Abstract
The growth of optically good quality bulk size single crystal of pure and additives added 4-N, N-dimethylamino-4-N-methyl stilbazolium tosylate (DAST) crystal is reported by adopting the conventional slow evaporation solution technique. The grown single crystals were identified by single crystal and power X-ray Diffraction analysis. The luminescence study revealed the transition mechanism of ions. By estimating the hardness, Mayer index, yield strength, elastic stiffness constant, fracture toughness, and brittle index for the grown DAST single crystal using the Vickers micro-hardness analyzer, it is revealed that the grown crystal is a soft material. Using a continuous wave Nd-YAG laser and the standard Z-scan technique, the third-order nonlinearity of the pure and doped DAST single crystal was carefully examined. The third-order nonlinear optical properties show significantly higher values of the nonlinear absorption coefficient (β) and third-order nonlinear susceptibility (χ3). The calculated χ3 of grown pure, EDTA, and DTPA doped DAST crystals are 9.41 × 10−6, 8.06 × 10−6 and 7.92 × 10−6, respectively. The enhanced third-order nonlinear behavior suggests that the title compound is suitable for nonlinear optical applications.
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References
K Jagannathan, P Umarani, V Ratchagar, V Ramesh and S Kalainathan Spectrochim. Acta, Part A 153 735 (2016)
G Viju, L Mariappan, M Jose and S Jerome Das Optik 125 5926 (2014)
S N Vijayan, M Vij, K Thukral, N Khan, D Haranath, Rajnikant and M.S. Jayalakshmy Chin. J. Chem. Eng. 27, 701 (2019)
H Zhang, Y Sun, X Chen and X Yan J. Cryst. Growth 324 196 (2011)
S J Zhuang, B Teng, L Cao, D G Zhong, K Feng, Y X Shi, Y N Li, Q J Guo and M S Yang Adv. Mater. Res. 709 36 (2013)
S R Marder, J W Perry and W P Schaefer J. Mater. Chem. 9 985 (1992)
K S Rao, A K Chaudhary, M Venkatesh, K Thirupugalmani and S Brahadeeswaran Curr. Appl. Phys. 16 777 (2016)
X Xu, Z Sun, K Fan, Y Jiang, R Huang, Y Wen, Q He and T Ao Sci. Rep. 5 12269 (2015)
A S Haja Hameed, S Rohani, W C Yu, C Y Tai and C W Lan Mater. Chem. Phys. 102 60 (2007)
B Liu, Y Yang, Y Zhang, X Lv, L Wei and X Wang J. Mater. Sci. Mater. Electron. 26 8097 (2015)
M Manivannan, S A Martin Britto Dhas, M Balakrishnan and M Jose Appl. Phys. B 124 166 (2018)
F Pan, M S Wong, C Bosshard and P Gunter Adv. Mater. 8 592 (1996)
M Manivannan, S A Martin Britto Dhas and M Jose J. Cryst. Growth 455 161 (2016)
E Marin Eur J. Phys. 28 429 (2007)
W J Parker, R J Jenkins, C P Butler and G L Abbott J. Appl. Phys. 32 1679 (1961)
S R Marder, J W Perry and C P Yakymyshy Chem. Mater. 6 1137 (1994)
W L Barros Melo and R M Faria Appl. Phys. Lett. 67 3892 (1995)
P Karuppasamy, V Sivasubramani, M Senthil Pandian and P Ramasamy, RSC Adv. 6 109105 (2016)
M Senthil Pandian and P Ramasamy J. Cryst. Growth 312 413 (2010)
S Suresh, A Ramanand and D Jayaraman Optoelectron. Adv. Mater. Rapid Commun. 4 1987 (2010)
R Surekha, R Gunaseelan, P Sagayaraj and K Ambujam Cryst. Eng. Comm. 16 7979 (2014)
M Manivannan and A Saranraj Indian J. Phys. (2022). https://doi.org/10.1007/s12648-022-02527-5
A Saranraj, J Thirupathi, S Sathya Jude Dhas, M Jose, G Vinitha and S A Martin Britto Dhas Appl. Phy. B 124 97 (2018)
P B Chapple, J Staromlynska, J A Hermann and R G McDuff J. Nonlinear Opt. Phys Mat. 6 251 (1997)
P Karuppasamy, M S Pandian, P Ramasamy and S Verma Opt. Mater. 79 152 (2018)
S P Ramteke, M I Baig, Mohd Shkir, S Kalainathan, M D Shirsat, G G Muley and Mohd Anis Opt. Laser Technol. 104 83 (2018)
S Karthigha and C Krishnamoorthi J Phys Chem Solids 114 133 (2018)
X-L Zhang and X Zhao J. Opt. 13 075202 (2011)
An Fatemi Sci. Rep. 12 12893 (2022)
K Thirupugalmani, S Karthick, G Shanmugam, V Kannan, B Sridhar, K Nehru and S Brahadeeswaran Opt. Mater. 49 158 (2015)
J George, V Sasikala, L K Joy, D Sajan, T Arumanayagam, P Murugakoothan and G Vinitha Opt. Mater. 89 48 (2019)
A T Ravichandran, R Rathika and M Kumaresavanji J. Mol. Struct. 1224 129048 (2021)
Acknowledgements
The authors would like to thank the DAE-BRNS for their support by providing funds for the completion of this work (Sanction Number: 34/14/54/2014-BRNS). For the linguistic correction, the authors thank Mr. Jesu Arokiyaraj, Manager, Winner Institute of Commutative English (WICE).
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Manivannan, M., Saranraj, A., Jose, M. et al. Investigation of pure, EDTA and DTPA-doped DAST single crystal for optoelectronic applications. Indian J Phys (2024). https://doi.org/10.1007/s12648-024-03138-y
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DOI: https://doi.org/10.1007/s12648-024-03138-y