Skip to main content

Advertisement

SpringerLink
Log in

Exploration of the Glass Domain in the SiO2-B2O3-TiO2-La2O3 System

  • Original Paper
  • Published:
Silicon Aims and scope Submit manuscript

Abstract

The conventional melting and annealing procedure were used to manufacture glass matrices with a nominal composition of \(x\) La2O3-(\(20-x\))TiO2-23SiO2-57B2O3 and a gradual partial replacement of TiO2 by La2O3. The present study uses X-ray diffraction (XRD), pulse-echo technique, and differential thermal analysis (DTA) to examine the effects of La2O3 content on the TiO2-B2O3-SiO2 glass. The amorphous structure of the samples was confirmed by (XRD) investigations. The DTA curve showed that the glass transition temperature increased between 501 and 566 °C with an increase in La2O3 content. The elastic properties of the glass were established by utilizing variations in density and ultrasonic velocities. The pulse-echo technique examinations revealed an increase in the ultrasonic velocities, the Debye temperature, the micro-hardness, the connectivity of fractal bonds, the Poisson's ratio, and the mechanical parameters. For prepared glasses, Makishima-theory Mackenzie's has also been shown to be applicable. Additionally, the majority of the experimentally determined elastic moduli and Poisson's ratio values are in good agreement with values estimated using Makishima and Mackenzie's model.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Data availability

My manuscript and associated personal data.

References

  1. Fayad AM, Shaaban KS, Abd-Allah WM, Ouis M (2020) Structural and Optical Study of CoO Doping in Borophosphate Host Glass and Effect of Gamma Irradiation. J Inorg Organomet Polym Mater 30(12):5042–5052. https://doi.org/10.1007/s10904-020-01641-3

    Article  CAS  Google Scholar 

  2. El-Maaref AA, Alotaibi BM, Alharbi N, El-Rehim AFA, Shaaban KS (2022) Effect of Fe2O3 as an aggregate replacement on mechanical and gamma/ neutron radiation shielding properties of phosphoaluminate glasses. Journal of Inorganic and Organometallic Polymers and Materials 32 8 3117–3127 https://doi.org/10.1007/s10904-022-02345-6

  3. Shaaban KS, Al-Baradi AM, Wahab EAA (2022) The Impact of Y2O3 on Physical and Optical Characteristics, Polarizability, Optical Basicity, and Dispersion Parameters of B2O3 – SiO2 – Bi2O3 – TiO2 Glasses. Silicon 14:5057. https://doi.org/10.1007/s12633-021-01309-8

    Article  CAS  Google Scholar 

  4. Shaaban KS, Alotaibi BM, Algarni SA et al (2022) Chemical Composition, Mechanical, and Thermal Characteristics of Bioactive Glass for Better Processing Features. Silicon 14:10817–10826. https://doi.org/10.1007/s12633-022-01784-7

    Article  CAS  Google Scholar 

  5. Wahab EAA, Al-Baradi AM, Sayed MA et al (2022) Crystallization and Radiation Proficiency of Transparent Sodium Silicate Glass Doped Zirconia. Silicon 14:8581–8597. https://doi.org/10.1007/s12633-021-01652-w

    Article  CAS  Google Scholar 

  6. Algarni SA, El-Maaref AA, Alotaibi BM et al (2022) Physical, Optical, and Radiation Shielding Features of Yttrium Lithium Borate Glasses. J Inorg Organomet Polym 32:2873–2881. https://doi.org/10.1007/s10904-022-02321-0

    Article  CAS  Google Scholar 

  7. Al-Baradi AM, El-Rehim AFA, Alrowaili ZA et al. (2022) FT-IR and gamma shielding characteristics of 22SiO2- 23Bi2O3-37B2O3-13TiO2-(5-x) LiF- x BaO glasses. Silicon 14 7043–7051. https://doi.org/10.1007/s12633-021-01481-x

  8. Al-Baradi AM, Wahab EAA, Shaaban KS (2022) Preparation and Characteristics of B2O3 – SiO2 – Bi2O3 – TiO2 – Y2O3 Glasses and Glass-Ceramics. Silicon 14:5277–5287. https://doi.org/10.1007/s12633-021-01286-y

