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Synthesis of Clay/Poly (styrene/2-ethylhexyl acrylate) Nanocomposite Latexes via Emulsion Polymerization

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Abstract

In this research, nanocomposite latex based on polystyrene-co-2-ethylhexyl acrylate with layered silicate was synthesized by emulsion polymerization procedure. For increasing compatibility between the organophilic montmorillonite (Cloisite 30B) and polymer matrix, the Cloisite 30B was reacted with vinyltricholorosilane as a coupling agent to replace the edge hydroxyl groups of the layered silicate with a vinyl moiety. The chemical grafting the polymer onto surface of Cloisite 30B was clearly confirmed by FT-IR spectroscopy. Wide-angle X-ray diffraction (WAXD) and scanning electron microscopy (SEM) analyses were performed in order to investigate the extent of dispersion of the filler in the matrix. The glass transition temperatures of the materials were determined by differential scanning calorimetry (DSC). Also, the thermal properties of the polymer nanocomposites were characterized using (TGA) analysis. The obtained results showed that the nanocomposites with the 0.3 and 0.5 wt% nanoclay had the exfoliated structures, whereas the nanocomposite with the 1.0 wt% nanoclay had both exfoliated and intercalated structures. The formation of these structures in nanocomposite with 1.0 wt% nanoclay was confirmed by WXRD, SEM and TEM.

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References

  1. Ebrahimnezhad-Khaljiri H, Eslami-Farsani R, Arbab Chirani S (2019) Microcapsulated epoxy resin with nanosilica-urea formaldehyde composite shell. J Appl Polym Sci 137:48580. https://doi.org/10.1002/app.48580

    Article  CAS  Google Scholar 

  2. Ebrahimnezhad-Khaljiri H, Eslami-Farsani R, Khosravi H, Shahrabi-Farahani A (2019) Improving the flexural properties of E-glass fibers/epoxy isogrid stiffened composites through addition of 3-glycidoxypropyltrimethoxysilane functionalized nanoclay. Silicon. https://doi.org/10.1007/s12633-019-00346-8

  3. Jlassi K, Chandran S, Mičušik M, Benna-Zayani M, Yagci Y, Thomas S, Chehimi MM (2015) Poly(glycidyl methacrylate)-grafted clay nanofiller for highly transparent and mechanically robust epoxy composites. Eur Polym J 72:89–101

    Article  CAS  Google Scholar 

  4. Follain N, Alexandre B, Chappey C, Colasse L, Médéric P, Marais S (2016) Barrier properties of polyamide 12/montmorillonite nanocomposites: effect of clay structure and mixing conditions. Compos Sci Technol 136:18–28

    Article  CAS  Google Scholar 

  5. Kotal M, Bhowmick AK (2015) Polymer nanocomposites from modified clays: recent advances and challenges. Prog Polym Sci 51:127–187

    Article  CAS  Google Scholar 

  6. Chiu C-W, Huang T-K, Wang Y-C, Alamani BG, Lin J-J (2014) Intercalation strategies in clay/polymer hybrids. Prog Polym Sci 39:443–485

    Article  CAS  Google Scholar 

  7. Abbasian M, Pakzad M, Amirmanesh M (2017) Polymericaly modified clays to preparation of polystyrene nanocomposite by nitroxide mediated radical polymerization and solution blending methods. Polym Compos 38:1127–1134

    Article  CAS  Google Scholar 

  8. Ma J, Xu J, Ren J-H, Yu Z-Z, Mai Y-W (2003) A new approach to polymer/montmorillonite nanocomposites. Polymer 44:4619–4624

    Article  CAS  Google Scholar 

  9. Sinha Ray S, Okamoto M (2003) Polymer/layered silicate nanocomposites: a review from preparation to processing. Prog Polym Sci 28:1539–1641

    Article  Google Scholar 

  10. Yermiyahu Z, Lapides I, Yariv S (2005) Thermo-XRD-analysis of montmorillonite treated with protonated Congo-red. Curve fitting. Appl Clay Sci 30:33–41

