Pilot-Scale Synthesis of Activated Carbons from Vetiver Roots and Sugar Cane Bagasse

Abstract

The main objective of this study was to produce, under pilot conditions, activated carbons (AC) from two different Caribbean by-products, specifically, sugarcane bagasse and vetiver roots. The produced activated carbons under both physical and chemical activation processes were characterised with respect to their texture and surface chemistry. The textural and chemical analyses showed that the nature of the precursor played a crucial role in determining the main characteristics of the activated carbon that was produced. Indeed, under the pilot production chemical activation conditions, bagasse-derived AC (“Bag-pilot”) showed the highest specific surface area (i.e. Brunauer, Emmett and Teller surface, SBET) with 1,030 m2/g compared to 555 m2/g for vetiver-derived AC (“Vet-pilot”). Porous texture analysis revealed that “Bag-pilot” developed more volume (0.807 cm3/g) than “Vet-pilot” (0.352 cm3/g), whereas “Vet-pilot” displayed more micropores (27 %). As for the surface chemistry, results showed that “Bag-pilot” contain more acidic and basic groups than “Vet-pilot” which makes it more interesting for adsorption purposes. The cost estimate of producing AC from vetiver roots in Haiti revealed that the chemically activated carbon presented the lowest cost at $1.17 per kg compared with 1.46$ per kg for physically activated carbon.

This is a preview of subscription content, access via your institution.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6

References

  1. 1.

    Altenor, S.: Physicochemical studies of algae and activated carbons derived from the Caribbean and their applicability for water treatment. PhD Thesis, University of Antilles and Guyane (2008)

  2. 2.

    Lavania, U.C.: Central Institute of Medicinal and Aromatic Plants, Lucknow, other uses, and utilization of vetiver: vetiver oil. http://www.vetiver.com/ICV3-Proceedings/IND_vetoil.pdf Accessed September 2012

  3. 3.

    Caribbean Office of Trade Negotiations: CARICOM’s essential oils trade, private sector trade note, vol. 9. http://www.crnm.org Accessed September 2012 (2009)

  4. 4.

    Valix, M., Cheung, W.H., McKay, G.: Preparation of activated carbon using low temperature carbonisation and physical activation of high ash raw bagasse for acid dye adsorption. Chemosphere 56, 493–501 (2004)

    Article  Google Scholar 

  5. 5.

    Jung, M.W., Ahn, K.H., Lee, Y., Kim, K.P., Rhee, J.S., Park, J.T., Paeng, K.J.: Adsorption characteristics of phenol and chlorophenols on granular activated carbons (GAC). Microchem. J. 70, 123–131 (2001)

    Article  Google Scholar 

  6. 6.

    Juang, R.S., Wu, F.C., Tseng, R.L.: Characterization and use of activated carbons prepared from bagasses for liquid-phase adsorption. Colloid. Surf. A Physicochem. Eng. Aspects 201, 191–199 (2002)

    Article  Google Scholar 

  7. 7.

    Tsai, W.T., Chang, C.Y., Lin, M.C., Chien, S.F., Sun, H.F., Hsieh, M.F.: Adsorption of acid dye onto activated carbons prepared from agricultural waste bagasse by ZnCl2 activation. Chemosphere 45, 51–58 (2001)

    Article  Google Scholar 

  8. 8.

    Ahmedna, M., Marshall, W.E., Rao, R.M.: Production of granular activated carbons from select agricultural byproducts and evaluation of their physical, chemical, and adsorption properties. Bioresour. Technol. 71, 113–123 (2000)

    Article  Google Scholar 

  9. 9.

    Cronje, K.J., Chetty, K., Carsky, M., Sahu, J.N., Meikap, B.C.: Optimization of chromium(VI) sorption potential using developed activated carbon from sugarcane bagasse with chemical activation by zinc chloride. Desalination 275, 276–284 (2011)

    Article  Google Scholar 

  10. 10.

    Altenor, S., Carene, B., Emmanuel, E., Lambert, J., Ehrhardt, J.J., Gaspard, S.: Adsorption studies of methylene blue and phenol onto vetiver roots activated carbon prepared by chemical activation. J. Hazard. Mater. 165, 1029–1039 (2009)

    Article  Google Scholar 

  11. 11.

    Arami-Niya, A., Daud, W.M., Mjalli, F.S.: Comparative study of the textural characteristics of oil palm shell activated carbon produced by chemical and physical activation for methane adsorption. Chem. Eng. Res. Design 89, 657–664 (2011)

    Article  Google Scholar 

  12. 12.

