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The Impact of Cr2O3 on the Mechanical, Physical, and Radiation Shielding Characteristics of Na2B4O7–CaO–SiO2 Glasses

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Abstract

The rapid-quenching route was used to prepare Na2B4O7–CaO–SiO2 glass formulations with various Cr2O3 concentrations. XRD analyses were used to determine the amorphous states of glasses. With the addition of Cr2O3, the glass density increased while molar volume reduces. The elastic moduli and velocities have been discovered to be affected by Cr2O3 concentration. A theoretical model of the prepared glasses’ gamma-ray shielding ability has also been developed. With increasing photon energy, the mass attenuation coefficient values were found to reduce. As a result, G 5 glass provides more shielding than other glasses. Incorporating Cr2O3 into the investigated glass compositions has a significant influence on their mechanical and gamma shielding features, according to the findings of this study. In the future, this research could be used to improve mechanical efficiency and reduce radiation’s harmful effects on organisms.

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References

  1. Alrowaili ZA, Ali AM, Al-Baradi AM et al (2022) A significant role of MoO3 on the optical, thermal, and radiation shielding characteristics of B2O3–P2O5–Li2O glasses. Opt Quant Electron 54:88. https://doi.org/10.1007/s11082-021-03447-0

    Article  CAS  Google Scholar 

  2. Wahab EAA, Al-Baradi AM, Sayed MA et al (2022) Crystallization and radiation proficiency of transparent sodium silicate glass doped zirconia. Silicon. https://doi.org/10.1007/s12633-021-01652-w

  3. Rammah YS, El-Agawany FI, Wahab EAA, Hessien MM, Shaaban K (2022) Significant impact of V2O5 content on lead phosphor-arsenate glasses for mechanical and radiation shielding applications. Radiation Phys Chem 193:109956. https://doi.org/10.1016/j.radphyschem.2021.109956

    Article  CAS  Google Scholar 

  4. Fayad AM, Shaaban KS, Abd-Allah WM, Ouis M (2020) Structural and optical study of CoO doping in borophosphate host glass and effect of gamma irradiation. J Inorg Organomet Polym Mater 30:5042–5052. https://doi.org/10.1007/s10904-020-01641-3

    Article  CAS  Google Scholar 

  5. Koubisy MSI, Shaaban KS, Wahab EAA, Sayyed MI, Mahmoud KA (2021) Synthesis, structure, mechanical and radiation shielding features of 50SiO2–(48 + X) Na2B4O7–(2 – X) MnO2 glasses. Eur Phys J Plus 136. https://doi.org/10.1140/epjp/s13360-021-01125-4

  6. Shaaban KHS, Saddeek YB, Aly K (2018) Physical properties of pseudo quaternary Na2B4O7– SiO2– MoO3– Dy2O3 glasses. Ceram Int 44:3862–3867. https://doi.org/10.1016/j.ceramint.2017.11.175

    Article  CAS  Google Scholar 

  7. Abdel Wahab EA, Koubisy MSI, Sayyed MI, Mahmoud KA, Zatsepin AF, Makhlouf SA, Shaaban KS (2021) Novel borosilicate glass system: Na2B4O7-SiO2-MnO2: Synthesis, average electronics polarizability, optical basicity, and gamma-ray shielding features. J Non-Cryst Solids 553:120509. https://doi.org/10.1016/j.jnoncrysol.2020.120509

    Article  CAS  Google Scholar 

  8. El-Rehim AFA, Zahran HY, Yahia IS, Ali AM, Shaaban KS (2020) Physical, radiation shielding and crystallization properties of Na2O-Bi2O3- MoO3-B2O3- SiO2-Fe2O3 glasses. Silicon. https://doi.org/10.1007/s12633-020-00827-1

    Article  Google Scholar 

  9. Shaaban KS, Al-Baradi AM, Alrowaili ZA, Ali AM, Al-Buriahi MS, Wahab EAA (2021) Structural, thermal, and mechanical characteristics of yttrium lithium borate glasses and glass–ceramics. J Mater Sci: Mater Electron 32:28065–28075. https://doi.org/10.1007/s10854-021-07158-w

    Article  CAS  Google Scholar 

  10. El-Rehim AFA, Zahran HY, Yahia IS, Makhlouf SA, Shaaban KS (2021) Radiation, crystallization, and physical properties of cadmium borate glasses. Silicon 13:2289–2307. https://doi.org/10.1007/s12633-020-00798-3

