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Extraction and Characterization of γ-Alumina from Waste Aluminium Dross

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Abstract

Aluminium (Al) dross, a chemical waste from an aluminium production factory in Malaysia, was used in this study for the recovery of aluminium in the form of γ-Al2O3. The different methods, such as acid leaching, alkaline precipitation at different pH and calcination steps were successfully applied to extract the γ-Al2O3 from Al dross. The products were characterized by X-ray diffraction, atomic absorption spectroscopy, X-ray fluorescence, thermogravimetric analysis, Brunauer–Emmett–Teller surface area analysis, particle size distribution and field emission scanning electron microscope. The results revealed that the γ-Al2O3 powders recovered from the Al dross has crystallite size around 5 nm, specific surface area between 111 and 128 m2/gwith different pore sizes. Thus, the present study illustrates an adequate utilization of the Al dross, which is, to date, neither adequately utilized nor properly dispensed in most of the developing countries.

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References

  1. Nemerow, N.L.: Industrial Waste Treatment: contemporary practice and vision for the future, pp. 13–24. Butterworth, Heinemann Press (2010a)

  2. Nemerow, N.L.: Industrial Waste Treatment: contemporary practice and vision for the future, pp. 1–8. Butterworth, Heinemann Press (2010b)

  3. Mukhopadhyay, J., Ramana, Y.V., Singh, U.: Extraction of value added products from aluminium dross material to achieve zero waste. J. Light Met. 120, 1209–1212 (2004)

    Google Scholar 

  4. Manfrendi, O., Wuth, W., Bohlinger, I.: Characterizing the physical and chemical properties of aluminum dross. J. Mater. Res. Summary 149, 48–51 (1997)

    Google Scholar 

  5. Asencios, Y.J.O., Sun-Kuo, M.R.: Synthesis of high-surface-area γ-Al2O3 from aluminum scrap and its use for the adsorption of metals: Pb(II), Cd(II) and Zn(II). Appl. Surf. Sci. 258, 10002–10011 (2012)

    Article  Google Scholar 

  6. Meor, Y.M.S., Masliana, M., Wilfred, P.: A waste to wealth study on converting aluminium dross schedule waste into γ and α alumina. Recent Adv. Environ. Ecosyst. Dev. 7, 17–21 (2009)

    Google Scholar 

  7. Tenorio, J.A.S., Espinosa, D.C.R.: Effect of salt/oxide interaction on the process of aluminum recycling. J. Light Met. 2(2), 89–93 (2002)

    Article  Google Scholar 

  8. Amer, A.M.: Extracting aluminum from dross tailings. Jom 54(11), 72–75 (2002)

    Article  Google Scholar 

  9. Kemeny, F.L., Sosinsky, D.J., Schmitt, R.J.: Development of a DC plasma-arc furnace for processing aluminum dross. In The 121st TMS annual meeting, pp. 1147-1153, San Diego, CA, USA (1991)

  10. Osborne, W.B.: In Queneau, P.B., Peterson R. (Eds.) Proceedings of 3rd international symposium on recycling of metals and engineered materials, The Minerals, Metals and Materials Society, TMS, pp. 947–954 (1995)

  11. Dube, G., Huni, J.-P., Lavoie, S., Stevens, W.D.: Recovery of non-ferrous metals from dross, US patent 4,959, 100 (1990)

  12. Boulos, M.I.: New frontiers in thermal plasma processing. Pure Appl. Chem. 68(5), 1007–1010 (1996)

    Article  Google Scholar 

  13. Ünlü, N., Drouet, M.G.: Comparison of salt-free aluminum dross treatment processes. Resour. Conserv. Recycl. 36(1), 61–72 (2002)

    Article  Google Scholar 

  14. Brisson, C., Chauvette, G., Kimmerle, F.M., Roussel, R.: Process for using dross residues to produce refractory products, US patent 5,132 246 (1992)

  15. Amer, A.M.: Extracting aluminum from dross tailings. J. Met. 54, 72–75 (2002)

    Google Scholar 

  16. Huckabay, D.A., Skiathas, D.A.: Aluminium sulfate manufacture from aluminum dross tailings. US Patent No. 4,320 (1982)

  17. Garret, L.W.: Process for the production of sulfates. US Patent No. 4,337 (1982)

  18. Dash, B., Das, B.R., Tripathy, B.C., Bhattacharya, I.N., Das, S.C.: Acid dissolution of alumina from waste aluminium dross. Hydrometallurgy 92(1), 48–53 (2008)

    Article  Google Scholar 

  19. Das, B.R., Dash, B., Tripathy, B.C., Bhattacharya, I.N., Das, S.C.: Production of η-alumina from waste aluminium dross. Miner. Eng. 20, 252–258 (2007)

    Article  Google Scholar 

  20. Bruckard, W.J., Woodcock, J.T.: Characterisation and treatment of Australian salt cakes by aqueous leaching. Miner. Eng. 20, 1376–1390 (2007)

    Article  Google Scholar 

  21. Bruckard, W.J., Woodcock, J.T.: Recovery of valuable materials from aluminium salt cakes. Int. J. Miner. Process. 93, 1–5 (2009)

    Article  Google Scholar 

  22. Alexander, L., Klug, H.P.: Determination of Crystallite Size with the X-Ray Spectrometer. J. Appl. Phys. 21(2), 137–142 (1950)

    Article  Google Scholar 

  23. Hellgardt, K., Chadwick, D.: On the preparation of high surface area aluminas from nitrate solutions. Ind. Eng. Chem. Res. 37, 405–411 (1998)

    Article  Google Scholar 

  24. Ono, T., Ohguchi, Y.,Togari, O.: Control of the pore structure of porous alumina. Stud. Surf. Sci. Catal. 16, 631–641 (1983)

    Article  Google Scholar 

  25. Rahmani, A., Mousavi, H.Z., Fazli, M.: Effect of nanostructure alumina on adsorption of heavy metals. Desalination 253, 94–100 (2010)

    Article  Google Scholar 

Download references

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Correspondence to Aminul Islam or Yun Hin Taufiq-Yap.

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How, L.F., Islam, A., Jaafar, M.S. et al. Extraction and Characterization of γ-Alumina from Waste Aluminium Dross. Waste Biomass Valor 8, 321–327 (2017). https://doi.org/10.1007/s12649-016-9591-4

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  • DOI: https://doi.org/10.1007/s12649-016-9591-4

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