    Barret, E.P., Joyner, P.B., Halenda, P.: The determination of pore volume and area distributions in porous substances. I. Computations from nitrogen isotherms. J. Amer. Chem. Soc. 73, 373–380 (1951)

    Article  Google Scholar 

  13. 13.

    Diaz-Diez, M.A., Gomez-Serrano, V., Fernandez-Gonzalez, C., Cuerda-Correa, E.M., Marcias-Garcia, A.: Porous texture of activated carbons prepared by phosphoric acid activation of woods. Appl. Surf. Sci. 238, 309–313 (2004)

    Article  Google Scholar 

  14. 14.

    Ng, C., Marshall, W.E., Rao, R.M., Bansode, R.R., Losso, J.N.: Activated carbon from pecan shell: process description and economic analysis. Ind. Crops Prod. 17, 209–217 (2003)

    Article  Google Scholar 

  15. 15.

    Lima, I.M., McAloon, A., Boateng, A.A.: Activated carbon from broiler litter: process description and cost of production. Biomass Bioenergy 32, 568–572 (2008)

    Article  Google Scholar 

  16. 16.

    Molina-Sabio, M., Rodriguez-Reinoso, F., Caturla, F., Selles, M.J.: Porosity in granular carbons activated with phosphoric acid. Carbon 33, 1105–1113 (1995)

    Article  Google Scholar 

  17. 17.

    Gratuito, M.K., Panyathanmaporn, T., Chumnanklang, R.A., Sirinuntawittaya, N., Dutta, A.: Production of activated carbon fromcoconut shell: optimization using response surface methodology. Bioresour. Technol. 99, 4887–4895 (2007)

    Article  Google Scholar 

  18. 18.

    Ncibi, M.C., Altenor, S., Seffen, M., Brouers, F., Gaspard, S.: Modelling single compound adsorption onto porous and non-porous sorbents using a deformed Weibull exponential isotherm. Chem. Eng. J. 145, 196–202 (2008)

    Article  Google Scholar 

  19. 19.

    Gupta, V.K., Gupta, B., Rastogi, A., Agarwal, S., Nayak, A.: Pesticides removal from waste water by activated carbon prepared from waste rubber tire. Water Res. 45, 4047–4055 (2011)

    Article  Google Scholar 

  20. 20.

    Brouers, F., Sotolongo, O., Marquez, F., Pirard, J.P.: Microporous and heterogeneous surface adsorption isotherms arising from Levy distributions. Phys. A 349, 271–282 (2005)

    Article  Google Scholar 

  21. 21.

    Dabrowski, A., Podkosicielny, P., Hubicki, Z., Barczak, M.: Adsorption of phenolic compounds by activated carbon: a critical review. Chemosphere 58, 1049–1070 (2005)

    Article  Google Scholar 

  22. 22.

    Radovic, L.R., Moreno-Castilla, C., Rivera-Utrilla, J.: Carbons materials as adsorbents in aqueous solutions. In: Radovic, L.R. (ed.) Chemistry and physics of carbon. A series of advances, pp. 267–269. Marcel Dekker, New York (2000)

  23. 23.

    Gaspard, S., Altenor, S., Dawson, E.A., Barnes, P.A., Ouensanga, A.: Activated carbon from vetiver roots: gas and liquid adsorption studies. J. Hazard. Mater. 144, 73–81 (2007)

    Article  Google Scholar 

  24. 24.

    Toles, C.A., Marshall, W.E., Johns, M.M., Wartelle, L.H., McAloon, A.: Acid-activated carbons from almond shells: physical, chemical and adsorptive properties and estimated cost of production. Bioresour. Technol. 71, 87–92 (2000)

    Article  Google Scholar 

  25. 25.

    Toles, C.A., Marshall, W.E., Johns, M.M., Wartelle, L.H., McAloon, A.: Steam- or carbon dioxide-activated carbons from almond shells: physical, chemical and adsorptive properties and estimated cost of production. Bioresour. Technol. 75, 197–203 (2000)

    Article  Google Scholar 

  26. 26.

    National statistics office, Dominican Republic, French embassy in Santo Domingo (2008)

Download references

Author information

Affiliations

Authors

Corresponding author

Correspondence to M. C. Ncibi.

Rights and permissions

Reprints and Permissions

About this article

Cite this article

Altenor, S., Ncibi, M.C., Brehm, N. et al. Pilot-Scale Synthesis of Activated Carbons from Vetiver Roots and Sugar Cane Bagasse. Waste Biomass Valor 4, 485–495 (2013). https://doi.org/10.1007/s12649-012-9180-0

Download citation

Keywords

  • Activated carbon
  • Vetiver
  • Bagasse
  • Pilot scale production
  • Process flow diagram
  • Cost estimate