    Article  CAS  Google Scholar 

  11. Alomairy S, Aboraia AM, Shaaban ER, Shaaban KS (2021) Comparative studies on spectroscopic and crystallization properties of Al2O3 -Li2O- B2O3-TiO2 glasses. Braz J Phys 51:1237–1248. https://doi.org/10.1007/s13538-021-00928-1

    Article  CAS  Google Scholar 

  12. Abdel Wahab EA, Shaaban KS, Yousef ES (2020) Enhancement of optical and mechanical properties of sodium silicate glasses using zirconia. Opt Quantum Electron 52. https://doi.org/10.1007/s11082-020-02575-3

    Article  Google Scholar 

  13. Wahab EAA, Aboraia AM, Shafey AME, Shaaban KS, Soldatov AV (2021) The effect of ZrO2 on the linear and non-linear optical properties of sodium silicate glass. Opt Quant Electron 53(9). https://doi.org/10.1007/s11082-021-03164-8

  14. Alharbi T, Mohamed HFM, Saddeek YB, El-Haseib AY, Shaaban KS (2019) Study of the TiO2 effect on the heavy metals oxides borosilicate glasses structure using gamma-ray spectroscopy and positron annihilation technique. Radiat Phys Chem 164:108345. https://doi.org/10.1016/j.radphyschem.2019.108345

    Article  CAS  Google Scholar 

  15. Shaaban KS, Saddeek YB (2017) Effect of MoO3 content on structural, thermal, mechanical and optical properties of (B2O3-SiO2-Bi2O3-Na2O-Fe2O3) glass system. Silicon 9:785–793. https://doi.org/10.1007/s12633-017-9558-5

    Article  CAS  Google Scholar 

  16. Mahmoud KH, Alsubaie AS, Wahab EAA, Abdel-Rahim FM, Shaaban KS (2021) Research on the effects of Yttrium on Bismuth Titanate Borosilicate glass system. Silicon. https://doi.org/10.1007/s12633-021-01125-0

    Article  Google Scholar 

  17. Shaaban KS, Boukhris I, Kebaili I, Al-Buriahi MS (2021) Spectroscopic and attenuation shielding studies on B2O3-SiO2-LiF-ZnO-TiO2 glasses. Silicon. https://doi.org/10.1007/s12633-021-01080-w

    Article  Google Scholar 

  18. Shaaban KS, Al-Baradi AM, Wahab EAA (2021) The impact of Y2O3 on physical and optical characteristics, polarizability, optical basicity, and dispersion parameters of B2O3– SiO2– Bi2O3– TiO2 glasses. Silicon. https://doi.org/10.1007/s12633-021-01309-8

    Article  Google Scholar 

  19. Al-Baradi AM, El-Rehim AFA, Alrowaili ZA, Al-Buriahi MS, Shaaban KS (2021)FT-IR and gamma shielding characteristics of 22SiO2- 23Bi2O3-37B2O3-13TiO2-(5-x) LiF- x BaO glasses. Silicon. https://doi.org/10.1007/s12633-021-01481-x

    Article  Google Scholar 

  20. Ali AM, Alrowaili ZA, Al-Baradi AM, Al-Buriahi MS, Wahab EAA, Shaaban KS (2021) A study of thermal, and optical properties of 22SiO2- 23Bi2O3-37B2O3-13TiO2-(5-x) LiF- x BaO glasses. Silicon. https://doi.org/10.1007/s12633-021-01440-6

  21. Shaaban KS, Al-Baradi AM, Wahab EAA (2021) The impact of Y2O3 on physical and optical characteristics, polarizability, optical basicity, and dispersion parameters of B2O3– SiO2– Bi2O3– TiO2 glasses. Silicon. https://doi.org/10.1007/s12633-021-01309-8

    Article  Google Scholar 

  22. Alrowaili ZA, Al-Baradi AM, Sayed MA, Mossad Ali A, Abdel Wahab EA, Al-Buriahi MS, Shaaban KS (2021) The impact of Fe2O3 on the dispersion parameters and gamma / fast neutron shielding characteristics of lithium borosilicate glasses. Optik 168259. https://doi.org/10.1016/j.ijleo.2021.168259

  23. Saddeek YB, Aly KA, Shaaban KS, Ali AM, Sayed MA (2019) The effect of TiO2 on the optical and mechanical properties of heavy metal oxide borosilicate glasses. Silicon 11:1253–1260. https://doi.org/10.1007/s12633-018-9912-2

