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A study of vibrational spectra of metallotetraphenyl porphryins: an algebraic approach

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Abstract

Using Lie algebraic method, we report a study of the vibrational frequencies of various metallotetraphenyl porphyrins and its cation radicals, i.e. Cu[TPP], Cu[TPP]+, Ni(TPP), Ni(TPP)+, ClFe(TPP) and ClFe(TPP)+ for 60 vibrational bands each using U(2) algebraic model Hamiltonian. Intermode couplings in algebraic models have been included to achieve improved RMS deviations as well as to get deep insight into detailed spectroscopy for these tetraphenyl porphyrin molecules.

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Acknowledgments

The author Srinivasa Rao Karumuri would like to thank Prof. Thomson G. Spiro for providing necessary literature for this study. The author Srinivasa Rao Karumuri also would like to thank The Department of Science & Technology (DST), New Delhi, India, for providing the financial assistance for this study.

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Authors and Affiliations

  1. Department of Electronics and Instrumentation, Lakireddy Bali Reddy College of Engineering, Mylavaram, 521230, Andhra Pradesh, India

    S. Rao Karumuri

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  1. S. Rao Karumuri
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Correspondence to S. Rao Karumuri.

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Karumuri, S.R. A study of vibrational spectra of metallotetraphenyl porphryins: an algebraic approach. Indian J Phys 86, 1147–1153 (2012). https://doi.org/10.1007/s12648-012-0174-3

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