    Article  CAS  Google Scholar 

  11. Bee S-L, Abdullah MAA, Mamat M, Bee S-T, Sin LT, Hui D, Rahmat AR (2017) Characterization of silylated modified clay nanoparticles and its functionality in PMMA. Compos Part B-Eng 110:83–95

    Article  CAS  Google Scholar 

  12. Sookyung U, Nakason C, Venneman N, Thaijaroend W (2016) Influence concentration of modifying agent on properties of natural rubber/organoclay nanocomposites. Polym Test 54:223–232

    Article  CAS  Google Scholar 

  13. He S, Jia H, Lin Y, Qian H, Lin J (2016) Effect of clay modification on the structure and properties of sulfonated poly(ether ether ketone)/clay nanocomposites. Polym Compos 37:2632–2638

    Article  CAS  Google Scholar 

  14. Raju A, Lakshmi V, Vishnu Prataap RK, Resmi VG, Rajan TPD, Pavithran C, Prasad VS, Mohan S (2016) Adduct modified nano-clay mineral dispersed polystyrene nanocomposites as advanced corrosion resistance coatings for aluminum alloys. Appl Clay Sci 126:81–88

    Article  CAS  Google Scholar 

  15. Ding C, Guo B, He H, Jia D, Hong H (2005) Preparation and structure of highly confined intercalated polystyrene/montmorillonite nanocomposite via a two-step method. Eur Polym J 41:1781–1786

    Article  CAS  Google Scholar 

  16. Penoff ME, Lanfranconi M, Alvarez VA, Ollier R (2015) Curing kinetics of epoxy/alkyl phosphonium modified nanoclay composites for high performance applications. Thermochim Acta 608:20–29

    Article  CAS  Google Scholar 

  17. Lin J-J, Chan Y-N Lan Y-F (2010) Hydrophobic modification of layered clays and compatibility for epoxy nanocomposites. Materials 3:2588–2605

    Article  CAS  Google Scholar 

  18. Xidas PI, Triantafyllidis KS (2010) Effect of the type of alkylammonium ion clay modifier on the structure and thermal/mechanical properties of glassy and rubbery epoxy–clay nanocomposites. Eur Polym J 46:404–417

    Article  CAS  Google Scholar 

  19. Salehi-Mobarakeh H, Yadegari A, Khakzad-Esfahlan F, Mahdavian A (2012) Modifying montmorillonite clay via silane grafting and interfacial polycondensation for melt compounding of nylon-66 nanocomposite. J Appl Polym Sci 124:1501–1510

    Article  CAS  Google Scholar 

  20. Dhanapal D, Srinivasan AK, Ramalingam N (2018) Role of POSS as coupling agent for DGEBA/GF reinforced nanocomposites. Silicon 10:537–546

    Article  CAS  Google Scholar 

  21. Dhanapal D, Muthukaruppan A, Srinivasan AK (2018) Tetraglycidyl epoxy reinforced with surface functionalized mullite fiber for substantial enhancement in thermal and mechanical properties of epoxy nanocomposites. Silicon 10:585–594

    Article  CAS  Google Scholar 

  22. Mansoori Y, Atghia SV, Zamanloo MR, Imanzadeh G, Sirousazar M (2010) Polymer–clay nanocomposites: free-radical grafting of polyacrylamide onto organophilic montmorillonite. Eur Polym J 46:1844–1853

    Article  CAS  Google Scholar 

  23. Bhanvase BA, Pinjari DV, Gogate PR, Sonawane SH, Pandit AB (2012) Synthesis of exfoliated poly(styrene-co-methyl methacrylate)/montmorillonite nanocomposite using ultrasound assisted in situ emulsion copolymerization. Chem Eng J 181-182:770–778

