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Alkaline Earth Based Borosilicate Glasses as Sealants in Solid Oxide Fuel Cell Applications

Abstract

Alkaline earth based glasses of composition 35AO – 50B2O3 – 15SiO2 (A = Ba, Ca, Sr) was prepared by conventional melt quenching technique. Density of the glasses was measured using Archimede’s method. X-ray diffraction patterns confirmed the amorphous nature of the glasses. This result was supported by scanning electron microscope (SEM) image. The structure of the glasses was investigated by FT-IR spectroscopy. FT-IR spectrum revealed the characteristic bands due to various borate and silicate structural units. FT-Raman spectroscopy was used to investigate the characteristic bands of these glasses and its changes due to the presence of various alkaline earth metals. The microhardness of the glass samples was measured by indentation technique. Microhardness of all glasses were high (6.9–7.1) GPa, reflecting higher bond strength. The co-efficient of thermal expansion (CTE) were measured and lie within the range (8–10) × 10–6o C−1, which was in good agreement with that of the other SOFC components.

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References

  1. Kaur N, Kaur G, Khan S, Singh K (2017) Conductivity, dielectric and structural studies of (30-x)SrO-xBaO-10Al2O3-45-SiO2-5B2O3-10Y2O3 (5<x<25) glasses. Ionics. https://doi.org/10.1007/s11581-017-2360-y

    Article  Google Scholar 

  2. Laopaiboon R, Bootjmchai C (2015) Characterization of elastic and structural properties of alkali borosilicate glasses doped with vanadium oxide using ultrasonic technique. Glas Phys Chem 4:352–358

    Article  Google Scholar 

  3. Zaid MHM, Matori KA, Aziz SHA, Zakaria A, Ghazali MSM (2012) Effect of ZnO on the physical properties and optical band gap of soda lime silicate glass. Int J Mol Sci 13:7550–7558

  4. Ibrahim MM, Funny MA, Hassaan MY, El-Batal HA (2016) Optical, FTIR and DC conductivity of Soda Lime Silicate Glass Containing Cement Dust and Transition Metal Ions. Silicon 8:443–453

    CAS  Article  Google Scholar 

  5. Borhan A I, Gromada M, Nedelcu G G, Leontie L (2018) Influence of additives (CoO, CaO, B2O3) on thermal and dielectric properties of BaO-Al2O3-SiO2 glass-ceramic sealant for OTM applications, https://arxiv.org/ftp/arxiv/papers/1507/1507.03390.pdf. Accessed 16 April 2018

  6. Kothiyal GP, Goswami M, Tiwari B et al (2012) Some recent studies on glass/glass-ceramics for use as sealants with special emphasis for high temperature applications. J Adv Ceram 1:110–129.

    CAS  Article  Google Scholar 

  7. Chou YS, Stevenson JW, Gow RN (2007) Novel alkaline earth silicate sealing glass for SOFC part 1. The effect of nickel oxide on the thermal and mechanical properties. J Power Sources 168:426–433

    CAS  Article  Google Scholar 

  8. Dev B, Walter ME, Arkenberg GB et al (2014) Mechanical and thermal characterization of a ceramic/glass composite seal for solid oxide fuel cells. J Power Sources 245:958–966

    CAS  Article  Google Scholar 

  9. Dai Z, Pu J, Yan D, Chi B et al (2011) Thermal cycle stability of Al2O3-based compressive seals for planar intermediate temperature solid oxide fuel cells. Int J Hydrog Energy 36:3131–3137

    CAS  Article  Google Scholar 

  10. Tiwari B, Dixit A, Kothiyal GP (2011) Study of glasses/glass-ceramics in the SrO-ZnO-SiO2 system as high temperature sealant for SOFC applications. Int J Hydrog Energy 36:15002–15008

    CAS  Article  Google Scholar 

  11. Kaur B, Singh K, Pandey OP et al (2017) Influence of modifier on dielectric and ferroelectric properties of aluminosilicate glasses. J Non-Cryst Solids 465:26–30

    CAS  Article  Google Scholar 

  12. Macmillan PW (1977) Glass – ceramics. Academic press, New York, pp 1–5

    Google Scholar 

  13. Thombare MD (2014) Study of physical properties of Lithiumborophosphate glasses. Int J Res Pure and Appl Phys 4(2):9–15

