Skip to main content

Advertisement

SpringerLink
Log in

Novel Polymer Nanocomposites Comprising Triazole Functional Silica for Dental Application

  • Original Paper
  • Published:
Silicon Aims and scope Submit manuscript

Abstract

In the present work, the synthesis of novel nanocomposite polymer resins with silica bearing triazole functional groups was realized. Silica nanoparticles were produced by sol-gel method known as stöber process. Then the surface was modified with 1H-1,2,4-triazole to form functional silica nanoparticles. Dental nanocomposites were produced by insertion of functional nanoparticles into the Bis-GMA/TEGDMA different weight fractions. The initiator system was CQ/EDMAB:0.1:0.4 wt%, and then photopolymerization was carried out by means of LED light having wavelength of 450 nm–500 nm and power density of 1000 mW/cm2. FT-IR used to confirm the final structures of the functional nanoparticles as well as nanocomposites. The surface morphology of the materials was analyzed by SEM and thermal properties were studied by TGA. Cytotoxicity test and mechanical test were carried out to evaluate cell viability and mechanical properties of the materials, respectively. Sorption and solubility were conducted on the different formulations to obtain the mean sorption and solubility values of the materials. The test results demonstrated that the composition of the nanocomposite resins significantly changed their properties compared to control samples.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Bowen RL (1963) Properties of a silica-reinforced polymer for dental restorations. J. Am. Dent. Assoc. 66:57–64

    Article  CAS  Google Scholar 

  2. Stein P, Sullivan J, Haubenreich J, Osborne P (2005) Composite resin in medicine and dentistry. J Long-Term Eff Med Implants 15(6):641–654

    Article  CAS  Google Scholar 

  3. T. Aure, P. Anto, M. Se, and A. D. Logue, (2006) A clinical evaluation of posterior composite restorations : 17-year findings, 34: 427

  4. Bayne SC, Heymann HO, Swift EJ (1994) Update on dental composite restorations. J Am Dent Assoc 125:687–701

    Article  CAS  Google Scholar 

  5. Rueggeberg FA (2002) From vulcanite to vinyl, a history of resins in restorative dentistry. J Prosthet Dent 87:364–379

    Article  CAS  Google Scholar 

  6. Moszner N, Salz U (2001) New developments of polymeric dental composites. Prog Polym Sci 26:535–576

    Article  CAS  Google Scholar 

  7. Ikejima I, Nomoto R, McCabe JF (2003) Shear punch strength and flexural strength of model composites with varying filler volume fraction, particle size and silanation. Dent Mater 19:206–211

    Article  CAS  Google Scholar 

  8. Ruddell DE, Maloney MM, Thompson JY (2002) Effect of novel filler particles on the mechanical and wear properties of dental composites. Dent Mater 18:72–80

    Article  CAS  Google Scholar 

  9. Xu HHK, Quinn JB, Smith DT, Antonucci JM, Schumacher GE, Eichmiller FC (2002) Dental resin composites containing silica-fused whiskers—effects of whisker-to-silica ratio on fracture toughness and indentation properties. Biomaterials 23:735–742

    Article  CAS  Google Scholar 

  10. Taylor DF, Kalachandra S, Sankarapandian M, McGrath JE (1998) Relationship between filler and matrix resin characteristics and the properties of uncured composite pastes. Biomaterials 19:197–204

    Article  CAS  Google Scholar 

  11. Chung C-M, Kim J-G, Kim M-S, Kim K-M, Kim K-N (2002) Development of a new photocurable composite resin with reduced curing shrinkage. Dent Mater 18:174–178

    Article  CAS  Google Scholar 

  12. Atai M, Nekoomanesh M, Hashemi SA, Amani S (2004) Physical and mechanical properties of an experimental dental composite based on a new monomer. Dent Mater 20:663–668

    Article  CAS  Google Scholar 

  13. Adabo GL, dos Santos Cruz CA, Fonseca RG, Vaz LG (2003) The volumetric fraction of inorganic particles and the flexural strength of composites for posterior teeth. J Dent 31:353–359

    Article  CAS  Google Scholar 

  14. Manhart J, Kunzelmann K-H, Chen HY, Hickel R (2000) Mechanical properties and wear behavior of light-cured packable composite resins. Dent Mater 16:33–40

    Article  CAS  Google Scholar 

  15. Wei Y, Jin D, Wei G, Yang D, Xu J (1998) Novel organic–inorganic chemical hybrid fillers for dental composite materials. J Appl Polym Sci 70:1689–1699

    Article  CAS  Google Scholar 

  16. Xia Y, Zhang F, Xie H, Gu N (2008) Nanoparticle-reinforced resin-based dental composites. J Dent 36:450–455

    Article  CAS  Google Scholar 

  17. Xu HHK, Quinn JB, Smith DT, Giuseppetti AA, Eichmiller FC (2003) Effects of different whiskers on the reinforcement of dental resin composites. Dent. Mater 19(5):–367

