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Cu-SBTU@MCM-41: As an Efficient and Reusable Nanocatalyst for Selective Oxidation of Sulfides an Oxidative Coupling of Thiols

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Abstract

Cu(II) complex with S-benzylisothiourea ligand was grafted into functionalized mesoporous MCM-41 (Cu-SBTU@MCM-41) and characterized by X-ray Diffraction (XRD), thermal gravimetric analysis (TGA), scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDX), Fourier transform infrared spectroscopy (FT-IR) and inductively Coupled Plasma (ICP-OES) techniques. After characterization of this catalyst its application has been studied in selective oxidation of sulfides to sulfoxides and oxidative coupling of thiols to disulfides using hydrogen peroxide (H2O2) as oxidant. This catalyst was shown good recyclability and reused for several consecutive runs without significant loss of its activity.

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References

  1. Gawande MB, Luque R, Zboril R (2014) ChemCatChem 6:3312–3313

    Article  CAS  Google Scholar 

  2. Nikoorazm M, Ghorbani-Choghamarani A, Panahi A, Tahmasbi B, Noori N (2018) J Iran Chem Soc 15:181–189

    Article  CAS  Google Scholar 

  3. Zolfigol MA, Khakyzadeh V, Moosavi-Zare AR, Rostami A, Zare A, Iranpoor N, Beyzavi MH, Luque R (2013) Green Chem 15:2132–2140