    Google Scholar 

  14. Pascuta P, Pop L, Rada S et al (2008) The local structure of bismuth borate glasses doped with europium ions evidenced by FTIR spectroscopy. J Mater Sci Mater Electron 19:424–428

    CAS  Article  Google Scholar 

  15. Varshneya AK (1994) Density and molar volume, fundamentals of inorganic glasses. Academic press, New York

    Google Scholar 

  16. Rejisha SR, Anjana PS, Gopakumar N (2016) Effect of cerium (IV) oxide on the optical and dielectric properties of strontium bismuth borate glasses. J Mater Sci Mater Electron 27:5475–5482

    CAS  Article  Google Scholar 

  17. Mandal AK, Agrawal D, Sen R (2013) Preparation of homogeneous barium borosilicate glass using microwave energy. J Non-Cryst Solids 371:41–46

    Article  Google Scholar 

  18. El-Egili K (2003) Infra-red studies of Na2O – B2O3 – SiO2 and Al2O3 – Na2O – B2O3 – SiO2 glasses. Physica B 325:340–348

    CAS  Article  Google Scholar 

  19. Abo-Naf SM, El-Sayed MK, El-Sayed E-SM et al (2015) In vitro bioactivity evaluation, mechanical properties andmicrostructural characterization of Na2O–CaO–B2O3–P2O5 glasses. Spectrochim Acta A Mol Biomol Spectrosc 144:88–98

    CAS  Article  Google Scholar 

  20. Elbatal FHA, Khalil MMI, Nada N, Desouky SA (2003) Gamma rays interaction with ternary silicate glasses containing mixed CoO + NiO. Mater Chem Phys 82:375–387

    CAS  Article  Google Scholar 

  21. Kamitsos EI, Karakassides MA, Chryssikos GD (1987) Vibrational spectra of magnesium – sodium – borate glasses.2.Raman and mid – infrared investigation of the network structure. J Phys Chem 91:1073

    CAS  Article  Google Scholar 

  22. Kamitsos EI, Karakassides MA, Chryssikos GD (1987) A vibrational study of li-borate glasses with high LiO2 content. Phys Chem Glasses 28:203–209

    CAS  Google Scholar 

  23. Kaur R, Singh S, Pandey OP (2012) FTIR structural investigation of gamma irradiated BaO-Na2O-B2O3-SiO2 glasses. Physica B 407:4765–4769

    CAS  Article  Google Scholar 

  24. Rejisha SR, Santha N (2011) Structural investigations on 20MO-xBi2O3-(80-x)B2O3 (M=ca, Sr and Ba; x=15and 55) glasses. J Non-Cryst Solids 357:3813–3821

    CAS  Article  Google Scholar 

  25. Kamitsos EI, Kapoutsis JA, Jain H, Hsieh CH (1994) Vibrational study of the role of trivalent ions in sodium trisilicateglass. J Non-Cryst Solids 171:31–45

    CAS  Article  Google Scholar 

  26. Furukawa T, Whtte WB (1981) Raman spectroscopic investigation of sodium borosilicate glass structure. J Mater Sci 16:2689–2700

    CAS  Article  Google Scholar 

  27. Eremyashev VE, Osipov AA, Osipova LM (2011) Borosilicate glass structure with rare-earth-metal cations substituted for sodium cations. Glas Ceram 68(7–8):205–208

    CAS  Article  Google Scholar 

  28. Gaskell PH (1991) In: Zarzcycki J (ed) Materials science and technology, glasses and amorphous materials, Vol 9. Wiley -VCH, Weinheim

  29. Chryssikos GD, Kamitsos EI, Patsis AP, Bitsis MS, Karakassides MA (1990) Thedevitrification of lithium metaborate: polymorphism and glass formation. J Non-Cryst Solids 6:42–51

    Article  Google Scholar 

  30. Gavenda T, Gedeon O, Jurek K (2017) Structural and volume changes and their correlation in electron irradiated alkali silicate glasses. Nucl Inst Methods Phys Res. B 397:15–26