    Article  CAS  Google Scholar 

  18. Fong H (2004) Electrospun nylon 6 nanofiber reinforced BIS-GMA/TEGDMA dental restorative composite resins. Polymer 45:2427–2432

    Article  CAS  Google Scholar 

  19. Wang X, Cai Q, Zhang X, Wei Y, Xu M, Yang X, Ma Q, Cheng Y, Deng X (2016) Improved performance of Bis-GMA/TEGDMA dental composites by net-like structures formed from SiO2 nanofiber fillers. Mater. Sci. Eng. C 59:464–470

    Article  CAS  Google Scholar 

  20. Mofarrehi MR, Shojaosadati SA (2012) Antibacterial properties of pure titanium coated with silver nanoparticles. Int J Nano Biomater 4:281

    Article  CAS  Google Scholar 

  21. Collins CJ, Bryant RW, Hodge K-LV (1998) A clinical evaluation of posterior composite resin restorations: 8-year findings. J Dent 26:311–317

    Article  CAS  Google Scholar 

  22. Ferracane JL (2006) Is the wear of dental composites still a clinical concern?: is there still a need for in vitro wear simulating devices? Dent Mater 22:689–692

    Article  CAS  Google Scholar 

  23. H. Sadeghpour, Y. Ghasemi, Z. Rezaie, and S. Khabnadideh, (2012) Antibacterial Activity of Some New Azole Compounds 8: 267

  24. I. A. Rahman et al., (2007) An optimized sol – gel synthesis of stable primary equivalent silica particles 294:102

  25. W. Stober and A. Fink, (1968) Controlled Growth of Monodisperse Silica Spheres in the Micron Size Range 1:69:62

  26. K. Sreenivasa, K. El-hami, T. Kodaki, and K. Matsushige, (2005) A novel method for synthesis of silica nanoparticles, 289:125

  27. C. Alzina, N. Sbirrazzuoli, and A. Mija, (2011) Epoxy-Amine Based Nanocomposites Reinforced by Silica Nanoparticles. Relationships between Morphologic Aspects , Cure Kinetics, and Thermal Properties, 22789

  28. U. S. YUSHA’U, (2017) Synthesis and characterization of multi-functional azole silica based nanocomposites for dental application. İstanbul University

  29. D. S. Achilias, M. M. Karabela, and I. D. Sideridou, (2008) Thermal degradation of light-cured dimethacrylate resins Part I. Isoconversional kinetic analysis 472:74

  30. Vouvoudi EC, Achilias DS, Sideridou ID (2015) Dental light-cured nanocomposites based on a dimethacrylate matrix : thermal degradation and isoconversional kinetic analysis in N 2 atmosphere. Thermochim Acta 599:63–72

    Article  CAS  Google Scholar 

  31. Standard I (2000) ISO 4049 polymer based filling, restorative and luting materials. Int Organ Stand 1

  32. Samuel SP, Li S, Mukherjee I, Guo Y, Patel AC, Baran G, Wei Y (2009) Mechanical properties of experimental dental composites containing a combination of mesoporous and nonporous spherical silica as fillers. Dent Mater 25:296–301

    Article  CAS  Google Scholar 

  33. Leprince J, Palin W, Mullier T, Devaux J, Vreven J, Leloup G (2010) Investigating filler morphology and mechanical properties of new low-shrinkage resin composite types. J Oral Rehabil 37:364–376

    Article  CAS  Google Scholar 

  34. A. Roman, M. Moldovan, and P. Iuliu, (2012) Study Regarding some Physico-chemical Properties of Composite Resins for Direct Restoration vol. 31, no. 3 pp. 1–8

  35. Wang H, Zhu M, Li Y, Zhang Q, Wang H (2011) Mechanical properties of dental resin composites by co- fi lling diatomite and nanosized silica particles. Mater Sci Eng C 31:600–605

    Article  Google Scholar 

  36. Cramer NB, Couch CL, Schreck KM, Carioscia JA, Boulden JE, Stansbury JW, Bowman CN (2010) Investigation of thiol-ene and thiol-ene-methacrylate based resins as dental restorative materials. Dent Mater 26:21–28

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of chemistry, Istanbul University, 34452, Istanbul, Turkey

    Umar S. Yushau

  2. Department of Biophysics, IRMC, Imam Abdulrrahman bin Faisal University, PO Box: 1982, Dammam, 31441, Saudi Arabia

    Lama Almofeez & Ayhan Bozkurt

Authors
  1. Umar S. Yushau
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Lama Almofeez
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Ayhan Bozkurt
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Ayhan Bozkurt.

Additional information

Publisher’s Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Yushau, U.S., Almofeez, L. & Bozkurt, A. Novel Polymer Nanocomposites Comprising Triazole Functional Silica for Dental Application. Silicon 12, 109–116 (2020). https://doi.org/10.1007/s12633-019-00104-w

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s12633-019-00104-w

Keywords

Search

Navigation