Indian Journal of Physics

, Volume 86, Issue 3, pp 225–235 | Cite as

Towards a broadband chirped pulse Fourier transform microwave spectrometer

Original Paper

Abstract

This article gives a brief review of microwave spectroscopy and the experimental techniques used for obtaining microwave spectrum of molecules and complexes since 1950s. It presents a brief summary of the pulsed nozzle Fourier transform microwave (PNFTMW) spectrometer, fabricated in our laboratory, and discusses some of the important results obtained using the spectrometer. The most significant among the results from this spectrometer is the direct structural determination of weakly bound complexes involving H2O/H2S. These have challenged the conventional wisdom on hydrogen bonding leading us to propose a modern definition for the same through IUPAC. The limitations of the PNFTMW spectrometer and the need for the new chirped pulse Fourier transform microwave spectrometer are discussed as well. Moreover, preliminary results from our laboratory on generating a 1 µs chirped pulse of 1 GHz bandwidth are given.

Keywords

Rotational spectroscopy Supersonic beams Chirp-pulse Fourier-transform microwave spectrometer 

PACS Nos.

33.20.Bx 07.57.Pt 84.40.-x 

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Copyright information

© Indian Association for the Cultivation of Science 2012

Authors and Affiliations

  1. 1.Department of Inorganic and Physical ChemistryIndian Institute of ScienceBangaloreIndia
  2. 2.Department of Electrical Communication EngineeringIndian Institute of ScienceBangaloreIndia

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