    CAS  Article  Google Scholar 

  31. Kacema IB, Gautron L, Coillot D, Neuville DR (2017) Structure and properties of lead silicate glasses and melts. Chem Geol 461:104–114

    Article  Google Scholar 

  32. McMillan P (1984) Structural studies of silicate glasses and melts applications and limitations of Raman spectroscopy. Am Mineral 69:622–644

    CAS  Google Scholar 

  33. Matson DW, Sharma SK, Philpotts JA (1983) The structure of high silica alkali-silicate glasses. A Raman spectroscopic investigation. J Non-Cryst Solids 58:323–352

    CAS  Article  Google Scholar 

  34. Rezazadeh L, Baghshahi S, NozadGolikand A, Hamnabard Z (2017) Structure, phase formation, and wetting behaviour of BaO–SiO2– B2O3 based glass–ceramics as sealants for solid oxide fuel cells. Ionics 20:55–64. https://doi.org/10.1007/s11581-013-0934-x

    CAS  Article  Google Scholar 

  35. Berwal N, Dhankhar S, Sharma P, Kundu RS, Punia R, Kishore N (2017) Physical, structural and optical characterization of silicate modified bismuth-borate-tellurite glasses. J Mol Struct 1127:636–644

    CAS  Article  Google Scholar 

  36. Kaky KM, Lakshminarayana G, Baki SO, Lira A, Meza-Rocha AN, Falcony C, Caldino U, Kityk IV, Taufiq-Yap YH, Halimah MK, Mahdi MA (2017) Structural and optical studies of Er3+ doped alkali/alkaline oxide containing zinc boro-aluminosilicate glasses for 1.5 mm optical amplifier applications. Opt Mater 69:401–419

    CAS  Article  Google Scholar 

  37. Nanda K, Berwal N, Kundu RS, Punia R, Kishore N (2015) Effect of doping of Nd3+ ions in BaO–TeO2–B2O3 glasses: A vibrational and optical study. J Mol Struct 1088:147–154

    CAS  Article  Google Scholar 

  38. Patil AL (2017) Measurments of Vickers hardness and refractive index properties of Na- Borophosphate glasses. Int J ChemTech Res 10(12):138–142

    Google Scholar 

  39. Zhang Q, Du X et al Effect of Nb2O5 doping on improving the thermo-mechanical stability of sealing interfaces for solid oxide fuel cells. Sci Report 7(5355). https://doi.org/10.1038/s41598_017_05725_y

  40. Barlet M, Delaye JM, Charpentier T, Gennisson M, Bonamy D, Rouxel T, Rountree CL (2015) Hardness and toughness of sodium borosilicate glasses via Vickers's indentations. J Non-Cryst Solids 417–418:66–79

    Article  Google Scholar 

  41. Meinhardt KD, Kim DS, Chou YS et al (2008) Synthesis and properties of a barium aluminosilicate solid oxide fuel cell glass–ceramic sealant. J Power Sources 182:188–196

    CAS  Article  Google Scholar 

  42. Kumar V, Arora A, Pandey OP et al (2008) Studies on thermal and structural properties of glasses as sealants for solid oxide fuel cells. Int J Hydrog Energy 33:434–438

    CAS  Article  Google Scholar 

Download references

Acknowledgements

The authors would like to acknowledge SAIF, Cochin, Kerala for providing the XRD facility. The authors are also thankful to SICC, University of Kerala for the SEM image. The authors are grateful to Dr. I. Ibnusaud, IIRBS, M.G. University, Kottayam for FT-IR analysis. Authors are also thankful to SAIF, M.G. University, Kottayam for FT-Raman analysis. The authors are also thankful to Dr. Ratheesh, C-MET, Thrisur for CTE analysis.

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Correspondence to P. S. Anjana.

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Salinigopal, M.S., Gopakumar, N. & Anjana, P.S. Alkaline Earth Based Borosilicate Glasses as Sealants in Solid Oxide Fuel Cell Applications. Silicon 12, 101–107 (2020). https://doi.org/10.1007/s12633-019-00103-x

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  • DOI: https://doi.org/10.1007/s12633-019-00103-x

Keywords

  • Borosilicate glass
  • Density
  • XRD
  • FT-IR
  • Co-efficient of thermal expansion