    Article  CAS  Google Scholar 

  24. El-Maaref AA, Wahab EAA, Shaaban KS, El-Agmy RM (2021) Enhancement of spectroscopic parameters of Er3+-doped cadmium lithium gadolinium silicate glasses as an active medium for lasers and optical amplifiers in the NIR-region. Solid State Sci 113:106539. https://doi.org/10.1016/j.solidstatesciences.2021.106539

    Article  CAS  Google Scholar 

  25. El-Rehim AFA, Shaaban KS (2021) Influence of La2O3 content on the structural, mechanical, and radiation-shielding properties of sodium fluoro lead barium borate glasses. J Mater Sci: Mater Electron 32:4651–4671. https://doi.org/10.1007/s10854-020-05204-7

    Article  CAS  Google Scholar 

  26. Shaaban KS, Alomairy S, Al-Buriahi MS (2021) Optical, thermal and radiation shielding properties of B2O3–NaF–PbO–BaO–La2O3 glasses. J Mater Sci: Mater Electron. https://doi.org/10.1007/s10854-021-05885-8

    Article  Google Scholar 

  27. El-Rehim AFA, Ali AM, Zahran HY, Yahia IS, Shaaban KS (2021) Spectroscopic, structural, thermal, and mechanical properties of B2O3-CeO2-PbO2 glasses. J Inorg Organomet Polym Mater 31:1774–1786. https://doi.org/10.1007/s10904-020-01799-w

    Article  CAS  Google Scholar 

  28. Shaaban KS, Yousef ES (2020) Optical properties of Bi2O3 doped boro tellurite glasses and glass ceramics. Optik 203:163976. https://doi.org/10.1016/j.ijleo.2019.163976

    Article  CAS  Google Scholar 

  29. Sayed MA, Ali AM, Abd El-Rehim AF et al (2021) Dispersion parameters, polarizability, and basicity of lithium phosphate glasses. J Elec Mater 50:3116–3128. https://doi.org/10.1007/s11664-021-08921-9

    Article  CAS  Google Scholar 

  30. Dahshan A, Saddeek YB, Aly KA, Shaaban KHS, Hussein MF, Naga AE, Shaban AO, Mahmoud SA (2019) Preparation and characterization of Li2B4O7– TiO2– SiO2 glasses doped with metal-organic framework derived nano-porous Cr. J Non-Crystalline Solids 508 2O3:51–61. https://doi.org/10.1016/j.jnoncrysol.2019.01.002

    Article  CAS  Google Scholar 

  31. Shaaban KS, Yousef ES, Mahmoud SA, Wahab EAA, Shaaban ER (2020) Mechanical, Structural and Crystallization Properties in Titanate doped phosphate glasses. J Inorg Organomet Polym Mater 30:4655–4663. https://doi.org/10.1007/s10904-020-01574-x

    Article  CAS  Google Scholar 

  32. El-Maaref AA, Badr S, Shaaban KS, Wahab A, Elokr EA (2019) Optical properties and radiative rates of Nd3+ doped zinc-sodium phosphate glasses. J Rare Earths 37:253–259. https://doi.org/10.1016/j.jre.2018.06.006

    Article  CAS  Google Scholar 

  33. Abdel Wahab EA, El-Maaref AA, Shaaban KS, Börcsök J, Abdelawwad M (2021) Lithium cadmium phosphate glasses doped Sm3+ as a host material for near-IR laser applications. Opt Mater 111:110638. https://doi.org/10.1016/j.optmat.2020.110638

    Article  CAS  Google Scholar 

  34. El-Taher A, Ali AM, Saddeek YB, Elsaman R, Algarni H, Shaaban K, Amer TZ (2019) Gamma ray shielding and structural properties of iron alkali alumino-phosphate glasses modified by PbO. Radiat Phys Chem 165:108403. https://doi.org/10.1016/j.radphyschem.2019.108403

    Article  CAS  Google Scholar 

  35. Yadav A, Dahiya MS, Hooda A, Chand P, Khasa S (2017) Structural influence of mixed transition metal ions on lithium bismuth borate glasses. Solid State Sci 70:54–65. https://doi.org/10.1016/j.solidstatesciences.2017.06.011