    Article  CAS  Google Scholar 

  9. Kh.S. Shaaban, B.M. Alotaibi, Nuha Alharbi, Z.A. Alrowaili, M.S. Al-Buriahi, Sayed A. Makhlouf, A.F. Abd El-Rehim 2022 Physical optical and radiation characteristics of bioactive glasses for dental prosthetics and orthopaedic implants applications Radiation Physics and Chemistry 193 109995 https://doi.org/10.1016/j.radphyschem.2022.109995

  10. Shaaban KS, Alotaibi BM, Alharbiy N et al (2022) Impact of TiO2 on DTA and Elastic Moduli of Calcium Potassium Borophosphosilicate Glasses in Prelude for Use in Dental and Orthopedic Applications. Silicon 14:11991–12000. https://doi.org/10.1007/s12633-022-02029-3

    Article  CAS  Google Scholar 

  11. Shaaban KS, Alyousef HA, El-Rehim AFA (2022) CeO2 Reinforced B2O3–SiO2–MoO3 Glass System: A Characterization Study Through Physical, Mechanical and Gamma / Neutron Shields Characteristics. Silicon 14:12001–12012. https://doi.org/10.1007/s12633-022-02124-5

    Article  CAS  Google Scholar 

  12. Shaaban KS, Al-Baradi AM, Ali AM (2022) (2022) The Impact of Cr2O3 on the Mechanical, Physical, and Radiation Shielding Characteristics of Na2B4O7–CaO–SiO2 Glasses. Silicon 14:10375–10382. https://doi.org/10.1007/s12633-022-01783-8

    Article  CAS  Google Scholar 

  13. Shaaban KS, Boukhris I, Kebaili I et al (2022) Spectroscopic and Attenuation Shielding Studies on B2O3-SiO2-LiF- ZnO-TiO2 Glasses. Silicon 14:3091–3100. https://doi.org/10.1007/s12633-021-01080-w

    Article  CAS  Google Scholar 

  14. Shaaban KS, Al-Baradi AM, Ali AM (2022) Cr2O3 effect on the structure, optical, and radiation shielding properties of Na2B4O7–SiO2–CaO–Cr2O3 glasses. Appl Phys A 128:208. https://doi.org/10.1007/s00339-022-05348-9

    Article  CAS  Google Scholar 

  15. E.A. Abdel Wahab, M.S.I. Koubisy, M.I. Sayyed, K.A. Mahmoud, A.F. Zatsepin, Sayed A. Makhlouf, Kh.S. Shaaban 2021 Novel borosilicate glass system: Na2B4O7-SiO2-MnO2 Synthesis, average electronics polarizability optical basicity and gamma-ray shielding features Journal of Non Crystalline Solids 553 120509 https://doi.org/10.1016/j.jnoncrysol.2020.120509

  16. Shaaban KS, Alrowaili ZA, Al-Baradi AM, Ali AM, Wahab EAA, Al-Buriahi MS (2021) Mechanical and Thermodynamic Characteristics of 22SiO2- 23Bi2O3-37B2O3-13TiO2-(5–x) LiF- x BaO Glasses. Silicon. https://doi.org/10.1007/s12633-021-01441-5

    Article  Google Scholar 

  17. Mahmoud KH, Alsubaie AS, Wahab EAA, Abdel-Rahim FM, Shaaban KS (2021) Research on the Effects of Yttrium on Bismuth Titanate Borosilicate Glass System. Silicon. https://doi.org/10.1007/s12633-021-01125-0

    Article  Google Scholar 

  18. Alrowaili ZA, Al-Baradi AM, Sayed MA, Mossad Ali A, Abdel Wahab EA, Al-Buriahi MS, Shaaban KS (2021) The impact of Fe2O3 on the dispersion parameters and gamma fast neutron shielding characteristics of lithium borosilicate glasses. Optik 168259. https://doi.org/10.1016/j.ijleo.2021.168259

  19. Shaaban KS, Al-Baradi AM, Ali AM (2022) Investigation of BaO reinforced TiO2–P2O5–li2O glasses for optical and neutron shielding applications. RSC Adv 12(5):3036–3043. https://doi.org/10.1039/d2ra00171c

