauch. Issled. Irst. Tsellyul. Bum. Prom. 52, 109–111 (1967)
Coat, A.W., Redfern, J.P.: Kinetic parameters from thermogravimetric data. Nature 201, 68–69 (1964)
Basta, A.H., El-Saied, H., Lotfy, V.F.: Performance assessment of deashed and dewaxed rice straw on improving the quality of RS-based composites. RSC Adv. 4(42), 21794–21801 (2014)
ISO 527–1:2012 (E) International Standard-Plastics-Determination of tensile properties. ISO 527–1.(2012)
Lievonen, M., Valle-Delgado, J.J., Mattinen, M.L., Hult, E.L., Lintinen, K., Kostiainen, M.A., Paananen, A., Szilvay, G.R., Setälä, H., Österberg, M.: A simple process for lignin nanoparticle preparation. Green Chem. 18(5), 1416–1422 (2016)
Aziz, M., Halim, F.S.A., Jaafar, J.: Preparation and characterization of graphene membrane electrode assembly. J. Teknol. 69(9), 11–14 (2014)
Thambiraj, S., Ravi Shankaran, D.: Green synthesis of highly fluorescent carbon quantum dots from sugarcane bagasse pulp. Appl. Surf. Sci. 390, 435–443 (2016)
Zheng, F., Wang, Z., Chen, J., Li, S.: Synthesis of carbon quantum dot-surface modified P25 nanocomposites for photocatalytic degradation of p-nitrophenol and acid violet 43. RSC Adv. 4(58), 30605–30609 (2014)
Somanathan, T., Prasad, K., Ostrikov, K., Saravanan, A., Krishna, V.M.: Graphene oxide synthesis from agro waste. Nanomater. 52, 826–834 (2015)
Hanifah, M.F.R., Jaafar, J., Aziz, M., Ismail, A.F., Rahman, M.A., Othman, M.H.: Synthesis of graphene oxide nanosheets via modified Hummers’ method and its physicochemical properties. J. Teknol. 74(1), 195–198 (2015)
Hu, J., Shen, D., Wu, S., Zhang, H., Xiao, R.: Effect of temperature on structure evolution in char from hydrothermal degradation of lignin. J. Anal. Appl. Pyrol. 106, 118–124 (2014)
Pirlar, M.A., Mirghaed, M.R., Honarmand, Y., Movahed, S.M.S., Karimzadeh, A.R.: Light scattering through the graphene oxide liquid crystal in a micro-channel. Opt. Express 27(17), 23864–23874 (2019)
Thommes, M., Kaneko, K., Neimark, A.V., Olivier, J.P., Rodriguez-Reinoso, F., Rouquerol, J., Sing, K.S.W.: Physisorption of gases, with special reference to the evaluation of surface area and pore size distribution (IUPAC technical report). Pure Appl. Chem. 87, 1051–1069 (2015)
Myint, A.A., Lee, H.W., Seo, B., Son, W.S., Yoon, J., Yoon, T.J., Park, H.J., Yu, J., Yoon, J., Lee, Y.W.: One pot synthesis of environmentally friendly lignin nanoparticles with compressed liquid carbon dioxide as an antisolvent. Green Chem. 18, 2129–2146 (2016)
Nair, V., Panigrahy, A., Vinu, R.: Development of novel chitosan-lignin composites for adsorption of dyes and metal ions from wastewater. Chem. Eng. J. 254, 491–502 (2014)
Klapiszewski, Ł, Wysokowski, M., Majchrzak, I., Szatkowski, T., Nowacka, M., Siwińska-Stefańska, K., Szwarc-Rzepka, K., Bartczak, P., Ehrlich, H., Jesionowski, T.: Preparation and characterization of multifunctional chitin/lignin materials. J. Nanomater. 2013, 425726 (2013)
Azimvand, J., Didehban, K., Mirshokrai, S.A.: Preparation and characterization of lignin polymeric nanoparticles using the green solvent ethylene glycol: acid precipitation technology. BioResources 13(2), 2887–2889 (2018)
Echeverria, C., Almeida, P.L., Feio, G., Figueirinhas, J.L., Godinho, M.H.: A cellulosic liquid crystal pool for cellulose nanocrystals: structure and molecular dynamics at high shear rates. Eur. Polym. J. 72, 72–81 (2015)
Segal, L., Creely, J.J., Martin, A.E., Conrad, C.M.: An empirical method for estimating the degree of crystallinity of native cellulose using the X-ray diffractometer. Text. Res. J. 29(10), 786–794 (1959)
Abdul Khalil, H.P.S., Marliana, M.M., Alshammari, T.: Material properties of epoxy-reinforced biocomposites with lignin from empty fruit bunch as cuting agent. BioResources 6(4), 5206–5223 (2011)
Pokharel, P., Lee, D.S.: Thermal and mechanical properties of reduced graphene oxide/polyurethane nanocomposite. J. Nanosci. Nanotechnol. 14, 5718–5721 (2014)
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The authors present many thanks to the National Research Centre for supporting this work, by facilities, as article delivered from MS. Thesis
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Basta, A.H., Lotfy, V.F. & Salem, A.M. Valorization of Biomass Pulping Waste as Effective Additive for Enhancing the Performance of Films Based on Liquid Crystal Hydroxypropyl-Cellulose Nanocomposites. Waste Biomass Valor 13, 2217–2231 (2022). https://doi.org/10.1007/s12649-021-01631-7
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DOI: https://doi.org/10.1007/s12649-021-01631-7