    Article  CAS  Google Scholar 

  24. Ganjeh MS, Ahmadinejad N, Akbarzadeh A (2019) Vinyl modified Cloisite 30B clay as an efficient filler for the synthesis of poly(styrene-co-butyl acrylate)/clay nanocomposite by emulsion polymerization. Polym Sci Ser B 61:493–502

    Article  CAS  Google Scholar 

  25. Mansoori Y, Hemmati S, Eghbali P, Zamanloo MR, Imanzadeh G (2013) Nanocomposite materials based on isosorbide methacrylate/Cloisite 20A. Polym Int 62:280–288

    Article  CAS  Google Scholar 

  26. Mansoori Y, Akhtarparast A, Reza Zamanloo M, Imanzadeh G, Masooleh TM (2011) Polymer-montmorillonite nanocomposites: chemical grafting of polyvinyl acetate onto Cloisite 20A. Polym Compos 32:1225–1234

    Article  CAS  Google Scholar 

  27. Zhang J, Gupta RK, Wilkie CA (2006) Controlled silylation of montmorillonite and its polyethylene nanocomposites. Polymer 47:4537–4543

    Article  CAS  Google Scholar 

  28. Akelah A, Moet A (1996) Polymer-clay nanocomposites: free-radical grafting of polystyrene on to organophilic montmorillonite interlayers. J Mater Sci 31:3589–3596

    Article  CAS  Google Scholar 

  29. Tai X, Ma Jh DZ, Wang W (2013) The facile preparation for temperature sensitive silica/PNIPAAm composite microspheres. Appl Surf Sci 268:489–495

    Article  CAS  Google Scholar 

  30. Salami-Kalajahi M, Haddadi-Asl V, Roghani-Mamaqani H (2012) Study of kinetics and properties of polystyrene/silica nanocomposites prepared via in situ free radical and reversible addition-fragmentation chain transfer polymerizations. Sci Iran 19:2004–2011

    Article  Google Scholar 

  31. Tjong SC, Ruan YH (2008) Fracture behavior of thermoplastic polyolefin/clay nanocomposites. J Appl Polym Sci 110:864–871

    Article  CAS  Google Scholar 

  32. Zhang WA, Chen DZ, Xu HY, Shen XF, Fang YE (2003) Influence of four different types of organophilic clay on the morphology and thermal properties of polystyrene/clay nanocomposites prepared by using the γ-ray irradiation technique. Eur Polym J 39:2323–2328

    Article  CAS  Google Scholar 

  33. Yeh J-M, Liou S-J, Chang Y-W (2004) Polyacrylamide–clay nanocomposite materials prepared by photopolymerization with acrylamide as an intercalating agent. J Appl Polym Sci 91:3489–3496

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Department of Chemistry, Shahre-rey Branch, Islamic Azad University, Tehran, Iran

    Sadaf Kazemi & Abolfath Akbarzadeh

  2. Department of Mechanical Engineering, Faculty of Enghelab-e Eslami, Tehran Branch, Technical and Vocational University (TVU), Tehran, Iran

    Sadegh Mirzamohammadi

  3. Faculty of Materials Science and Engineering, K. N. Toosi University of Technology, No. 17, Pardis St., Molasadra Ave., Vanaq Sq, Tehran, Iran

    Hossein Ebrahimnezhad-Khaljiri

Authors
  1. Sadaf Kazemi
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  2. Sadegh Mirzamohammadi
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  3. Abolfath Akbarzadeh
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  4. Hossein Ebrahimnezhad-Khaljiri
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Correspondence to Hossein Ebrahimnezhad-Khaljiri.

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Kazemi, S., Mirzamohammadi, S., Akbarzadeh, A. et al. Synthesis of Clay/Poly (styrene/2-ethylhexyl acrylate) Nanocomposite Latexes via Emulsion Polymerization. Silicon 13, 831–840 (2021). https://doi.org/10.1007/s12633-020-00483-5

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  • DOI: https://doi.org/10.1007/s12633-020-00483-5

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