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  20. Alomairy S, Aboraia AM, Shaaban ER et al (2021) Comparative Studies on Spectroscopic and Crystallization Properties of Al2O3 -Li2O- B2O3-TiO2 Glasses. Braz J Phys 51:1237–1248. https://doi.org/10.1007/s13538-021-00928-1

    Article  CAS  Google Scholar 

  21. El-Rehim AFA, Shaaban KS (2021) Influence of La2O3 content on the structural, mechanical, and radiation-shielding properties of sodium fluoro lead barium borate glasses. J Mater Sci: Mater Electron 32:4651–4671. https://doi.org/10.1007/s10854-020-05204-7

    Article  CAS  Google Scholar 

  22. El-Rehim AFA, Wahab EAA, Halaka MMA et al (2022) Optical Properties of SiO2 – TiO2 – La2O3 – Na2O – Y2O3 Glasses and A Novel Process of Preparing the Parent Glass-Ceramics. Silicon 14:373–384. https://doi.org/10.1007/s12633-021-01002-w

    Article  CAS  Google Scholar 

  23. Shaaban KS, Alomairy S, Al-Buriahi MS (2021) Optical, thermal and radiation shielding properties of B2O3–NaF–PbO–BaO–La2O3 glasses. J Mater Sci: Mater Electron 32:26034–26048. https://doi.org/10.1007/s10854-021-05885-8

    Article  CAS  Google Scholar 

  24. Makishima A, Mackenzie JD (1973) Direct calculation of young’s modulus of glass. J Non Cryst Solids 12:35–45. https://doi.org/10.1016/0022-3093(73)90053-7

    Article  CAS  Google Scholar 

  25. Makishima A, Mackenzie JD (1975) Calculation of bulk modulus, shear modulus and Poisson’s ratio of glass. J Non Cryst Solids 17:147–157. https://doi.org/10.1016/0022-3093(75)90047-2

    Article  CAS  Google Scholar 

  26. Sayed MA, Ali AM, Abd El-Rehim AF et al (2021) Dispersion Parameters, Polarizability, and Basicity of Lithium Phosphate Glasses. J Electron Mater 50:3116–3128. https://doi.org/10.1007/s11664-021-08921-9

    Article  CAS  Google Scholar 

  27. Wahab EAA, Alyousef HA, El-Rehim AFA et al (2023) Basicity, Optical Features, and Neutron/Charged Particle Attenuation Characteristics of P2O5-As2O3-PbO Glasses Doped with Tungsten Ions. J Electron Mater 52:219–236. https://doi.org/10.1007/s11664-022-09969-x

    Article  CAS  Google Scholar 

  28. Shaaban KS, Al-Baradi AM, Ali AM (2022) Gamma-ray shielding and mechanical characteristics of iron-doped lead phosphosilicate glasses. Silicon 14:8971–8979. https://doi.org/10.1007/s12633-022-01702-x

    Article  CAS  Google Scholar 

  29. Ali AM, Alrowaili ZA, Al-Baradi AM et al (2022) A Study of Thermal, and Optical Properties of 22SiO2- 23Bi2O3-37B2O3-13TiO2-(5–x) LiF- x BaO Glasses. Silicon 14:6447–6455. https://doi.org/10.1007/s12633-021-01440-6

    Article  CAS  Google Scholar 

  30. Subbalakshmi P, Veeraiah N (2002) Study of CaO–WO3–P2O5 glass system by dielectric properties, IR spectra and differential thermal analysis. J Non-Cryst Solids 298:89–98

    Article  CAS  Google Scholar 

  31. Han L, Song J, Zhang QS et al (2018) Structure and Properties of MgO-Al2O3-SiO2-B2O3 Transparent Glass-Ceramics. Silicon 10:2685–2693. https://doi.org/10.1007/s12633-018-9806-3

    Article  CAS  Google Scholar 

  32. Han J, Lai Y, Xiang Y et al (2017) Glass structure of the CaO–B2O3–SiO2–Al2O3–ZnO glasses system with different Si content. J Mater Sci: Mater Electron 28:6131–6137. https://doi.org/10.1007/s10854-016-6291-6

    Article  CAS  Google Scholar 

  33. Hordieiev YS, Karasik EV, Zaichuk AV (2022) Glass Formation in the MgO–B2O3–SiO2 System. Silicon. https://doi.org/10.1007/s12633-022-01745-0