    Article  CAS  Google Scholar 

  36. Shaaban KS, Alrowaili ZA, Al-Baradi AM, Ali AM, Wahab EAA, Al-Buriahi MS (2021) Mechanical and thermodynamic characteristics of 22SiO2- 23Bi2O3-37B2O3-13TiO2-(5-x) LiF- x BaO glasses. Silicon. https://doi.org/10.1007/s12633-021-01441-5

  37. Al-Baradi AM, El-Rehim AFA, Alrowaili ZA, Al-Buriahi MS, Shaaban KS (2021)FT-IR and gamma shielding characteristics of 22SiO2- 23Bi2O3-37B2O3-13TiO2-(5-x) LiF- x BaO glasses. Silicon. https://doi.org/10.1007/s12633-021-01481-x

    Article  Google Scholar 

  38. Shaaban KS, Al-Baradi AM, Ali AM (2022) Cr2O3 effect on the structure, optical, and radiation shielding properties of Na2B4O7–SiO2–CaO–Cr2O3 glasses. Appl Phys A 128:208. https://doi.org/10.1007/s00339-022-05348-9

    Article  CAS  Google Scholar 

  39. Şakar E, Özpolat ÖF, Alım B, Sayyed MI, Kurudirek M (2020) PhyX / PSD: Development of a user-friendly online software for calculation of parameters relevant to radiation shielding and dosimetry. Radiation Phys Chem 166:108496. https://doi.org/10.1016/j.radphyschem

    Article  Google Scholar 

  40. Shaaban KS, Abdel Wahab EA, El-Maaref AA, Abdelawwad M, Shaaban ER, Yousef ES, Wilke H, Hillmer H, Börcsök J (2020)Judd–Ofelt analysis and physical properties of erbium modified cadmium lithium gadolinium silicate glasses. J Mater Sci: Mater Electron 31:4986–4996. https://doi.org/10.1007/s10854-020-03065-8

    Article  CAS  Google Scholar 

  41. Shaaban KS, Koubisy MSI, Zahran HY, Yahia IS (2020) Spectroscopic properties, electronic polarizability, and optical basicity of titanium–cadmium Tellurite glasses doped with different amounts of lanthanum. J Inorg Organomet Polym Mater 30:4999–5008. https://doi.org/10.1007/s10904-020-01640-4

    Article  CAS  Google Scholar 

  42. El-Maaref AA, El-Agmy RM, Shaaban KS, Wahab A, E.A (2021) Optical and spectroscopic study of Nd2O3-doped SBN glass in the near-infrared, visible and UV regions under pumping up-conversion emissions. Eur Phys J Plus 136. https://doi.org/10.1140/epjp/s13360-021-01798-x

  43. Wahab EAA, Aboraia AM, Shafey AME, Shaaban KS, Soldatov AV (2021) The effect of ZrO2 on the linear and non-linear optical properties of sodium silicate glass. Opt Quant Electron 53. https://doi.org/10.1007/s11082-021-03164-8

  44. Abdel Wahab EA, Shaaban KS, Alomairy S, Al-Buriahi MS (2021) Electronegativity and optical basicity of glasses containing Na/Pb/B and their high performance for radiation applications: role of ZrO2 nanoparticles. Eur Phys J Plus 136. https://doi.org/10.1140/epjp/s13360-021-01572-z

  45. El-Rehim AFA, Shaaban KS, Zahran HY, Yahia IS, Ali AM, Halaka MMA, Makhlouf SA, Wahab EAA, Shaaban ER (2021) Structural and mechanical properties of Lithium Bismuth Borate Glasses Containing Molybdenum (LBBM) together with their glass–ceramics. J Inorg Organomet Polym Mater 31:1057–1065. https://doi.org/10.1007/s10904-020-01708-1

    Article  CAS  Google Scholar 

  46. Shaaban KS, Zahran HY, Yahia IS, Elsaeedy HI, Shaaban ER, Makhlouf SA, Wahab EAA, Yousef ES (2020) Mechanical and radiation-shielding properties of B2O3–P2O5–Li2O–MoO3 glasses. Appl Phys A 126. https://doi.org/10.1007/s00339-020-03982-9

  47. Shaaban KS, Al-Baradi AM, Ali AM (2022) Physical, mechanical, and thermal characteristics of B2O3- SiO2- Li2O -Fe2O3 glasses. Silicon. https://doi.org/10.1007/s12633-022-01703-w

