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Dielectric study of Ti-doped Bi2VO5.5 solid electrolyte

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Abstract

Synthesis and characterization of Bi2V1−xTixO5.5−(x/2)−δ (0 ≤ x ≤ 0.150) was done. For the present system, the lower limit of Ti required for near-complete tetragonal phase stabilization has been found to be x = 0.125. The optimum values of ionic conductivity were obtained for the compositions; Bi2V0.875Ti0.125O5.4375 and Bi2V0.9Ti0.1O5.45 at 300 °C and 600 °C, respectively. Interestingly, two peaks have been observed in frequency versus dielectric loss spectra for parent compound, which is in \(\alpha\)-orthorhombic phase, as well as for tetragonal phase stabilized specimens with compositions x ≥ 0.125 at temperatures below 300 °C. No such peaks have been found in \(\beta\)-orthorhombic (x = 0.085) as well as in mixed tetragonal and orthorhombic (x = 0.1 and 0.1125) phases. Thus, we propose that frequency-dependent dielectric loss spectra can be used to qualitatively distinguish \(\alpha\) and \(\gamma\)-phases from \(\beta\)-phase in BITIVOX system and it is the central result of this work.

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Acknowledgements

The authors are grateful to DST, New Delhi, for providing the FIST facility (Sanction Order Number SB/52/CMP-093/2013) in the Physics department for XRD and impedance studies. One of the authors (AJS) gratefully acknowledges DST, New Delhi, for INSPIRE fellowship.

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Authors and Affiliations

  1. Department of Physics, North Eastern Regional Institute of Science and Technology, Nirjuli, Arunachal Pradesh, 791109, India

    Diptimayee Tripathy, Amarjyoti Saikia, Gyati Tachang Tado & Arvind Pandey

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  1. Diptimayee Tripathy
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  2. Amarjyoti Saikia
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  3. Gyati Tachang Tado
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  4. Arvind Pandey
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Correspondence to Arvind Pandey.

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Tripathy, D., Saikia, A., Tado, G.T. et al. Dielectric study of Ti-doped Bi2VO5.5 solid electrolyte. Indian J Phys 93, 845–859 (2019). https://doi.org/10.1007/s12648-018-1356-4

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  • DOI: https://doi.org/10.1007/s12648-018-1356-4

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