    Article  Google Scholar 

  34. Kolay S, Bhargava P (2022) Role of MgO in lowering glass transition temperature and increasing hardness of lithium silicate glass and glass-ceramics. Ceram Int 48(9):12699–12711. https://doi.org/10.1016/j.ceramint.2022.01.139

    Article  CAS  Google Scholar 

  35. Kolay S, Bhargava P (2021) Effect of K2O:Al2O3 Ratio on Crystallization Phenomena and Microstructure of Lithium Silicate Glass-Ceramics. Trans Indian Ceram Soc 80(4):242–250. https://doi.org/10.1080/0371750X.2021.2001693

    Article  CAS  Google Scholar 

  36. Kolay S, Bhargava P (2019) Phase and microstructural evolution in lithium silicate glass-ceramics with externally added nucleating agent. J Am Ceram Soc 102:7312–7328. https://doi.org/10.1111/jace.16682

    Article  CAS  Google Scholar 

  37. Almuqrin AH, Mahmoud KA, Wahab EAA, Koubisy MSI, Sayyed MI, Shaaban KS (2021) Structural mechanical and nuclear radiation shielding properties of iron aluminoleadborate glasses. The European Physical Journal Plus 136:6. https://doi.org/10.1140/epjp/s13360-021-01564-z

    Article  CAS  Google Scholar 

  38. Alothman MA, Alrowaili ZA, Alzahrani JS, Wahab EAA, Olarinoye IO, Sriwunkum C, Shaaban KS, Al-Buriahi MS (2021) Significant influence of MoO3 content on synthesis mechanical and radiation shielding properties of B2O3-Pb3O4-Al2O3 glasses. J Alloys Compounds 882 160625. https://doi.org/10.1016/j.jallcom.2021.160625

  39. El-Rehim AFA, Shaaban KS, Zahran HY, Yahia IS, Ali AM, Halaka MMA, Makhlouf SA, Wahab EAA, Shaaban ER (2021) Structural and Mechanical Properties of Lithium Bismuth Borate Glasses Containing Molybdenum (LBBM) Together with their Glass-Ceramics. J Inorg Organomet Polym Mater 31:1057–1065. https://doi.org/10.1007/s10904-020-01708-1

    Article  CAS  Google Scholar 

  40. El-Rehim AFA, Zahran HY, Yahia IS et al (2021) Structural, Elastic Moduli, and Radiation Shielding of SiO2-TiO2-La2O3-Na2O Glasses Containing Y2O3. J of Materi Eng and Perform 30:1872–1884. https://doi.org/10.1007/s11665-021-05513-w

    Article  CAS  Google Scholar 

  41. Saddeek YB, Aly KA, Shaaban KS, Ali AM, Sayed MA (2019) The Effect of TiO2 on the Optical and Mechanical Properties of Heavy Metal Oxide Borosilicate Glasses. Silicon 11:1253–1260. https://doi.org/10.1007/s12633-018-9912-2

    Article  CAS  Google Scholar 

  42. Shaaban KS, Alomairy S, Al-Buriahi MS (2021) Optical thermal and radiation shielding properties of B2O3–NaF–PbO–BaO–La2O3 glasses. J Mater Sci: Mater Electron 32:26034. https://doi.org/10.1007/s10854-021-05885-8

    Article  CAS  Google Scholar 

  43. Rammah YS, El-Agawany FI, Wahab EAA, Hessien MM, Shaaban KS (2022) Significant impact of V2O5 content on lead phosphor-arsenate glasses for mechanical and radiation shielding applications. Radiat Phys Chem 193:109956.  https://doi.org/10.1016/j.radphyschem.2021.109956.