  48. Abdel Wahab EA, Shaaban KS, Yousef ES (2020) Enhancement of optical and mechanical properties of sodium silicate glasses using zirconia. Opt Quant Electron 52. https://doi.org/10.1007/s11082-020-02575-3

  49. Alothman MA, Alrowaili ZA, Alzahrani JS, Wahab EAA, Olarinoye IO, Sriwunkum C, Shaaban KS, Al-Buriahi MS (2021) Significant influence of MoO3 content on synthesis, mechanical, and radiation shielding properties of B2O3-Pb3O4-Al2O3 glasses. J Alloys Compd 882:160625. https://doi.org/10.1016/j.jallcom.2021.160625

    Article  CAS  Google Scholar 

  50. Albarzan B, Almuqrin AH, Koubisy MS, Abdel Wahab EA, Mahmoud KA, Shaaban KhS, Sayyed MI (2021) Effect of Fe2O3 doping on structural, FTIR and radiation shielding characteristics of aluminium-lead-borate glasses. Prog Nucl Energy. https://doi.org/10.1016/j.pnucene.2021.103931

    Article  Google Scholar 

  51. Alomairy S, Alrowaili ZA, Kebaili I, Wahab EAA, Mutuwong C, Al-Buriahi MS, Shaaban KS (2021) Synthesis of Pb3O4-SiO2-ZnO-WO3 glasses and their fundamental properties for gamma shielding applications. Silicon. https://doi.org/10.1007/s12633-021-01347-2

    Article  Google Scholar 

  52. Alomairy S, Al-Buriahi MS, Abdel Wahab EA, Sriwunkum C, Shaaban K (2021) Synthesis, FTIR, and neutron/charged particle transmission properties of Pb3O4–SiO2–ZnO–WO3 glass system. Ceram Int 47:17322–17330. https://doi.org/10.1016/j.ceramint.2021.03.045

    Article  CAS  Google Scholar 

  53. Shaaban KS, Alomairy S, Al-Buriahi MS (2021) Optical, thermal and radiation shielding properties of B2O3–NaF–PbO–BaO–La2O3 glasses. J Mater Sci: Mater Electron. https://doi.org/10.1007/s10854-021-05885-8

    Article  Google Scholar 

  54. Shaaban KS, Al-Baradi AM, Ali AM (2022)Gamma-ray shielding and mechanical characteristics of iron-doped lead phosphosilicate glasses. Silicon. https://doi.org/10.1007/s12633-022-01702-x

  55. Shaaban KS, Al-Baradi AM, Ali AM (2022) Investigation of BaO reinforced TiO2–P2O5–li2O glasses for optical and neutron shielding applications. RSC Adv 12(5):3036–3043. https://doi.org/10.1039/d2ra00171c

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  56. El-Rehim AFA, Zahran HY, Yahia IS, Wahab EAA, Shaaban KS (2021) Structural, elastic moduli, and radiation shielding of SiO2-TiO2-La2O3-Na2O glasses containing Y2O3. J Mater Eng Perform 30:1872–1884. https://doi.org/10.1007/s11665-021-05513-w

    Article  CAS  Google Scholar 

  57. Shaaban KS, Al-Baradi AM, Ali AM (2022) Physical, optical, and advanced radiation absorption characteristics of cadmium lead phosphate glasses containing MoO3 J Mater Sci: Mater Electron. https://doi.org/10.1007/s10854-021-07530-w

    Article  Google Scholar 

  58. Rammah YS, El-Agawany FI, Wahab EAA, Hessien MM, Shaaban K (2022) Significant impact of V2O5 content on lead phosphor-arsenate glasses for mechanical and radiation shielding applications. Radiat Phys Chem 109956. https://doi.org/10.1016/j.radphyschem.2021.109956

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Acknowledgements

We would like to thank Taif University Research Supporting Project number (TURSP-2020/24), Taif University, Taif, Saudi Arabia. Moreover, the authors express their gratitude to the Deanship of Scientific Research at King Khalid University for funding this work through research groups program under grant number R.G.P. 1/298/42.

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Shaaban, K.S., Al-Baradi, A.M. & Ali, A.M. The Impact of Cr2O3 on the Mechanical, Physical, and Radiation Shielding Characteristics of Na2B4O7–CaO–SiO2 Glasses. Silicon 14, 10375–10382 (2022). https://doi.org/10.1007/s12633-022-01783-8

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