    Article  CAS  Google Scholar 

  4. Mokhtary M (2016) J Iran Chem Soc 13:1827–1845

    Article  CAS  Google Scholar 

  5. Cheng T, Zhang D, Li H, Liu G (2014) Green Chem 16:3401–3427

    Article  CAS  Google Scholar 

  6. Nikoorazm M, Noori N, Tahmasbi B, Faryadi S (2017) Transit Met Chem 42:469–481

    Article  CAS  Google Scholar 

  7. Koukabi N, Kolvari E, Zolfigol MA, Khazaei A, Shirmardi Shaghasemi B, Fasahati B (2012) Adv Synth Catal 354:2001–2008

    Article  CAS  Google Scholar 

  8. Karimi B, Mansouri F, Mirzaei HM (2015) ChemCatChem 7:1736–1789

    Article  CAS  Google Scholar 

  9. Koukabi N, Kolvari E, Khazaei A, Zolfigol MA, Shirmardi-Shaghasemi B, Khavasi HR (2011) Chem Commun 47:9230–9232

    Article  CAS  Google Scholar 

  10. Nikoorazm M, Ghorbani-Choghamarani A, Khanmoradi M (2016) J Porous Mater 23:761–772

    Article  CAS  Google Scholar 

  11. Maria G, Stoica AI, Luta I, Stirbet D, Radu GL (2012) Micro Meso Mater 162:80–89

    Article  CAS  Google Scholar 

  12. Idris SA, Harvey SR, Gibson LT (2011) J Hazard Mater 193:171–176

    Article  CAS  PubMed  Google Scholar 

  13. Yan S, Xiu-Wu L, Wei S, Yaping Z, Li Z (2007) Appl Surf Sci 253:5650–5655

    Article  CAS  Google Scholar 

  14. Benhamou A, Basly JP, Baudu M, Derriche Z, Hamacha R (2013) J Colloid Interface Sci 404:135–139

    Article  CAS  PubMed  Google Scholar 

  15. Nikoorazm M, Ghorbani-Choghamarani A, Noori N, Tahmasbi B (2016) Appl Organometal Chem 30:843–851

    Article  CAS  Google Scholar 

  16. Abdollahi-Alibeik M, Pouriayevali M (2012) Catal Commun 22:13–18

    Article  CAS  Google Scholar 

  17. Havasi F, Ghorbani-Choghamarani A, Nikpour F (2016) Microporous Mesoporous Mater 224:26–35

    Article  CAS  Google Scholar 

  18. Huang Y, Hao W, Ding G, Cai MZ (2012) J Organometal Chem 715:141–146

    Article  CAS  Google Scholar 

  19. Nikoorazm M, Ghorbani-Choghamarani A, Noori N (2016) Res ChemIntermed 42:4621–4640

    CAS  Google Scholar 

  20. Ghorbani-Choghamarani A, Ghasemi B, Safari Z, Azadi G (2015) Catal Commun 60:70–75

    Article  CAS  Google Scholar 

  21. Zolfigol MA (2000) Synth Commun 30:1593–1597

    Article  CAS  Google Scholar 

  22. Shirini F, Zolfigol MA, Lakouraj MM, Azadbar MR (2001) Russ J Org Chem 37:1340–1341

    Article  CAS  Google Scholar 

  23. Hajjami M, Ghorbani-Choghamarani A, Ghafouri-Nejad R, Tahmasbi B (2016) New J Chem 40:3066–3074

    Article  CAS  Google Scholar 

  24. Sreedhar B, Radhika P, Neelima B, Hebalkar N, Mishra AK (2008) Catal Commun 10:39–44

    Article  CAS  Google Scholar 

  25. Villalobos L, Ren T (2013) Inorg Chem Commun 28:52–54

    Article  CAS  Google Scholar 

  26. Ghorbani-Choghamarani A, Tahmasbi B, Moradi P, Havasi N (2016) Appl Organometal Chem 30:619–625

    Article  CAS  Google Scholar 

  27. Shaabani A, Rezayan AH (2007) Catal Commun 8:1112–1116

    Article  CAS  Google Scholar 

  28. Romanelli GP, Villabrille PI, Cáceres CV, Vázquez PG, Tundo P (2011) Catal Commun 12:726–730

    Article  CAS  Google Scholar 

  29. Villalobos L, Ren T (2013) Inorg Chem Commun 28:52–54

    Article  CAS  Google Scholar 

  30. Molassiotis A, Bryan G, Caress A, Bailey C, Smith J (2010) Respir Med 104:934–944

    Article  CAS  PubMed  Google Scholar 

  31. Ghorbani-Choghamarani A, Moradi P, Tahmasbi B (2016) RSC Adv 6:56458–56466

    Article  CAS  Google Scholar 

  32. Abbasi M;Khalili D (2015) J Iran Chem Soc 12:1425–1430

    Article  CAS  Google Scholar 

  33. Rattanangkool E, Krailat W, Vilaivan T, Phuwapraisirisan P, Sukwattanasinitt M, Wacharasindhu S (2014) Eur J Org Chem 22:4795–4804

    Article  CAS  Google Scholar 

  34. Ghorbani-Choghamarani A, Azadi G, Tahmasbi B, Hadizadeh-Hafshejani M, Abdi Z (2014) Elem 189:433–439

    CAS  Google Scholar 

  35. Tamhankar BV Int (2014) J Res Org Chem 4:4–6

    Google Scholar 

  36. Liu Y, Wang H, Wang C, Wan JP, Wen C (2013) RSC Adv 3:21369–21372

    Article  CAS  Google Scholar 

  37. Ghorbani-Choghamarani A, Hajjami M, Tahmasbi B, Noori N (2016) J Iran Chem Soc 13:2193–2202

    Article  CAS  Google Scholar 

  38. Firouzabadi F, Iranpoor N, Zolfigol MA (1998) Synth Commun 28:377–385

    Article  CAS  Google Scholar 

  39. Firouzabadi H, Iranpoor N, Zolfigol MA (1998) Synth Commun 28:1179–1187

    Article  CAS  Google Scholar 

  40. Zolfigol MA, Amani K, Ghorbani-Choghamarani A, Hajjami M, Ayazi-Nasrabadi R, Jafari S (2008) Catal Commun 9:1739–1744

    Article  CAS  Google Scholar 

  41. Ghorbani-Choghamarani A, Moradi P, Tahmasbi B (2016) RSC Adv 6:56638–56646

    Article  CAS  Google Scholar 

  42. Ghorbani-Choghamarani A, Rabiei H, Tahmasbi B, Ghasemi B, Mardi F (2016) Res Chem Intermed 42:5723–5737

    Article  CAS  Google Scholar 

  43. Hajjami M, Shirvandi Z, Yousofvand Z (2017) J Porous Mater 24:1461–1472

    Article  CAS  Google Scholar 

  44. Shiri L, Tahmasbi B (2017) Phosphorus, Sulfur, and Silicon 192:53–57

    Article  CAS  Google Scholar 

  45. Shiri L, Kazemi M (2017) Phosphorus, Sulfur, and Silicon 192:1171–1176

    Article  CAS  Google Scholar 

  46. Nikoorazm M, Jabbari A (2017) J Porous Mater 24:477–486

    Article  CAS  Google Scholar 

  47. Azizi M, Maleki A, Hakimpoor F, Ghalavand R, Garavand A (2017) Catal Lett 147:2173–2177

    Article  CAS  Google Scholar 

  48. Dou Y, Huang X, Wang H, Yang L, Li H, Yuan B, Yang G (2017) Green Chem 19:2491–2495

    Article  CAS  Google Scholar 

  49. Yang L, Li S, Dou Y, Zhen S, Li H, Zhang P, Yuan B, Yang G (2017) Asian J Org Chem 6:265–268

    Article  CAS  Google Scholar 

  50. Nikoorazm M, Ghorbani-Choghamarani A, Khanmoradi M (2017) J Iran Chem Soc 14:1215–1225

    Article  CAS  Google Scholar 

  51. Ghorbani-Choghamarani A, Tahmasbi B, Noori N, Ghafouri-Nejad R (2017) J Iran Chem Soc 14:681–693

    Article  CAS  Google Scholar 

Download references

Acknowledgments

Financial support for this work by the research affairs of Ilam University, Ilam, Iran is gratefully acknowledged.

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Authors and Affiliations

  1. Department of Chemistry, Ilam University, P.O. Box 69315516, Ilam, Iran

    Mohsen Nikoorazm & Massoud Ghobadi

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  1. Mohsen Nikoorazm
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  2. Massoud Ghobadi
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Correspondence to Mohsen Nikoorazm.

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Nikoorazm, M., Ghobadi, M. Cu-SBTU@MCM-41: As an Efficient and Reusable Nanocatalyst for Selective Oxidation of Sulfides an Oxidative Coupling of Thiols. Silicon 11, 983–993 (2019). https://doi.org/10.1007/s12633-018-9871-7

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  • DOI: https://doi.org/10.1007/s12633-018-9871-7

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