  44. Shaaban KhS, Al-Baradi AM, Alotaibi BM, Abd El-Rehim AF (2023) Mechanical and radiation shielding features of lithium titanophosphate glasses doped BaO. J Mater Res Technol 23:756–764. https://doi.org/10.1016/j.jmrt.2023.01.062

    Article  CAS  Google Scholar 

  45. Shaaban KS, Alyousef HA, Alotaibi BM, El-Rehim AFA, Wahab EAA (2022) The Vital Role of TiO2 on the Bioglass System P2O5-CaO-B2O3-SiO2- K2O for Optics and Shielding Characteristics. J Inorg Organomet Polym 32:4295. https://doi.org/10.1007/s10904-022-02446-2

    Article  CAS  Google Scholar 

  46. Shaaban KS, Al-Baradi AM, Ali AM (2022) The Impact of Cr2O3 on the Mechanical, Physical, and Radiation Shielding Characteristics of Na2B4O7–CaO–SiO2 Glasses. SILICON 14:10375. https://doi.org/10.1007/s12633-022-01783-8

    Article  CAS  Google Scholar 

  47. Rammah YS, El-Agawany FI, Wahab EAA, Hessien MM, Shaaban KS (2022) Significant impact of V2O5 content on lead phosphor-arsenate glasses for mechanical and radiation shielding applications. Radiat Phys Chem 193: 109956. https://doi.org/10.1016/j.radphyschem.2021.109956

  48. El-Rehim AFA, Shaaban KS, Zahran HY, Yahia IS, Ali AM, Halaka MMA, Makhlouf SA, Wahab EAA, Shaaban ER (2021) Structural and Mechanical Properties of Lithium Bismuth Borate Glasses Containing Molybdenum (LBBM) Together with their Glass-Ceramics. J Inorg Organomet Polym 31:1057. https://doi.org/10.1007/s10904-020-01708-1

    Article  CAS  Google Scholar 

  49. El-Rehim AFA, Ali AM, Zahran HY, Yahia IS, Shaaban KS (2021) Spectroscopic, Structural, Thermal, and Mechanical Properties of B2O3-CeO2-PbO2 Glasses. J Inorg Organomet Polym Mater 31:1774–1786. https://doi.org/10.1007/s10904-020-01799-w

    Article  CAS  Google Scholar 

Download references

Acknowledgements

This work was supported by the King Khalid University through a grant RCAMS/KKU/04-22 under the Research Center for Advance Materials (RCAMS) at King Khalid University, Saudi Arabia. The authors express their gratitude to princess Nourah bint Abdulrahman University, Researchers Supporting Project (Grant No. PNURSP2023R32) Princess Nourah bint Abdulrahman University, Riyadh, Saudi Arabia.

Author information

Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, Al - Azhar University, P.O. 71452, Assiut, Egypt

    Kh. S. Shaaban

  2. Physics Department, College of Science, Princess Nourah Bint Abdulrahman University, P.O. Box 84428, Riyadh, 11681, Saudi Arabia

    B. M. Alotaibi

  3. Department of Physics, College of Science, Taif University, P.O. Box 11099, Taif, 21944, Saudi Arabia

    Ateyyah M. Al-Baradi

  4. Research Center for Advanced Materials Science (RCAMS), King Khalid University, Zip Code: 61413, Abha, Saudi Arabia

    El Sayed Yousef

  5. Physics Department, Faculty of Science, King Khalid University, Zip Code: 61413, Abha, Saudi Arabia

    El Sayed Yousef

  6. Physics Department, Faculty of Science, Islamic University, P. O. Box 170, Al Madinah, Saudi Arabia

    A. Ashour

Authors
  1. Kh. S. Shaaban
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. B. M. Alotaibi
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Ateyyah M. Al-Baradi
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. El Sayed Yousef
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. A. Ashour
    View author publications

    You can also search for this author in PubMed Google Scholar

Contributions

Khamies Saber Shaaban, methodology, writing the manuscript, review the manuscript, Ateyyah Mohamed Al-Baradi, review the manuscript and Badriah Mesfer Alotaibi, review the manuscript, El Sayed Yousef, review the manuscript and A. Ashour, review the manuscript.

Corresponding author

Correspondence to Kh. S. Shaaban.

Ethics declarations

Ethics Approval and Consent to Participate

The manuscript has not been published.

Consent to Participate and Publication

The authors consent to participate and publication.

Competing Interests

The authors declare no competing interests.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Shaaban, K.S., Alotaibi, B.M., Al-Baradi, A.M. et al. Exploration of the Glass Domain in the SiO2-B2O3-TiO2-La2O3 System. Silicon 15, 4409–4416 (2023). https://doi.org/10.1007/s12633-023-02351-4

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s12633-023-02351-4

Keywords

Search

Navigation